Selective Determination of Nanogram γ-Globulin in Human Blood Serum by Resonance Light Scattering of Functionalized Nano-PbS

Functionalized nano-PbS has been prepared and characterized. The functionalized nanoparticles have good dispersibility in water. Reaction of functionalized nano-PbS with γ-globulin (γ-IgG) results an enhanced resonance light scattering (RLS) around 385nm.However, when the content of HSA is lower than 0.5μg/ml^-1 the RLS enhancement is very weak and is nonlinear to concentration of HSA. Based on these results, a new direct quantitative determination method for γ-globulin in blood serum samples without separation is established.Under optimal conditions, the enhanced RLS intensity is in proportion to the γ-IgG concentration in the range 10-500ng/mL. The limit of detection is 2.75ng/mL. This method is proved to be very sensitive, rapid, simple and selective for detection of γ-IgG in blood serum.     

THE INTERIOR LAYER SOLUTION TO NONLOCAL REACTION DIFFUSION EQUATIONS

An initial boundary value problem of semilinear nonlocal reaction diffusion equations is considered.Under some suitable conditions,using the asymptotic theory,the existence and asymptotic behavior of the interior layer solution to the initial boundary value problem are studied.     

Prediction of Decomposition Temperature for Lanthanide Complexes Involving Cyclopentadienyl and Benzohydroxamic Acid Ligand by ANNs

The decomposition temperatures of the lanthanide organic complexes(η^5-C5H5)2Ln(C6H5CONHO)involving cyclopentadienyl and benzohydroxamic acid ligands were calculated and predicted by the model based on ANNs(artificial neural netowrks)method.The comparison was carried out between results from ANNs method and traditinal regression method.It is proved that ANNs could be used more efficiently for the prediction of decomposition temperature of lanthanide organic complexes.     

采用光纤技术实现拉曼光谱和扫描隧道显微镜实时联用测试

设计并制作了与扫描隧道显微镜（ＳＴＭ）探头和拉曼光谱仪相适配的光纤探测装置，该装置采用配有不很短焦距的自聚焦透镜以获得较大的相对孔径，并使用多束光纤以充分利用扫描隧道显微镜探针周围有限空间，提高了拉曼散射光的收集效率，获得具有较高信噪比的拉曼谱图，在该装置的基础上进一步建立拉曼－扫描隧道显微镜联用系统，初步实验表明该联用系统用于实时研究固／气和固／液界面体系是可行的，即利用扫描隧道显微镜可获得固体     

沿齐次曲线的强奇异积分算子在调幅空间上的有界性

设Γ_θ(t)为R~n(n≥2)中的齐次曲线,定义沿齐次曲线的强奇异积分算子T_(n,α,β)f(x)=p.v.∫_(-1)~1f(x-Γ_θ(t))(e~((-2πi|t|)~(-β))/(t|t|~α))dt,α,β>0.本文讨论了上述奇异积分算子在广义调幅空间上的有界性.     

THE SINGULARLY PERTURBED NONLINEAR BOUNDARY VALUE PROBLEMS

§ 1　 IntroductionA class of singularly perturbed boundary value problems were studied by Mo[1～ 6] .Now we consider the following singularly perturbed nonlinear boundary value problem ofthe formεd2 ydx2 =f(x,y,y′) ,　 0 相似文献   

拉曼谱仪新聚光会集系统研制及用于电化学时间分辨研究的初步结果

为了进一步提高拉曼谱仪检测灵敏度,对Ｓ３０００型拉曼光谱仪的聚光会集系统进行了重新设计,新设计的聚光会集系统可以显著提高拉曼散射光的光强,理论上收集光强增大９倍。采用配制该聚光会聚系统和以光学多道分析仪（ＯＭＡ）作为信号检测器的拉曼谱仪,并采用分区间录谱方法进行了电化学现场时间分辨测量,获得了质量较高的时间分辨值为５ｍｓ的ＳＥＲＳ谱图,该时间分辨值目前尚未见报道。以Ａｇ／ＳＣＮ－为体系初步结果表明：提高检测灵敏度将有助于从分子水平研究电化学界面动态过程．     

钯微粒修饰聚苯胺电极对甲酸氧化的电催化研究

有机小分子的燃料电池具有重要的应用前景,人们对它在贵重金属上的电催化氧化进行了大量研究。Pd具有不同于其它贵重金属的特性,在甲酸氧化中表现出与其它金属不同的电催化机理。Gholamian报道了将Pt微粒修饰聚苯胺电极对甲酸氧化的电催化研究,我们发现以多聚磷酸作为支持电解质所聚合的聚苯胺(PAN)再修饰金属原子方面具有其独特之处,并且用Pt进行再修饰之后对甲酸氧化的催化活性明显高于文献[4]的报道。因此本实验选用多聚磷酸为支持电解质电聚合苯胺,然后将钯微粒嵌入沉积到PAN中,并研究其对甲酸氧化的电催化作用。     

RELATIONS BETWEEN SOLUTIONS TO STOCHASTIC DIFFERENTIAL EQUATIONS DRIVEN BY SEMIMARTINGALE WITH NON-LIPSCHITZ COEFFICIENTS

In this paper, a class of stochastic differential equations (SDEs) driven by semi-martingale with non-Lipschitz coefficients is studied. We investigate the dependence of solutions to SDEs on the initial value. To obtain a continuous version, we impose the conditions on the local characteristic of semimartingale. In this case, it gives rise to a flow of homeomorphisms if the local characteristic is compactly supported.     

光导纤维拉曼光谱技术及其在化学中的应用

本文综述了光导纤维拉曼光谱法的研究近况,主要介绍其实验技术及其应用于化学中常规拉曼光谱、表面增强拉曼光谱和近红外富里叶变换拉曼光谱等领域的工作,讨论了该领域存在问题和应用前景.