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1.
E. Schnell W. Kiesewetter Y. H. Kim E. Hayek 《Monatshefte für Chemie / Chemical Monthly》1971,102(5):1327-1336
Zusammenfassung Die für den Einbau in die Calciumphosphate der Knochensubstanz in Frage kommenden Strontiumphosphate wurden auf ihre Existenzbedingungen untersucht. Oktacalciumphosphat tauscht in verd. Lösungen einige Prozente des Calciums gegen Strontium aus. Obwohl der Struktur nach apatitartige Strontiumphosphate zwischen Sr/P=1.33 und 1.67 erhältlich sind, läßt sich ein röntgenoptisch reines Strontiumoktaphosphat nicht isolieren, jedoch ein solches mit kleinem Carbonatgehalt und — leicht — die den Calciumsalzen analogen Strontiumphosphatcarbonate verschiedener Zusammensetzung. Im Hydrothermalbereich (375o) sind je nach relativer Zusammensetzung des Strontiumphosphat-Systems SrHPO4, Sr2P2O7, Sr2(PO4)2 und Sr5(PO4)3OH stabil und gut kristallin erhältlich. Das Salz Sr6H3(PO4)5 läßt sich aus Lösungen von Strontiumphosphaten in Kohlensäure-Wasser, H2S-Wasser und in einem Barbiturat-Puffersystem rein darstellen.
Mit 2 Abbildungen
Herrn Prof. Dr. Dr. h. c.Hans Nowotny gewidmet. 相似文献
Ortho strontium phosphates
Strontium phosphates which possibly are being incorporated into the calcium phosphates of bony tissue were investigated. Octacalcium phosphate in dilute solutions exchanges a few percent of calcium against strontium. While strontium phosphates with apatite-like structures, and with ratios of Sr/P between 1.33 and 1.67 can be prepared, no pure strontium octaphosphate, as a distinctive X-ray phase can be isolated. Only preparations with small amounts of carbonate, as well as strontium phosphate carbonates analogous to the corresponding calcium salts can be obtained. At hydrothermal conditions (375o), the compounds SrHPO4, Sr2P2O7, Sr3(PO4)2 and Sr5(PO4)3OH are stable, and can be prepared in well cristallized form, depending on the relative composition of the strontium phosphate system. The salt Sr6H3(PO4)5 can be prepared in a pure state from solutions of strontium phosphates in aqueous solutions of carbonic acid, H2S and barbiturate buffer systems.
Mit 2 Abbildungen
Herrn Prof. Dr. Dr. h. c.Hans Nowotny gewidmet. 相似文献
2.
Werner Unterberger Bernd Jenewein Bernhard Kl?tzer Simon Penner Wolfgang Reichl Günther Rupprechter Di Wang Di Wang Robert Schl?gl Konrad Hayek 《Reaction Kinetics and Catalysis Letters》2006,87(2):215-234
Summary The effect of hydrogen reduction on the structure and catalytic properties of “thin film”and “inverse”model systems for supported
metal catalysts is discussed. Thin film model catalysts were obtained by epitaxial growth of Pt and Rh nanoparticles on NaCl(001),
which were coated with amorphous or crystalline supports of alumina, silica, titania, ceria and vanadia. Structural and morphological
changes upon hydrogen reduction between 473 and 973 K were examined by high resolution electron microscopy. Metal-oxide interaction
sets in at a specific reduction temperature and is characterized by an initial “wetting”stage, followed by alloy formation
at increasing temperature, in the order VOx< TiOx< SiO2< CeOx< Al2O3. “Inverse”model systems were prepared by deposition of oxides on a metal substrate, e.g. VOx/Rh and VOx/Pd. Reduction of inverse systems at elevated temperature induces subsurface alloy formation. In contrast to common bimetallic
surfaces, the stable subsurface alloys of V/Rh and V/Pd have a purely noble metal-terminated surface, with V positioned in
near-surface layers. The uniform composition of the metallic surface layer excludes catalytic ensemble effects in favor of
ligand effects. Activity and selectivity, e.g. for CO and CO2methanation and for partial oxidation of ethene, are mainly controlled by the temperature of annealing or reduction. Reduction
above 573 K turned out to be beneficial for the catalytic activity of the subsurface alloys, but not for the corresponding
thin film systems which tend to deactivate viaparticle encapsulation.</o:p> 相似文献
3.
We consider a pricing and advertising dynamic-optimization problem where the goodwill dynamics evolve à la Nerlove–Arrow. The firm maximizes its profit over a finite-planning horizon corresponding to the product’s lifespan, and it turns out that the Hamiltonian is non-concave. We show the existence and uniqueness of an optimal solution under some mild conditions. 相似文献
4.
This paper presents the derivation of the equations for nonaxisymmetric motion of prolate spheroidal shells of constant thickness. The equations include the effect of distributed mechanical surface forces and moments. The shell theory used in this derivation includes three displacements and two thickness shear rotations. Thus, the effects of membrane, bending, shear deformation, and rotatory inertia are included in this theory. The resulting five coupled partial differential equations are self-adjoint and positive definite. The frequency-wave-number spectrum has five branches, two acoustic and three optical branches representing flexural, extensional, torsional, and two thickness shear. For the case of axisymmetric motion, these were computed for various spheroidal shell eccentricities and thickness-to-length ratios for a large number of modes. The axisymmetric dynamic response for damped shells of various eccentricities and thicknesses under point and ring surface forces are presented. 相似文献
5.
