全文获取类型
收费全文 | 15565篇 |
免费 | 3021篇 |
国内免费 | 2943篇 |
专业分类
化学 | 12484篇 |
晶体学 | 241篇 |
力学 | 729篇 |
综合类 | 342篇 |
数学 | 1783篇 |
物理学 | 5950篇 |
出版年
2024年 | 33篇 |
2023年 | 265篇 |
2022年 | 375篇 |
2021年 | 482篇 |
2020年 | 622篇 |
2019年 | 657篇 |
2018年 | 544篇 |
2017年 | 534篇 |
2016年 | 796篇 |
2015年 | 865篇 |
2014年 | 901篇 |
2013年 | 1251篇 |
2012年 | 1361篇 |
2011年 | 1471篇 |
2010年 | 1071篇 |
2009年 | 1102篇 |
2008年 | 1173篇 |
2007年 | 1026篇 |
2006年 | 1044篇 |
2005年 | 941篇 |
2004年 | 725篇 |
2003年 | 643篇 |
2002年 | 667篇 |
2001年 | 536篇 |
2000年 | 500篇 |
1999年 | 357篇 |
1998年 | 222篇 |
1997年 | 202篇 |
1996年 | 198篇 |
1995年 | 165篇 |
1994年 | 147篇 |
1993年 | 120篇 |
1992年 | 100篇 |
1991年 | 73篇 |
1990年 | 56篇 |
1989年 | 56篇 |
1988年 | 41篇 |
1987年 | 43篇 |
1986年 | 36篇 |
1985年 | 27篇 |
1984年 | 14篇 |
1983年 | 14篇 |
1982年 | 11篇 |
1981年 | 11篇 |
1980年 | 7篇 |
1979年 | 6篇 |
1974年 | 4篇 |
1973年 | 5篇 |
1965年 | 4篇 |
1957年 | 5篇 |
排序方式: 共有10000条查询结果,搜索用时 78 毫秒
1.
2.
为提高煤与瓦斯突出矿井瓦斯抽放效果,建立了3个一级指标、14个二级指标的突出矿井瓦斯抽放限制影响因素评价指标体系,利用AHP和熵权法分别确定指标因子主、客观权重.通过实地调研分析和反馈验证了AHP-熵权法的可行性和正确性,利用加权平均法确定评价模型的综合权重.研究表明:封孔方式、钻孔半径、抽放时间、煤体裂隙发育程度和抽放负压是目前影响煤矿瓦斯抽放效果的主控因素. 相似文献
3.
The Ramanujan Journal - We calculate the dimensions of the spaces of invariant vectors under the Klingen congruence subgroup of level $${\mathfrak {p}}^2$$ for all irreducible, admissible... 相似文献
4.
5.
Nonlinear Dynamics - With an increasing number of people sharing feelings and opinions online, the online platforms have become one of the most important channels for public opinion dissemination.... 相似文献
6.
Yi Han Zibo Xue Dr. Guangwu Li Dr. Yanwei Gu Dr. Yong Ni Dr. Shaoqiang Dong Prof. Chunyan Chi 《Angewandte Chemie (Weinheim an der Bergstrasse, Germany)》2020,132(23):9111-9116
Incorporation of a non-hexagonal ring into a nanographene framework can lead to new electronic properties. During the attempted synthesis of naphthalene-bridged double [6]helicene and heptagon-containing nanographene by the Scholl reaction, an unexpected azulene-embedded nanographene and its triflyloxylated product were obtained, as confirmed by X-ray crystallographic analysis and 2D NMR spectroscopy. A 5/7/7/5 ring-fused substructure containing two formal azulene units is formed, but only one of them shows an azulene-like electronic structure. The formation of this unique structure is explained by arenium ion mediated 1,2-phenyl migration and a naphthalene to azulene rearrangement reaction according to an in-silico study. This report represents the first experimental example of the thermodynamically unfavorable naphthalene to azulene rearrangement and may lead to new azulene-based molecular materials. 相似文献
7.
