Random Copolymers of 1,5-Dioxepan-2-one

ABSTRACT

Copolymers of 1,5-dioxepan-2-one (DXO) and e-caprolactone (?-CL), δ-valerolactone (δ-VL) or L-lactide (LLA) have been synthesized and characterized. High molecular weight copolymers were obtained using stannous-2-ethyl hexanoate as catalyst in bulk. Reactivity ratios for the copolymerization of DXO and δ-VL were determined at 110°C as r_VL=0.5 and r_DXO=2.3. At high conversion, depolymerization of δ-VL occurred, resulting in lower molecular weight and variations in the copolymer composition.

Physical properties, such as crystallinity and melting temperature of the DXO-copolymers proved to be strongly dependent on the choice of comonomer and on the molar composition of the copolymers. DXO appears to be incorporated into the poly-?-caprolactone (PCL) crystals and to some extent into the poly-δ-valerolactone (PVL) crystals, resulting in a more gradual decrease in crystallinity with increasing amount of DXO.     

Secondary ion yields produced by keV atomic and polyatomic ion impacts on a self-assembled monolayer surface

A suite of keV polyatomic or 'cluster' projectiles was used to bombard unoxidized and oxidized self-assembled monolayer surfaces. Negative secondary ion yields, collected at the limit of single ion impacts, were measured and compared for both molecular and fragment ions. In contrast to targets that are orders of magnitude thicker than the penetration range of the primary ions, secondary ion yields from polyatomic projectile impacts on self-assembled monolayers show little to no enhancement when compared with monatomic projectiles at the same velocity. This unusual trend is most likely due to the structural arrangement and bonding characteristics of the monolayer molecules with the Au(111). Copyright 1999 John Wiley & Sons, Ltd.     

Fusion around the barrier for 7Li+12C

Fusion cross-sections for the ⁷Li + ¹²C reaction have been measured at energies above the Coulomb barrier by the direct detection of evaporation residues. The heavy evaporation residues with energies below 3 MeV could not be separated out from the α-particles in the spectrum and hence their contribution was estimated using statistical model calculations. The present work indicates that suppression of fusion cross-sections due to the breakup of ⁷Li may not be significant for ⁷Li + ¹²C reaction at energies around the barrier.     

Spectroscopy of Ly-α Lines at Storage Rings by Crystal Spectrometry and Absorption Edge Technique

Crystal spectrometry and absorption edge technique have the capability to overcome the gap in accuracy between experiment and theory in the strong field domain of QED. New results are presented which indicate the capacity of these methods to measure the energies of X-rays emitted by highly charged heavy ions at modern storage rings with a precision sensitive to second order corrections to the Lambshift in H-like very heavy ions. This revised version was published online in July 2006 with corrections to the Cover Date.     

X-rays from radiative electron capture of highly-charged heavy ions in an electron cooler

The x-ray spectra induced by spontaneous capture of free cooling electrons into bare and hydrogenlike heavy ions have been observed. Au⁷⁸⁺, Au⁷⁹⁺ and U⁹¹⁺ ions were stored in the storage ring ESR at velocities between 60% and 65% of the velocity of light and the x rays were measured in coincidence with stored particles having captured one electron in the electron cooler. The lines observed can be attributed to the direct transition of cooling electrons into theK shell of the projectile and to the characteristicL K transitions. The latter are mainly induced by capture into higher shells and subsequent cascade transitions. The measurements are compared to detailed calculations within the framework of presently available theories. Although the relative structure of the measured spectra is in fair agreement with the theoretical prediction, the total charge-changing rate in the electron cooler is about a factor of three smaller than expected.     

High X-ray conversion efficiency with target irradiation by a frequency tripled Nd : Glass laser

High conversion efficiency of laser energy into X-rays from a laser irradiated target is of great interest for a variety of dynamical (pulsed) studies, e.g.: radiography of laser-imploded targets, structure determination by diffraction and absorption fine-structure, and X-ray laser pumping. We report here on a frequency tripled Nd : glass laser used to irradiate targets of various materials at ～5 x 10¹⁴W/cm². We find conversion efficiencies of between 1% and 0.1% (with respect to the incident laser energy) for individual X-ray lines between 1.8 and 7.8 keV. These efficiencies are more than an order of magnitude higher than whose achieved with 1.06 μm lasers.     

Energy shifts versus projectile Z for Ti Kα X ray and satellites

A high resolution study of Ti Kα X-ray spectra versus projectile Z has been performed. Energy shifts and width changes were observed in both the diagram and satellite lines. These effects are explained as multiple ionization of the M shell.