Two new eudesmane derivatives from Verbesina virginica

<正>Two new eudesmane derivatives were isolated from the leaves and flowers of Verbesina virginica,along with the known 6-O-β-E -p-coumaroyl-4α-hydroxyeudesmane(1).Their structures were determined as 6-O-β-Z-p-coumaroyl-4α-hydroxyeudesmane(2) and 6-O-α-E-p-coumaroyl-1β-4α-dihydroxyeudesmane(3) by spectroscopic methods.     

Effect of Pr-Ca substitution on the transport and magnetic behavior of LaMnO3 perovskite

The effect of simultaneous substitution of a fluctuating cation and a divalent cation in LaMnO₃ perovskite modifies the properties of the material to exhibit large valence colossal magnetoresistance (CMR) effect. A good example of these properties is (La_1−2x Pr _x Ca _x )MnO₃ (LPCMO) type CMR material. In this communication it is reported that, with the increase in x (for x=0.1, 0.15, 0.2), the T _c varies between 100 and 120 K with improvisation in metal-insulator transition. Interestingly, resistance increases with x from few hundred ohms to few kilo ohms with corresponding decrease in the unit cell volume. The results of the studies using X-ray diffraction (XRD), electrical resistivity, magnetoresistance and ac susceptibility measurements on LPCMO samples for understanding the structural, transport and magnetic properties are discussed in detail.     

PRESSURE-VELOCITY EQUILIBRIUM HYDRODYNAMIC MODELS

This article describes mathematical models for phase separated mixtures of materials that are in pressure and velocity equilibrium but not necessarily temperature equilibrium. General conditions for constitutive models for such mixtures that exhibit a single mixture sound speed are discussed and specific examples are described.     

Recent results on particle production from silicon emulsion interactions at 14.6A GeV

A comparative study of results obtained from the interactions of 14.6A GeV ²⁸Si in nuclear emulsion is presented. In this work the experimental data serve as one of the decisive signature of quark–gluon plasma formation. The data for 200 and 400 proton-emulsion interactions are used to investigate the assumption which consider interaction of ²⁸Si-Em at 14.6A GeV is such that for a proton with total energy corresponding to that for effective number of interacting nucleons (12.6×14.6=175) or as a proton having the total energy of ²⁸Si (i.e., 28×14.6=409 GeV). It is also shown that the relativistic quantum molecular dynamics model nicely predicts the multiplicities and correlations of shower and grey particles in the interactions of ²⁸Si with emulsion nuclei at 14.6A GeV.     

Simultaneous determination of dimethoate and its metabolite omethoate in curry leaf using LC-MS/MS and risk assessment

This study presents the method development, validation, and simultaneous determination of dimethoate and its metabolite omethoate in curry leaf. Samples were extracted following modified quick, easy, cheap, effective, rugged, and safe extraction protocol and analyzed using liquid chromatography-tandem mass spectrometry. The limit of quantification in the matrix was 0.005 μg g⁻¹ for dimethoate and omethoate. Extraction using acetonitrile recorded the average recoveries in the range of 82.25 to 112.97% for dimethoate and 85.57 to 107.22% for omethoate at 0.005, 0.025 and 0.050 μg g⁻¹ fortification levels and relative standard deviation less than 5%. Similarly, the relative standard deviation values for intraday (Repeatability) and interday (Reproducibility) tests were less than 15%. Dissipation kinetics of dimethoate 30% emulsifiable concentrate at 200 and 400 g a.i h⁻¹ recorded initial deposits of 5.20 and 10.05 μg g⁻¹ and 0.33 and 0.48 μg g⁻¹ for dimethoate and omethoate, respectively, and half-life of 3.07 and 3.34 days. The estimated hazard index value found more than one at a day after dimethoate application. It is not safe for consumer health to use curry leaves in the initial days after application.     

The characteristics of proton and induced neutron-emulsion high energy interactions

We used the technique of the separation of Coulomb and diffraction dissociation of incident heavy ion to select the events due to induced neutron from ¹⁶O leaving sub-oxygen nucleus to break-up. The characteristics of these events of neutron emulsion collisions are displayed and compared with that obtained from incident proton at the same energy.

The studied interactions are classified according to the type of target nucleus (H, CNO and AgBr) by using the method of separation. Cascade-evaporation model (CEM) calculations are taken into account and compared with that obtained from the interactions of induced neutron from ¹⁶O (4.5 A GeV/c) with emulsion nuclei and with the results of incident proton at the same target and energy. CEM can describe the distributions of proton and neutron interactions. It is conjuctured that it may be possible to develop a similar theoretical model based on the modern methods of nonlinear dynamics, neural network and complexity [Randomness and Undecidability in Physics, World Scientific, Singapore, 1993].