FAR-INFRARED AND INFRARED REFLECTIONS OF Tl2Ba2Ca2Cu3O10 FILM

The far-infrared and infrared reflection spectra of Tl₂Ba₂Ca₂Cu₃O₁₀ superconducting film are reported in this paper. It is found there are three sharp reflection edges in both the superconducting and normal states, their positions being near ≈ 150, ≈ 350 and ≈600 cm^-1. We attribute these reflection spectra to the Drude free carriers and a wide mid-infrared absorption band. When the incident angle increases from 7° to 30°, some additional stractures appear in the refiection spectra, which are the A_2u phonon modes vibrating along c-axis.     

高温超导体的红外光谱研究

本文首次报道高温超导体的各向异性在其红外光谱中的表现行为,并在理论上进行了系统描述.通过对Y系单晶薄膜、Y系空气淬火系列样品及掺Pr的Y系样品的红外光谱研究,对Y系高温超导体的红外声子振动模进行了系统指认,并着重指出,CuO₂面内晶格振动模与超导电性存在密切关系,还讨论了这些振动对高温超导电性的作用.     

晶格振动、载流子与高温超导电性的关系

系统地从红外光谱的结果论述了晶格振动、载流子与高温超导电性的关系。指出,在高温超导体中,载流子对晶格振动的作用不是屏蔽作用,而是两者之间的局域强耦合相互作用,这种局域的耦合不同于普通的电声子耦合。在此基础上,通过理论和实验研究,论述了局域耦合强度及其整体效应与超导电性的关系。 关键词：     

掺Pr的Y-Ba-Cu-O体系超导体的红外光谱研究

本文报道了对Pr_xY_1-xBa₂Cu₃O_7-δ体系超导体红外光谱研究的结果。发现在整个光谱范围内(中红外和远红外),Pr含量增加的直接结果是大部分反射峰的强度增强。在远红外区,Y原子的“指纹”性声子190cm^-1峰的频率位置与Pr含量无关,证明了Pr在该体系中价态要比Y的+3价高,介于+3价与+4价之间。通过对各个声子结构的指认,我们发现:随Pr含量增高,声子活性增强的振动模必定是属于CuO₂面内的或与CuO₂平面平行的振动模,与YBa₂Cu₃O_7-δ体系中减少氧的情况类似。这意味着CuO₂面内的振动对于高温超导性的重要作用。 关键词：     

高温超导氧化物中非平衡载流子的能量弛豫与电声相互作用

利用超导体中非平衡能量平衡模型,研究室温下YBa₂Cu₃O_7-δ(δ=0.1,0.4,0.8)和PrBa₂Cu₃O₇外延膜中光激活非平衡载流子的弛豫动力学,计算了电声耦合常数λ发现随着氧含量的降低及用Pr替代Y,Cu-O面上空穴Fermi面向Cud⁹/d¹⁰带方向移动,非平衡载流子的驰豫时问增加而电声耦合常数明显减小.这一结果与瞬态反射谱测量结果符合得很好.这表明载流子浓度的降低减弱了电声相互作用,而这种作用可能是一种实空间的局域相互作用.     

FAR-INFRARED AND INFRARED REFLECTIONS OF Tl2Ba2Ca2Cu3O10 FILM

The far-infrared and infrared reflection spectra of Tl₂Ba₂Ca₂Cu₃O₁₀ superconducting film are reported in this paper. It is found there are three sharp reflection edges in both the superconducting and normal states, their positions being near ≈ 150, ≈ 350 and ≈600 cm^-1. We attribute these reflection spectra to the Drude free carriers and a wide mid-infrared absorption band. When the incident angle increases from 7° to 30°, some additional stractures appear in the refiection spectra, which are the A_2u phonon modes vibrating along c-axis.