Naila Raziq Muhammad Shaiq Ali Salman Zafar Muhammad Imran Ali 《Natural product research》2015,29(24):2265-2270
Phytochemical investigations on Hypericum oblongifolium led to the isolation of a flavone named folicitin (1) and a bicyclic conjugated lactone, folenolide (2) from the ethyl acetate fraction of methanolic extract. Both metabolites were characterised as new compounds based on detailed spectroscopic analyses. In vitro anti-oxidant potential of both the compounds was evaluated by the DPPH radical scavenging assay. Compound 1 exhibited significant antioxidant activity while compound 2 was found inactive. 相似文献
6.
Rapid preparative isolation of erythrocentaurin from Enicostemma littorale by medium‐pressure liquid chromatography,its estimation by high‐pressure thin‐layer chromatography,and its α‐amylase inhibitory activity 下载免费PDF全文
Naila Hassan Javed Ahamad Saima Amin Mohd Mujeeb Showkat R. Mir 《Journal of separation science》2015,38(4):592-598
Erythrocentaurin is a relatively simple natural product present among the members of Gentianaceae. A preparative method for the isolation of erythrocentaurin from the ethyl acetate fraction of Enicostemma littorale using medium‐pressure liquid chromatography has been reported. The method consisted of a simple step gradient from 10 to 20% ethyl acetate in n‐hexane. Using a 70 × 460 mm Si60 column, this method is capable of processing 20 g of material in <3 h (purity ≈ 97%). The recovery of erythrocentaurin was 87.77%. Estimation of erythrocentaurin in extracts and fractions based on high‐pressure thin‐layer chromatography was carried out on silica gel 60 F254 plates with toluene/ethyl acetate/formic acid (80:18:2 v/v/v) as the mobile phase. The densitometric analysis was performed at 230 nm. A well‐separated compact band of erythrocentaurin appeared at Rf 0.54 ± 0.04. The analytical method showed good linearity in the concentration range of 200–1500 ng/band with a correlation coefficient of 0.99417. The limits of detection and quantification were found to be ≈60 and ≈180 ng/band, respectively. Erythrocentaurin exhibited a concentration‐dependent α‐amylase inhibition (IC50 1.67 ± 0.28 mg/mL). The outcome of the study should be considered for pharmacokinetic and biotransformation studies involving E. littorale. 相似文献
7.
S2O5F2 hat gute Lösungsfähigkeit für unpolare Substanzen. Seine Stabilität gegen Fluor ist bemerkenswert. Als Anhydrid der Fluorsulfonsäure kann man es zur Herstellung von reiner verdünnter Lösung dieser Säure benutzen. In seiner Giftwirkung ist das Disulfurylfluorid dem Phosgen ähnlich. 相似文献
8.
Ohne Zusammenfassung 相似文献
9.
Zusammenfassung Durch Umsetzung von Chloriden mit Fluorsulfonsäure im wasserfreien System wurden TiCl2(SO3F)2, ZrF3(SO3F), TaCl3(SO3F)2 und SbCl4(SO3F) neben bekannten und weniger definierten Umsetzungsprodukten erhalten. Die Reaktionsfähigkeit der Chloride, die Löslichkeit, Zusammensetzung und Bindungsverhältnisse der Reaktionsprodukte werden diskutiert. 相似文献
10.
Gabasch H Knop-Gericke A Schlögl R Penner S Jenewein B Hayek K Klötzer B 《The journal of physical chemistry. B》2006,110(23):11391-11398
The adsorption and thermal desorption of Zn and ZnO on Pd(111) was studied in the temperature range between 300 and 1300 K with TDS, LEED, and CO adsorption measurements. At temperatures below 400 K, multilayer growth of Zn metal on the Pd(111) surface takes place. At a coverage of 0.75 ML of Zn, a p(2 x 2)-3Zn LEED structure is observed. Increasing the coverage to 3 ML results in a (1 x 1) LEED pattern arising from an ordered Zn multilayer on Pd(111). Thermal desorption of the Zn multilayer state leads to two distinct Zn desorption peaks: a low-temperature desorption peak (400-650 K) arising from upper Zn layers and a second peak (800-1300 K) originating from the residual 1 ML Zn overlayer, which is more strongly bound to the Pd(111) surface and blocks CO adsorption completely. Above 650 K, this Zn adlayer diffuses into the subsurface region and the surface is depleted in Zn, as can be deduced from an increased amount of CO adsorption sites. Deposition of >3 ML of Zn at 750 K leads to the formation of a well-ordered Pd-Zn alloy exhibiting a (6 x 4 square root 3/3)rect. LEED structure. CO adsorption measurements on this surface alloy indicate a high Pd surface concentration and a strong reduction of the CO adsorption energy. Deposition of Zn at T > 373 K in 10(-6) mbar of O2 leads to the formation of an epitaxial (6 x 6) ZnO overlayer on Pd(111). Dissociative desorption of ZnO from this overlayer occurs quantitatively both with respect to Zn and O2 above 750 K, providing a reliable calibration for both ZnO, Zn, and oxygen coverage. 相似文献