Field gradient electrophoresis

The class of equilibrium gradient methods utilizes the opposition of two forces, at least one of which changes in magnitude with position, to separate and concentrate analytes. The drawback of many methods of this type is that the production of two opposing forces requires in comparison to standard methods, such as capillary electrophoresis, a relatively complex apparatus. In addition, for techniques such as electric field gradient focusing, hydrodynamic flow leads to Taylor dispersion, which limits the attainable concentration factor. We propose a new method, gradient field electrophoresis, which achieves analyte separation and focusing with only one spatially varying force, an electric field gradient. A model for the method is developed and used to analyze peak capacity. Experimental results for a protein (R-phycoerythrin) are given and compared to the model.     

An Ultra-Microporous Metal–Organic Framework with Exceptional Xe Capacity

Molecular confinement plays a significant effect on trapped gas and solvent molecules. A fundamental understanding of gas adsorption within the porous confinement provides information necessary to design a material with improved selectivity. In this regard, metal–organic framework (MOF) adsorbents are ideal candidate materials to study confinement effects for weakly interacting gas molecules, such as noble gases. Among the noble gases, xenon (Xe) has practical applications in the medical, automotive and aerospace industries. In this Communication, we report an ultra-microporous nickel-isonicotinate MOF with exceptional Xe uptake and selectivity compared to all benchmark MOF and porous organic cage materials. The selectivity arises because of the near perfect fit of the atomic Xe inside the porous confinement. Notably, at low partial pressure, the Ni–MOF interacts very strongly with Xe compared to the closely related Krypton gas (Kr) and more polarizable CO₂. Further ¹²⁹Xe NMR suggests a broad isotropic chemical shift due to the reduced motion as a result of confinement.     

Differential cross sections for the charge exchange process π+p → π0 (π+p) at 8, 16 and 23 GeV/c

The differential cross section $\text{d}\text{σ}\text{d}\text{t′}$ for the charge-exchange process π⁺p → π⁰ (π⁺p) at 8, 16 and 23 GeV/c is presented for several regions of the π⁺p effective mass. It is found that the dip at t′ ≈ 0.6 (GeV/c)² which is observed in the Δ(1236) mass band becomes a less pronounced structure in the higher mass regions. However, while the slope of the $\text{d}\text{σ}\text{d}\text{t′}$ distributions in the near-forward direction decreases strongly with increasing π⁺p mass, there is no evidence that the observed structure moves to higher values of t′ as the π⁺p mass increases. These results are consistent with a Regge-exchange picture where the position of the dip is determined by the exchanged trajectory, but are inconsistent with a simple geometrical picture.     

Impact parameter description of the charge exchange process π+ p → π° (π+ p)

The “Reggeometry” model — universal impact parameter profile and Reggen behaviour — is applied to recent data on π⁺ p → π° (π⁺ p) at different energies and (π⁺p) missing masses, including Δ production. We are able, in particular, to explain the filling of the dips and the variation of the slope with respect to the missing mass.