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在不同频率和偏置电场下测量了BaTiO3晶体从三方相到正交相再到四方相相变过程中的介电温谱.基于BaTiO3晶体在电场作用下的偶极子偏转假设和介电特性实验结果,提出BaTiO3各结构相在电场作用下的偶极子偏转路径可以由其相邻相的介电常数随温度的变化特性表现出来.推断出各结构相的偶极子偏转路径,以及偏置电场对偶极子偏转路径的影响.
关键词:
3晶体')" href="#">BaTiO3晶体
介电特性
结构相变
偶极子偏转路径 相似文献
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CuO added Pb_(0.92)Sr_(0.06)Ba_(0.02)(Mg_(1/3)Nb_(2/3))_(0.25)(Ti_(0.53)Zr_(0.47))_(0.75)O_3 ceramics sintered with Ag electrodes at 900℃ for multilayer piezoelectric actuator 下载免费PDF全文
CuO added Pb_(0.92)Sr_(0.06)Ba_(0.02)(Mg_(1/3)Nb_(2/3))_(0.25)(Ti_(0.53)Zr_(0.47))_(0.75)O_3 ceramics were studied to prepare high-quality multilayer piezoelectric actuators with pure Ag electrodes at 900℃. Cu O addition not only reduced the sintering temperature significantly from 1260℃ to 900℃ but also improved the ceramic density to 7.742 g/cm~3. The 0.7 wt.% Cu O added ceramic sintered at 900℃ shows the remnant polarization(P_r) of 40 μC/cm~2, 0.28% strain at 40 kV/cm, and the piezoelectric coefficient(d_(33)) of 630 pC/N. This ceramic shows a strong relaxor characteristic with a Curie temperature of 200℃. Furthermore, the 0.7 wt.% CuO added ceramic and pure Ag electrodes were co-fired at 900℃ to prepare a high-quality multilayer piezoelectric actuator with a d_(33) of over 450 pC/N per ceramic layer. 相似文献
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Optical Dispersion Behavior and Band Gap Energy of Relaxor Ferroelectric 0.92Pb(Mgl/3Nb2/3)O3-0.08PbTiO3 Single Crystal 下载免费PDF全文
Refractive indices and extinction coefficients of O.92Pb(Mgl/3Nb2/3)O3-O.O8PbTiO~(PMN-O.OSPT) single crystaJ are investigated by variable angle spectroscopic ellipsometry (VASE) at different wavelengths. The parameters relative to the energy band structure are obtained by fitting to the single-oscillator dispersion equation, and the band gap energy is also deduced from the Tauc equation. Similar to most oxygen-octahedra ferroelectries, PMN-O.OSPT has the same dispersion behavior described by the refractive-index dispersion parameters. 相似文献
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