全文获取类型
收费全文 | 131篇 |
免费 | 4篇 |
专业分类
化学 | 34篇 |
晶体学 | 1篇 |
力学 | 10篇 |
数学 | 72篇 |
物理学 | 18篇 |
出版年
2022年 | 1篇 |
2021年 | 1篇 |
2019年 | 3篇 |
2018年 | 2篇 |
2017年 | 3篇 |
2016年 | 6篇 |
2015年 | 3篇 |
2014年 | 7篇 |
2013年 | 13篇 |
2012年 | 11篇 |
2011年 | 11篇 |
2010年 | 10篇 |
2009年 | 12篇 |
2008年 | 7篇 |
2007年 | 5篇 |
2006年 | 3篇 |
2005年 | 6篇 |
2004年 | 2篇 |
2003年 | 3篇 |
2002年 | 2篇 |
2001年 | 3篇 |
2000年 | 7篇 |
1999年 | 2篇 |
1998年 | 2篇 |
1996年 | 2篇 |
1992年 | 1篇 |
1991年 | 3篇 |
1990年 | 1篇 |
1986年 | 1篇 |
1984年 | 1篇 |
1982年 | 1篇 |
排序方式: 共有135条查询结果,搜索用时 296 毫秒
1.
Alkaloids such as cinchonidine, quinine and N-methylephedrine have been N-alkylated using polymeric benzyl halides or co-polymerized and then N-alkylated, thus affording a series of polymer-supported chiral ammonium salts which have been employed as phase-transfer catalysts in the asymmetric benzylation of an N-(diphenylmethylene)glycine ester. These new polymeric catalysts can be easily recovered by simple filtration after the reaction and reused. The best ee's were achieved when Merrifield resin-anchored cinchonidinium ammonium salts were employed. 相似文献
2.
Offord's equation, a relationship between electrophoretic mobility and charge, size and shape of peptides, has been extended to quantitate the electrophoretic mobility of vinca alkaloids. Partly aqueous protonation constants and the derived theoretical mobilities have been proven to be able to predict experimental electrophoretic mobilities. In practice, seven vincamine derivatives of very low water-solubility were separated by capillary electrophoresis. Buffer total concentration, apparent pH and methanol content, the three most important parameters of the running buffer, were used in triangular resolution mapping to characterize separation. Even though electrophoresis is well known to slow down in partly aqueous media, under our optimized circumstances a baseline separation was achieved within 8 min in each case. 相似文献
3.
We obtain a representation for the sharp coefficient in an estimate of the modulus of the nth derivative of an analytic function in the upper half-plane
\mathbbC+ {\mathbb{C}_{+} } . It is assumed that the boundary value of the real part of the function on
?\mathbbC+ \partial {\mathbb{C}_{+} } belongs to L
p
. This representation is specified for p = 1 and p = 2. For p = ∞ and for derivatives of odd order, an explicit formula for the sharp coefficient is found. A limit relation for the sharp
coefficient in a pointwise estimate for the modulus of the n-th derivative of an analytic function in a disk is found as the point approaches the boundary circle. It is assumed that
the boundary value of the real part of the function belongs to L
p
. The relation in question contains the sharp constant from the estimate of the modulus of the n-th derivative of an analytic function in
\mathbbC+ {\mathbb{C}_{+} } . As a corollary, a limit relation for the modulus of the n-th derivative of an analytic function with the bounded real part is obtained in a domain with smooth boundary. Bibliography:
8 titles. 相似文献
4.
5.
6.
Liping Liao Bing Wu Dr. Evgeniya Kovalska Dr. Vlastimil Mazánek Dr. Martin Veselý Ivo Marek Lucie Spejchalová Prof. Dr. Zdeněk Sofer 《Chemistry (Weinheim an der Bergstrasse, Germany)》2021,27(52):13235-13241
The intercalation of cations into layered-structure electrode materials has long been studied in depth for energy storage applications. In particular, Li+-, Na+-, and K+-based cation transport in energy storage devices such as batteries and electrochemical capacitors is closely related to the capacitance behavior. We have exploited different sizes of cations from aqueous salt electrolytes intercalating into a layered Nb2CTx electrode in a supercapacitor for the first time. As a result, we have demonstrated that capacitive performance was dependent on cation intercalation behavior. The interlayer spacing expansion of the electrode material can be observed in Li2SO4, Na2SO4, and K2SO4 electrolytes with d-spacing. Additionally, our results showed that the Nb2CTx electrode exhibited higher electrochemical performance in the presence of Li2SO4 than in that of Na2SO4 and K2SO4. This is partly because the smaller-sized Li+ transports quickly and intercalates between the layers of Nb2CTx easily. Poor ion transport in the Na2SO4 electrolyte limited the electrode capacitance and presented the lowest electrochemical performance, although the cation radius follows Li+>Na+>K+. Our experimental studies provide direct evidence for the intercalation mechanism of Li+, Na+, and K+ on the 2D layered Nb2CTx electrode, which provides a new path for exploring the relationship between intercalated cations and other MXene electrodes. 相似文献
7.
8.
Repická Zuzana Moncol Jan Puchoňová Miroslava Jorík Vladimír Mikloš Dušan Lis Tadeusz Padělková Zdenka Mazúr Milan Valigura Dušan 《Structural chemistry》2010,21(5):1093-1102
Novel copper(II) X-salicylate complexes with N,N-diethylnicotinamide (dena) of the formula [Cu(RCOO)2(dena)2(H2O)2] (RCOO = 3-methylsalicylate anion (3-Mesal, 1), 4-methylsalicylate anion (4-Mesal, 2), 5-methylsalicylate anion (5-Mesal, 3), 5-methoxysalicylate anion (5-MeOsal, 4) or 4-methoxysalicylate anion (4-MeOsal, 5)), and complex [Cu(3-MeOsal)2(dena)2(H2O)2]∙2H2O (3-MeOsal = 3-methoxysalicylate anion (6)) have been prepared in the crystalline forms and characterized by spectroscopic methods (IR, Vis–UV, EPR). All the compounds
according to their composition (1–5) seem to possess octahedral copper(II) stereochemistry. The complex 1 has been prepared in two different forms. X-ray analyses of the complexes 1, 4, and 5 were carried out and they featured a tetragonal-bipyramidal geometry around the copper atoms. The tetragonal planes are created
by X-salicylate anions bonded to the copper(II) atoms via unidentate carboxylate oxygen atoms and the pyridine ring nitrogen
atoms of the neutral ligand N,N-diethylnicotinamide, while in axial positions are water molecules. The two forms of complex 1 present conformation polymorphs and supramolecular isomers. 相似文献
9.
The present paper establishes boundedness of $[m-\frac{n}{2}+\frac{1}{2} ]$ derivatives for the solutions to the polyharmonic equation of order 2m in arbitrary bounded open sets of ${\mathbb{R}}^{n}$ , 2≤n≤2m+1, without any restrictions on the geometry of the underlying domain. It is shown that this result is sharp and cannot be improved in general domains. Moreover, it is accompanied by sharp estimates on the polyharmonic Green function. 相似文献
10.
Fuensanta Andreu Vicent Caselles Jose M. Mazón Salvador Moll 《Mathematische Annalen》2010,347(1):135-199
We prove existence and uniqueness of entropy solutions for the nonhomogeneous Dirichlet problem associated to the relativistic
heat equation. 相似文献