Tri-hexagonal charge order in kagome metal CsV3Sb5 revealed by 121Sb nuclear quadrupole resonance

We report ¹²¹Sb nuclear quadrupole resonance(NQR)measurements on kagome superconductor CsV₃Sb₅ with Tc=2.5 K.¹²¹Sb NQR spectra split after a charge density wave(CDW)transition at 94 K,which demonstrates a commensurate CDW state.The coexistence of the high temperature phase and the CDW phase between 91 K and 94 K manifests that it is a first order phase transition.The CDW order exhibits tri-hexagonal deformation with a lateral shift between the adjacent kagome layers,which is consistent with 2×2×2 superlattice modulation.The superconducting state coexists with CDW order and shows a conventional s-wave behavior in the bulk state.