The influence of Triton X-100 (concentration 5 mM) on acid-base properties of aminomethylated calix[4]resorcinarene (H
8L) containing alkyl (R
1 = C
11H
23) and dimethylaminomethyl (R
2 = CH
2N(CH
3)
2) substituents and interaction of H
8L with copper(II) is studied by potentiometry and mathematical simulation of equilibria in solutions. It is found that the presence of a nonionic surfactant favors the aggregation of H
8L (the degree of aggregation is higher than four), whereas, in 80% isopropanol at the same pH ≈ 10.2, a neutral species of the compound is only dimerized. The addition of Triton X-100 affects both the composition and stability of formed copper(II) complexes. The fraction of the highly charged tetranuclear [Cu
4(H
4L)]
4+ complex sharply decreases. The formation of a large amount of [Cu(H
7L)]
+ complex appears to be preferable compared to [Cu(H
8L)
2]
2+ complex containing two ligands in the coordination sphere (pH ≈ 5.7). An enhancement of the acidic properties of protonated species of the compound and a decrease in the apparent constants of H
8L-copper(II) complex formation in Triton X-100 solutions compared to those in water-alcohol solutions are attributed to the formation of mixed micelles.__________Translated from Kolloidnyi Zhurnal, Vol. 67, No. 4, 2005, pp. 527–533.Original Russian Text Copyright © 2005 by Sal’nikov, Boos, Ryzhkina,
Lukashenko, Tiforova.
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