Dendrite formation is a major obstacle, e.g., capacity loss and short circuit, to the next-generation high-energy-density lithium (Li)-metal batteries. The development of successful Li dendrite mitigation strategies is impeded by an insufficient understanding in Li dendrite growth mechanisms. The Li-plating-induced internal stress in Li-metal and its effects on dendrite growth have been widely studied, but the underlying microcosmic mechanism is elusive. In the present study, the role of the plating-induced stress in dendrite formation is analyzed through first-principles calculations and ab initio molecular dynamic (AIMD) simulations. It is shown that the deposited Li forms a stable atomic nanofilm structure on the copper (Cu) substrate, and the adsorption energy of Li atoms increases from the Li-Cu interface to the deposited Li surface, leading to more aggregated Li atoms at the interface. Compared with the pristine Li-metal, the deposited Li in the early stage becomes compacted and suffers the in-plane compressive stress. Interestingly, there is a giant strain gradient distribution from the Li-Cu interface to the deposited Li surface, making the deposited atoms adjacent to the Cu surface tend to press upwards with perturbation and causing the dendrite growth. This provides an insight into the atomicscale origin of Li dendrite growth, and may be useful for suppressing the Li dendrite in Li-metal-based rechargeable batteries. 相似文献
8.
以4-羟基吲哚为原料,经吲哚环4位乙酰基化、3位亲电取代、酰胺化和还原加氢等反应合成目标化合物7.通过核磁共振氢谱及碳谱对化合物进行结构表征,并对目标化合物进行体外抗氧化生物活性测试.初步生物活性测试结果表明,化合物7a,7b,7c和7d对DPPH·均有很强的清除作用(清除率为85.25%~90.73%),7e,7f,7g,7h作用较差;目标化合物与Vc相比,对·OH的清除作用稍差,最高清除率25.66%(Vc的最高清除率为34.67),但各化合物整体水平相当;在清除O-2·能力上化合物7a,7d,7g,7h最大清除率(分别为19.34,35.35,27.93和31.74)均强于同等浓度的Vc(17.58). 相似文献
9.
In the view of substrate availability, atomic efficiency and cost, directly using arenols as coupling partners in cross‐coupling, would be one of the most attractive goals. Up to date, many efforts have been made to activate the C—O bond of phenols with different strategies, for example, through in‐situ formed intermediates, through a catalytic reductive dearomatization‐condensation‐rearomatization sequence or catalytic deoxygenation. In this review, we summarized recent advances in cross‐couplings of arenols as the electrophiles via C—O activation. 相似文献
10.
Polypyrrole Shell@3D‐Ni Metal Core Structured Electrodes for High‐Performance Supercapacitors 下载免费PDF全文
Gao‐Feng Chen Yu‐Zhi Su Pan‐Yong Kuang Zhao‐Qing Liu Dao‐Yi Chen Xu Wu Nan Li Prof. Shi‐Zhang Qiao 《Chemistry (Weinheim an der Bergstrasse, Germany)》2015,21(12):4614-4621
Three‐dimensional (3D) nanometal films serving as current collectors have attracted much interest recently owing to their promising application in high‐performance supercapacitors. In the process of the electrochemical reaction, the 3D structure can provide a short diffusion path for fast ion transport, and the highly conductive nanometal may serve as a backbone for facile electron transfer. In this work, a novel polypyrrole (PPy) shell@3D‐Ni‐core composite is developed to enhance the electrochemical performance of conventional PPy. With the introduction of a Ni metal core, the as‐prepared material exhibits a high specific capacitance (726 F g?1 at a charge/discharge rate of 1 A g?1), good rate capability (a decay of 33 % in Csp with charge/discharge rates increasing from 1 to 20 A g?1), and high cycle stability (only a small decrease of 4.2 % in Csp after 1000 cycles at a scan rate of 100 mV s?1). Furthermore, an aqueous symmetric supercapacitor device is fabricated by using the as‐prepared composite as electrodes; the device demonstrates a high energy density (≈21.2 Wh kg?1) and superior long‐term cycle ability (only 4.4 % and 18.6 % loss in Csp after 2000 and 5000 cycles, respectively). 相似文献