Measurements on diproton emission from the break-up channels of ~(23)Al and ~(22)Mg

Two-proton relative momentum distributions from the break-up channels 23Al→p+p+21Na and 22Mg→p+p+20Ne at an energy of 60-70 A MeV have been measured together with two-proton opening angles at the projectile fragment separator beamline (RIPS) in the RIKEN Ring Cyclotron Facility. The results demonstrate the existence of diproton emission component from single-step 2He for highly excited 23Al and 22Mg.     

Theory of the magnon Kerr effect in cavity magnonics

We develop a theory for the magnon Kerr effect in a cavity magnonics system, consisting of magnons in a small yttrium iron garnet(YIG) sphere strongly coupled to cavity photons, and use it to study the bistability in this hybrid system. To have a complete picture of the bistability phenomenon, we analyze two different cases in driving the cavity magnonics system, i.e.,directly pumping the YIG sphere and the cavity, respectively. In both cases, the magnon frequency shifts due to the Kerr effect exhibit a similar bistable behavior but the corresponding critical powers are different. Moreover, we show how the bistability of the system can be demonstrated using the transmission spectrum of the cavity. Our results are valid in a wide parameter regime and generalize the theory of bistability in a cavity magnonics system.     

“多靶串接”饱和增益软X光激光实验研究

采用“多靶串接”设计,利用强度为0.8×10~(13)～1.0×10~(13)W/cm~2,波长为1.05μm,脉宽约1ns的两路钕玻璃激光线聚焦辐照四块串接的平面厚锗靶,观察到波长为23.2和23.6nm的接近饱和的类Ne锗软X光激光输出。当总靶长为5.6cm时,这两种波长的软X光激光输出的GL值都达到16左右,沿靶法线和靶平面方向的发散角都只有3～4mrad。     

A new approach to the bicyclo[3.3.1]nonane framework of huperzine A-like molecules via palladium-catalyzed intramolecular γ-arylation

In our synthetic studies toward huperzine A, a diastereoselective α′-alkylation of the α-amido-γ-methyl hexenone 4 was realized through a dianion intermediate which significantly enhanced the reactivity. Under the attempted Heck reaction conditions, an unexpected and unprecedented palladium-catalyzed intramolecular γ-arylation of 3 was observed, which generated 18 with bicyclo[3.3.1]nonane framework in satisfactory yield.     

Orbital selection of the double [CuO_2] layer compound Ca_3Cu_2O_4Cl_2

正The discovery of high-temperature copper oxide superconductors(HTS)by Bednorz and Muller[1]in 1986 opened up a new field of superconductivity.Since then,several different families of materials have been discovered with greatly increased superconducting critical temperature(T_c)[2].Oxychloride cuprates,Ca_(n+1)Cu_nO_(2n)Cl_2,are one such type of     

Orbital selection of the double [CuO2] layer compound Ca3Cu2O4Cl2

We present a first-principles investigation on the dynamics and mechanism of the oxidation reaction between water molecules and the reduced PuO_2(110) surface using ab initio molecular dynamics(AIMD) simulations in combination with density functional theory(DFT) + U calculations. We find a dominating dissociation preference of water molecules for the vacancy defect sites on the PuO_2(110) surface, irrespective of the water or vacancy coverage. Due to hybridizations between the frontier orbitals of water molecule and the electronic states of the vacancy vicinity, partial water dissociation at the vacancy sites is exothermic and barrierless. The dissociation product, an OH group, further hydrogenates the PuO_2(110) surface by occupying the vacancy site.We also observe surface vacancy diffusion induced by the interactions between the water molecules and the surface oxygen atom in the proximity of the defect sites.     

新型双光子吸收化合物的合成、光物理及其在固态分散体系中的性质

通过多步反应制备了三个新型的双光子吸收化合物,测试了它们的光物理性质,发现该系列化合物具有较大的双光子吸收截面,并且随温度降低其双光子吸收截面增大.尤其是化合物TMVDB,其量子效率为0.83,常温时的双光子吸收截面达到1164GM,其双光子吸收截面除以分子量为2.08,表现出了优良的双光子吸收发光性能.进一步将TMVDB掺杂到固体材料中,得到强双光子诱导发光的固体材料.     

Computational design and simulation of the Mg-Cu system graded density impactors for complex loading experiments

Two types of Mg-Cu composition system graded density impactors used for complex loading (shock loading and quasi-isentropic compression) are designed by the elastic-plastic hydrodynamic method in this paper. Mixtures of metal powders in the Mg-Cu system are cast into a series of 17 and 25 uniform compositions ranging from 100% Mg to 100% Cu. The graded density impactors are launched to the stationary 10 m aluminum film and 12 mm LiF window targets by a two-stage light-gas gun in the National Key Laboratory ...     

Convenient synthesis of tropos phosphine-oxazoline ligands

Tropos phosphine-oxazoline ligands have shown interesting coordination behavior and excellent chiral inducing ability in asymmetry catalysis.Here we present a convenient and economic route for the synthesis of this type of ligands.According to this new route,the ligands with different electronic and steric properties have been prepared successfully.     

Observation of negative differential resistance in diketopyrrolopyrrole-based copolymer films

Remarkable and repeatable negative differential resistance (NDR) phenomenon was observed in a metal-polymer-metal structure diode based on bishexyloxy-divinyl-benzene-alt-diketopyrrolopyrrole (C6DPPPPV),a type of donor-acceptor (D-A) conjugated copolymer.Thickness dependence of the devices implied that the observed NDR characteristics were bulk-controlled.The device performance was considered to depend on the slow trapping and releasing processes related to the local deep states,which was enhanced by the gr...