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Kenan Koran Ahmet Ozkaya Furkan Ozen Erol Cil Mustafa Arslan 《Research on Chemical Intermediates》2013,39(3):1109-1124
Hexachlorocylotriphosphazene (1) was reacted with 4-hydroxy-3-methoxybenzaldehyde to give hexakis[(4-formyl-2-methoxy)phenoxy]cyclotriphosphazene (2). Hexakis[(4-(hydroxyimino)2-methoxy)phenoxy]cyclotriphosphazene (3) was synthesized by reaction of 2 with hydroxlamine hydrochloride in pyridine. Compound 3 was reacted with benzyl chloride, acetyl chloride, allyl bromide, benzoyl chloride, propanoyl chloride, 4-methoxybenzoyl chloride, 2-chlorobenzoyl chloride, chloroacetyl chloride, methyl iodide, and thiophene-2-carbonyl chloride. From these reactions, full or partially substituted compounds were obtained, usually in high yields. Pure or defined products could not be obtained from reaction of 3 with methacryloyl chloride and O-acetylsalicyloyl chloride. The structures of the compounds were determined by elemental analysis, and IR, 1H, 13C, and 31P NMR spectroscopy. The synthesized compounds were screened for in-vitro antimicrobial activity against two Gram-positive bacteria (Staphylococcus aureus and Enterococcus faecalis), two gram-negative bacteria (Escherichia coli and Klebsiella pneumonia), and fungal strains (Aspergillus niger, and Candida albicans) by the agar well diffusion method. Few compounds had significant activity against both Gram-positive and Gram-negative bacteria. None of the compounds had antifungal activity except compounds 7 and 9, which had moderate activity. 相似文献
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Keziban Usta Ozlem Ozen Karakus Ayhan Usta Hasalettin Deligoz 《Magnetic resonance in chemistry : MRC》2013,51(10):671-675
A macrocyclic azocalix[4]arene (1) based ester derivative was synthesized. The single crystals of azocalix[4]arene were produced by slow evaporation of concentrated ethyl acetate solutions. These single crystals were exposed to 60Co gamma rays with a dose rate of 0.980 kGy h‐1 for 48 and 72 h to produce a stable free radical. Electron paramagnetic resonance (EPR) measurements were performed in three mutually perpendicular planes of the single crystal in the magnetic field, in addition, temperature dependence of the EPR signal was studied between 120 K and 450 K. The spectra were found to be temperature and angular dependent. Analysis based on the spectra recorded showed that a free radical was formed by fission of a C–H bond. This radical is described as ?CaHCbH3 The averages of the principal values of the hyperfine parameters and g‐factor are: g = 2.0034, AHa = 1.28 mT, AH1=H2 = 1.00 mT, and AH3 = 0.49 mT. Copyright © 2013 John Wiley & Sons, Ltd. 相似文献
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Tokatlı A Ozen E Ucun F Bahçeli S 《Spectrochimica acta. Part A, Molecular and biomolecular spectroscopy》2011,78(3):1201-1211
The optimized molecular geometry, vibrational frequencies, and gauge including atomic orbital (GIAO) (1)H and (13)C NMR shift values of 5-(4-bromophenylamino)-2-methylsulfanylmethyl-2H-1,2,3-triazol-4-carboxylic acid ethyl ester have been calculated by using Hartree-Fock (HF) and density functional method (DFT/B3LYP) with 6-31G(d), 6-31G(d,p) and LANL2DZ basis sets. The optimized molecular geometric parameters were presented and compared with the data obtained from X-ray diffraction. In order to fit the calculated harmonic wavenumbers to the experimentally observed ones, scaled quantum mechanics force field (SQM FF) methodology was proceeded. Correlation factors between the experimental and calculated (1)H chemical shift values of the title compound in vacuum and in CHCl(3) solution by using the conductor-like screening continuum solvation model (COSMO) were reported. The calculated results showed that the optimized geometry well reproduces the crystal structure. The theoretical vibrational frequencies and chemical shifts are in very good agreement with the experimental data. In solvent media the energetic behavior of the title compound was also examined by using the B3LYP method with the 6-31G(d) basis set, applying the COSMO model. The obtained results indicated that the total energy of the title compound decreases with increasing polarity of the solvent. Furthermore, molecular electrostatic potential (MEP), natural bond orbital (NBO) and frontier molecular orbitals (FMOs) of the title compound were performed by the B3LYP/LANL2DZ method, and also thermodynamic parameters for the title compound were calculated at all the HF and B3LYP levels. 相似文献
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The mesoscopic morphologies of linear and graft fluorinated block copolymers of ABCBA and C:BA types, respectively, have been investigated by using dissipative particle dynamics method. Self-assembly in a selective solvent has been examined by the introduction of dimethylformamide as the choice of solvent. By comparing the solubility parameters calculated using atomistic simulations, fluorine-containing segments are found to be immiscible both with other segments of the polymer and with the solvent. Morphologies of the pure linear and graft copolymers were lamellar and cylindrical, respectively. Interfacial tension versus concentration curves have been used to explain the self-assembly behavior of copolymers in solution, as well as to predict the kinetic mechanisms responsible for this behavior. 相似文献
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S Cenk B Demirata M L Ove?oglu G Ozen 《Spectrochimica acta. Part A, Molecular and biomolecular spectroscopy》2001,57(12):2367-2372
