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Kinetics investigations for holographic Bragg gratingbased on polymer dispersed liquid crystal 下载免费PDF全文
This paper investigates the monomer kinetics of polymer dispersed
liquid crystal (PDLC) grating. Fourier transform infrared (FTIR)
spectra are used in the studies of photoreaction kinetics. The
results indicate that there is a relative stable stage arises after
a very short initial stage. Based on FTIR studies, the monomer
diffusion equation is deduced and necessary numerical simulations
are carried out to analyse the monomer conversion which is an
important point to improve phase separation structure of PDLC
grating. Some simulation results have a good agreement with
experimental data. In addition, the effects induced by monomer
diffusion constant $D$ and diffusion--polymerization-ratio rate $R$
are discussed. Results show that monomer conversion can be improved
by increasing value of $D$. Besides, a good equilibrium state
($R=1$) is more beneficial to the diffusion of monomer which is
important in the process of phase separation. 相似文献
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