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Antonio Zecca 《International Journal of Theoretical Physics》2003,42(7):1621-1628
The superposition relation extended to the statistical operators is shown to be invariant under tensor product and partial trace operations. Particular mathematical examples of superposition are characterized as well as the nature of the Schmidt decomposition of pure states superposition of other pure states. 相似文献
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Antonio Zecca 《International Journal of Theoretical Physics》1995,34(7):1083-1091
A straightforward calculation shows that, in contrast to what happens for the Dirac equation in the Kerr metric, the net current of particles is not conserved in the case of the Dirac equation in the Tolman-Bondi and Robertson-Walker space-times. 相似文献
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Summary Global average temperatures from 1860 to 1989 were analysed with a simple fitting procedure. The temperature records can be
fitted with a rising exponential up to 1946 and with the same exponential minus an increasing cooling action from 1946 to
1989. It is shown that the results are compatible with the hypothesis of an albedo increase caused by SO2 emissions. This hypothesis gives satisfactory explanations of the temperature drop in the years 1940–1970, of the different
warming of the northern and southern hemispheres and of the slower warming observed over North America. The results give an
indication that the greenhouse warming in the next years could be faster than predicted until now.
Due to the relevance of its scientific content, this paper has been given priority by the Journal Direction. 相似文献
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DFT computational study of the mechanism of allyl halides carbonylation catalyzed by nickel tetracarbonyl 总被引:1,自引:0,他引:1
Bottoni A Miscione GP Novoa JJ Prat-Resina X 《Journal of the American Chemical Society》2003,125(34):10412-10419
A theoretical investigation at the DFT(B3LYP) level on the carbonylation reaction of allyl bromide catalyzed by nickel tetra-carbonyl Ni(CO)(4) is discussed. The computational results show the following: (i) Three main steps characterize the catalytic cycle: (a) an oxidative addition step, (b) a carbonylation step, and (c) a reductive elimination step where the acyl product is obtained and the catalyst is regenerated. (ii) Both Ni(CO)(3) and Ni(CO)(4) complexes can behave as "active" catalytic species. (iii) The oxidative addition leads to the formation of either eta(3) or eta(1)-allyl nickel complexes, which are involved in a fast equilibrium. (iv) The carbonylation occurs much more easily on the eta(1) than on the eta(3) intermediates. 相似文献
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Pietro Aiena 《Rendiconti del Circolo Matematico di Palermo》1987,36(2):194-204
Nella prima parte di questo lavoro vengono studiate le relazioni che intercorrono tra il concetto di relativa regolarità in un'algebra non necessariamente unitaria ed alcuni ideali (radicale, zoccolo, prezoccolo) che intervengono nello sviluppo della teoria di Fredholm in algebre di Banach. Nella seconda parte del lavoro viene dimostrato che in certe algebre di BanachA complesse semiprime l'esistenza di un ideale relativamente regolare chiuso implica cheA è unitaria e di dimensione finita. 相似文献
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Pierfrancesco Bravo Calimero Ticozzi Beatrice Pelli Pietro Traldi 《Journal of heterocyclic chemistry》1988,25(2):685-688
The mass spectrometric behavior of 3-methyl-3-hydroxybenzoxocines has been studied in detail by means of linked scans and mass analyzed ion kinetic energy spectrometry. The structure of the molecular ion and the fragmentation processes are strictly related to the structure of the neutral moieties. The possible isomerization of 3-hydroxy-10-methoxy-3-methyl-3,4,5,6-tetrahydro-2H-[1]benzoxocine to 2-methyl-2-[3-(3′-methoxy-2′-hydroxy)phenyl]pentyloxirane and to 2-hydroxymethyl-9-methoxy-2-methyl-2,3,4,5-tetrahydro[1]benzoxepine is investigated. 相似文献