排序方式: 共有31条查询结果,搜索用时 552 毫秒
1.
Masato Hasebe Catherine Lazare Paul de Mayo Alan C. Weedon 《Tetrahedron letters》1981,22(51):5149-5152
Irradiation of a number of aromatic hydrocarbons adsorbed on alumina in the presence of ferric chloride leads to monochlorination. 相似文献
2.
In this work, the nanostructuring induced in femtosecond (fs) laser irradiation of biopolymers is examined in self-standing films of collagen and gelatine. Irradiation by single 90 fs pulses at 800, 400 and 266 nm is shown to result in the formation of a modified layer with submicrometric size structures. The size and uniformity of the observed features are strongly dependent on irradiation wavelength and on the characteristics of the biopolymer (water content and mechanical strength). Examination of the films by laser induced fluorescence serves to assess the chemical modifications induced by laser irradiation, revealing changes in the emission bands assigned to the aromatic amino acid tyrosine and its degradation products. The results are discussed in the framework of a mechanism involving the generation of large free-electron densities, through multiphoton and avalanche ionization, which determine the temperature and stress distribution in the irradiated volume. 相似文献
3.
S. Lazare I. Elaboudi M. Castillejo A. Sionkowska 《Applied Physics A: Materials Science & Processing》2010,101(1):215-224
A set of polymers including biopolymers and polymers from renewable resources are studied, with attention paid to their capability
to form a foamy surface layer by laser irradiation. A model of laser-induced pressure wave is discussed, with its tensile
tail giving rise to a fast and dense nucleation of cavities that can expand to microbubbles when filled with ablation gas.
The intensity of the pressure wave has a maximum for an absorption coefficient of ∼1000 cm−1. Polyvinyl acetate, studied as a prototype polymer experimentally and by modeling, allows discussing the role of the viscosity
drop in the dynamics of the laser-induced cavitations. In the Zeldovich frequency factor, a T (temperature) and P (pressure) dependent model of viscosity, and a T-dependent model of surface tension are introduced. It is further suggested that the well-known free-volume nanoholes existing
in the material before the irradiation can constitute the nuclei of importance and that their concentration is one of the
factors controlling the pre-exponential factor in the nucleation rate law. 相似文献
4.
S. Gaspard M. Oujja R. de Nalda M. Castillejo L. Bañares S. Lazare R. Bonneau 《Applied Physics A: Materials Science & Processing》2008,93(1):209-213
We have recently shown that irradiation of self-standing films of the biopolymers collagen and gelatine with single femtosecond
laser pulses produces a nanofoaming layer with regular bubble size which can be controlled by wavelength selection. Following
these initial studies, here we report on the temporal evolution of the foaming effect by measurements in situ and in real
time of the change in the transmittance of a cw probe HeNe laser through the irradiated films. Self standing films of the
biopolymers were irradiated with 90 fs laser pulses at 800, 400, and 266 nm. For fluences below and above the modification
threshold a permanent attenuation of the transmission occurs (increasing with fluence). The initial decay of the transmission
is fast (around few tens of ns), and is followed by dynamics in the longer timescale (micro and milliseconds). The temporal
evolution of the transmission measured upon fs laser irradiation is similar with that determined in the irradiation of the
biopolymer films at 248 nm with 25 ns laser pulses. The method allows separating in time the different processes occurring
after irradiation that lead to a permanent nanofoaming structure, while the results allow us to understand the mechanisms
of femtosecond laser processing of the biopolymers and their interest in biomedical applications. 相似文献
5.
T. Dumont S. Lazare T. Lippert A. Wokaun 《Applied Physics A: Materials Science & Processing》2004,79(4-6):1271-1274
The ablation rates of a polyimide and a triazene polymer were studied gravimetrically by a quartz micro balance for 248-nm and 308-nm irradiation. Special care was taken to examine the dependence of the ablation rate at constant fluences for single pulses and the influence of consecutive pulses at the same position. A clear trend was observed in these measurements, i.e., that the mass loss after the first pulse is always different from values for the following pulses. This implies that it is very difficult to determine true ablation rates, which are the foundation of most ablation models. The differences of the mass loss between the first pulse and the following pulses is most probably due to carbonization of the material, resulting in varying ablation rates for the following pulses. The ablation rates are thus not a real material property but a superposition of the material ablation rates with the ablation rates of carbon and carbonized material. PACS 52.38.Mf; 71.20.Rv; 07.10.Lw 相似文献
6.
A total synthesis of (?)hibaene 1 is described. The key steps are a photochemical cycloaddition of vinyl acetate on the α-β unsaturated ketone 2 and a Wagner-Meerwein type rearrangement of the diols 14 and 15, which contain a highly strained cyclobutane ring. A selective esterification of the rearranged diols 22a or 22b leads to intermediates which can conveniently be transformed into (?)hibaene. 相似文献
7.
Abstract Measurements were performed to determine the action spectrum and dose dependence for photoreactivation of E. coli Bs-1 cells after γ-irradiation. The similarities between photoreactivation after UV- and after γ-irradiation in action spectra, kinetics, and other characteristics indicate that the increased survival of γ-irradiated cells after illumination with photoreactivating light is the result of true photoenzymatic repair. 相似文献
8.
9.
Lazare Dragos 《Zeitschrift für Angewandte Mathematik und Physik (ZAMP)》1966,17(2):249-259
Summary Writing the MTE equations in non-dimensional variables, the author points out the essential parameters and the structure of the equations. The equation of the MTE system characteristics is determined, as well as the displacement velocities of the waves of weak discontinuity. Furthermore, the equation which is satisfied by the current density vectorJ is determined.The paper considers the Cauchy problem for the infinite perfectly conductive plane, in the presence of a temperature and of a magnetic field. The general solution for the current density and the magnetic field are determined from Maxwell's equation. The solution obtained permits one to determine the displacement and the temperature fields by means of the classical thermoelasticity.The method of solving the Cauchy problem is based upon the representation of the general solution by a continous superposition of plane waves. 相似文献
10.
Do Khac Manh Duc Marcel Fetizon Sylvani Lazare Peter K. Grant Murray J. Nicholls Henry T.L. Liau Malcolm J. Francis Jacques Poisson Jean-Marie Bernassau Nidia Franca Roque Peter M. Wovkulich Ernest Wenkert 《Tetrahedron》1981,37(13):2371-2374
A caarbon shift analysis of hibaene, phyllocladene, cafestol, cafamarine, mascaroside and hilbane-like substances is presented. 相似文献