Glasses with the composition of (1 - x)TeO2 + (x)WO3, where x = 0.15, 0.25 and 0.3 were prepared and, their thermal and absorption measurements were carried out. Differential thermal analysis (DTA) curves taken in the 23-600 degrees C temperature range with a heating rate of 10 degrees C/min reveal a change in the value of the glass transition temperature, Tg, while crystallization was not observed for the glasses containing a WO3 content of more than 15 mol%. All the glasses were found to be moisture-resistant. The absorption bands corresponding to the absorption of the 1G4, 3F2, 3F3 and 3F4, 3H5 and 3H4 levels from the 3H6 ground level of the Tm3+ ion were observed in the optical absorption spectra. Integrated absorption cross-sections of each band except that of 3H5 level was found to vary with the glass composition. Judd-Ofelt analysis was carried out for the samples doped with 1.0 mol% Tm2O3. The omega2 parameter shows the strongest dependence on the host composition and it increases with the increasing WO3 amount. The value of omega4 increases rather slowly while the value of omega6 is practically independent of the composition. The strong dependence of the parameter omega2 indicates that this parameter is related to the structural change and the symmetry of the local environment of the Tm3+ ions in this glass. 相似文献
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Ozen AS Aviyente V Tezcanli-Güyer G Ince NH 《The journal of physical chemistry. A》2005,109(15):3506-3516
Sonochemical bleaching of monoazo dyes C.I. Acid Orange 7 and C.I Acid Orange 8, which exist in their hydrazone forms in dye solutions, was investigated by irradiating 40 microM dye solutions using a 300 kHz emitter. It was found that the rate of bleaching was first-order with respect to the maximum absorption of the dye in the visible band and accelerated with increased acidity. Decolorization of Acid Orange 7 was slightly faster than that of Acid Orange 8 at equivalent test conditions. The oxidative degradation of Acid Orange 7 and Acid Orange 8 were modeled by means of density functional theory calculations. The adduct formation by hydroxyl radical attack to the carbon atom bearing the azo linkage was more preferred over the attack on the nitrogen atom. A competing reaction of hydrogen abstraction from the CH3 group in C.I Acid Orange 8 was found responsible for the difference in color removal rates. 相似文献
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Ozen G Demirata B 《Spectrochimica acta. Part A, Molecular and biomolecular spectroscopy》2000,(9):1795-1800
Luminescence of Ce3+ in the hydrogen peroxide induced sulfuric acid solutions was observed to be quenched by Ce4+ ions in the solution by energy transfer due to electric dipole interaction between Ce3+ and Ce4+. A systematic investigation of the energy transfer characteristics of Ce3+-Ce4+ mixture has been made by measuring the absorption, luminescence and excitation spectra at room temperature. The effect of the concentration of Ce3+ on the energy transfer process has been also studied and the critical transfer distance (Ro) has been calculated considering F?rster type interaction between the ions and found to be 8.7 A for the mixture of 1 x 10(-4) mol 1(-1) Ce3+ and 3 x 10(-4) mol l(-1) Ce4+. 相似文献
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Sodium acetate-catalyzed L-lactide polymerization reaction is a simple yet efficient reaction. It provides a robust system to produce poly(L-lactide) in industrial scale. In this study, the mechanism of this reaction has been studied by means of computational chemistry tools based on the experimental results. Basically, the mechanism consists of two steps: lactide coordination and ring opening through O-Acyl bond cleavage. Additionally, the effect of cation size and substituent on carboxylate moiety have been evaluated. The calculations indicate that the larger cation leads to faster reactions. Moreover, the stronger electron-donating group on carboxylate moiety accelerates the reaction rates. To obtain further insights, an orbital analysis has been also carried out. Our calculations are consistent with experimental findings and clarify underlying mechanistic features of the present reaction. 相似文献
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Serife O. Hacioglu Emre Ataoglu Gonul Hizalan Tolga Depci Levent Toppare 《Phosphorus, sulfur, and silicon and the related elements》2013,188(9):937-946
AbstractTwo novel thiadiazoloquinoxaline and benzodithiophene (BDT) bearing copolymers were designed and synthesized. Different BDT units (alkoxy and thiophene substituted) were used as donor materials and the effect of alkoxy and thiophene substitution on the electrochemical, spectroelectrochemical and photovoltaic properties were investigated. Both polymers exhibited low oxidation potentials at around 0.90 V and low optical band gaps at around 1.00?eV due to the insertion of electron poor thiadiazoloquinoxaline unit into the polymer backbone. Both P1 (poly-6,7-bis(3,4-bis(decyloxy)phenyl)-4-(4,8-bis(nonan-3-yloxy)benzo[1,2-b:4,5-b']dithiophen-2-yl)-[1, 2, 5]thiadiazolo[3,4-g]quinoxaline) and P2 (poly- 4-(4,8-bis(5-(nonan-3-yl)thiophen-2-yl)benzo[1,2-b:4,5-b']dithiophen-2-yl)-6,7-bis(3,4-bis(decyloxy)phenyl)-[1, 2, 5]thiadiazolo[3,4-g]quinoxaline) exhibited multichromic behavior with different tones of greenish yellow and gray in the neutral and fully oxidized states, respectively. In addition, both polymers revealed very high optical contrasts (~87%) in the NIR region which make these promising polymers good candidates for NIR applications. Finally, in order to explore the organic photovoltaic performances, P1 and P2 were mixed with PC71BM in the active layer of organic solar cells (OSCs) by conventional device structure. As a result P1 and P2 based devices revealed power conversion efficiencies (PCEs) of 0.33% and 0.60% respectively. However, the additive treatment enhanced PCE from 0.49 to 0.73% for P2 based devices. 相似文献