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Kinsel GR Knochenmuss R Setz P Land CM Goh SK Archibong EF Hardesty JH Marynick DS 《Journal of mass spectrometry : JMS》2002,37(11):1131-1140
The photoionization of (pro)(n)DHB (pro = proline, DHB = 2,5-dihydroxybenzoic acid, n = 0, 1, 2 or 4) clusters was studied both experimentally and computationally. Experimentally the (pro)(n)DHB clusters are generated in the gas phase by laser desorption and supersonic jet entrainment. The photoionization thresholds are then determined by the mass-selective measurement of both one- and two-color photoionization efficiency curves. These experiments demonstrate that the ionization energies (IEs) of the (pro)(n)DHB clusters are substantially reduced in comparison with the IE of free DHB. Computational studies of the (pro)(n)DHB clusters provide insights into the mechanism of IE reduction. For the (pro)DHB system the IE reduction results from spin delocalization in the ion state of the cluster. In contrast, for the (pro)(2)DHB and (pro)(4)DHB clusters the IE reduction results from an inductive delocalization of electron density from pro to DHB in the ground state of the cluster. This latter effect, which is a result of the specific hydrogen-bonding interactions occurring in the mixed clusters, leads to IE reductions of >1 eV. Finally, determination of the energetics of the (pro)(2)DHB radical cation demonstrate that the DHB-to-proline proton transfer reaction is a barrierless, exoergic process in the ion state and that energetic demands for cluster dissociation to protonated (pro)(2) plus a deprotonated DHB radical are substantially lower than those for cluster dissociation to (pro)(2) plus DHB(+*). Cumulatively, these studies provide new energetic and mechanistic insights into both primary and secondary MALDI ionization processes. 相似文献
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Martin Pomerantz Jiping Wang Seeyearl Seong Kyle P. Starkey Long Nguyen Dennis S. Marynick 《Phosphorus, sulfur, and silicon and the related elements》2013,188(1-4):507-508
Abstract Poly(benzo[1,2-b:4,5-b′]dithiophene-4,8-diyl vinylene) (1) has been prepared by the pyrolysis of the precursor polymer 2 and studied. Quantum mechanical calculations on the aromatic and quinoid monomers, oligomers and polymers indicate that 1 is a planar aromatic polymer. 相似文献
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The gas-phase basicities (GBs), gas-phase proton affinities (PAs) and ionization potentials (IPs) of all six isomers of dihydroxybenzoic acid have been calculated using density functional theory at the B3LYP/6-311++G(2df,p)//B3LYP/6-31+G** level. A detailed conformational analysis of each isomer was performed, and the calculated thermodynamic properties were Boltzmann averaged over all conformations. Respectively, the GBs and the gas-phase PAs vary from 803.8 and 832.5?kJ?mol?1 for the least basic species (3,5-DHB) to 830.1 and 861.4?kJ?mol?1 for the most basic isomer (2,4-DHB). The reported GBs and gas-phase PAs of 2,3-DHB and 2,4-DHB, are in excellent agreement with previous experimental measurements. Agreement for the 2,5-DHB and 3,4-DHB isomers are not as good, but still close to or within the experimental error estimates. The calculated values for the GB and gas-phase PA of 2,6-DHB and especially 3,5-DHB are significantly outside the experimental error brackets. Repeating these calculations on the lowest energy conformation of each isomer at the MP2/6-311++G(2df,p)//MP2/6-31+G** level yielded significantly worse results. Our results indicate that protonation in all isomers takes place on the carboxylic sites. The vertical IPs vary from 8.14 eV for 2,5-DHB to 8.56 eV for 2,4-DHB. 相似文献
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CM Thaker S Rayaprol Krushna Mavani DS Rana MS Sahasrabudhe SI Patil DG Kuberkar 《Pramana》2002,58(5-6):1035-1039
The effect of simultaneous substitution of a fluctuating cation and a divalent cation in LaMnO3 perovskite modifies the properties of the material to exhibit large valence colossal magnetoresistance (CMR) effect. A good
example of these properties is (La1−2x
Pr
x
Ca
x
)MnO3 (LPCMO) type CMR material. In this communication it is reported that, with the increase in x (for x=0.1, 0.15, 0.2), the T
c varies between 100 and 120 K with improvisation in metal-insulator transition. Interestingly, resistance increases with x from few hundred ohms to few kilo ohms with corresponding decrease in the unit cell volume. The results of the studies using
X-ray diffraction (XRD), electrical resistivity, magnetoresistance and ac susceptibility measurements on LPCMO samples for
understanding the structural, transport and magnetic properties are discussed in detail. 相似文献