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1.
Maurits de Graaf 《Discrete Mathematics》2004,280(1-3):219-223
We show that each directed graph (with no parallel arcs) on n vertices, each with indegree and outdegree at least n/twhere t=2.888997… contains a directed circuit of length at most 3. 相似文献
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This work is devoted to the determination of the vibrational population of hydrogen molecules in the ground and excited electronic states from the analysis of visible spectra of the H2 molecules excited by an RF discharge in an expanding thermal arc plasma. Comparison of the experimental results on relative electron-impact excitation cross sections for the transition H2(X1Σ, υ0 = 0)→ H2(d3IIu, υ′) with other experiments, and with calculations based on the Franck-Condon principle, shows good agreement. This means, that for plasma under investigation: 1) in the ground electronic state H2(d3IIu,υ′), only the lowest vibrational level with υ0 = 0 is significantly populated, and 2) direct electron exictation of H2(d3IIu, υ′, υ′) state from the ground state H2(X1Σ, υ0 = 0) dominates. 相似文献
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Age K. Smilde Piet Hein van der Graaf Durk A. Doornbos Ton Steerneman Anita Sleurink 《Analytica chimica acta》1990
When retention measurements are available for a set of solutes on different stationary phases, with varying mobile phase compositions, the resulting data set can be represented by a three-way array. Models that describe the systematic variation in this training set sufficiently, can be used to calibrate a new stationary phase. Two models are tested for this purpose: three-way partial least squares and parallel factor analysis. 相似文献
6.
The total synthesis of (±) dihydroreynosin and of (±) 1-oxocostic acid (R = H) are illustrative examples for a short entry into 1-oxygenated eudesmanes via an easily accessible key intermediate . 相似文献
7.
A number of polyfunctionalized cis-bicycio ¦3.3.0¦octanes have been synthesized starting from the tricyclic key intermediate which was obtained by the intramolecular cyclopropanation reaction of the diazo keto ester . Selected stereocontrolled transformations of using nucleophiles and electrophiles have been studied for the preparation of the title compounds. 相似文献
8.
高岭石吸附乙烯和苯的Delft分子力学研究 总被引:1,自引:0,他引:1
运用Delft分子力学(DMM)程序及其粘土和共轭烯烃力场,计算研究了高岭石对乙烯和苯的吸附作用,探讨了吸附对粘土晶体和有机分子的结构、电荷分布和能量的影响,求得了高岭石吸附乙烯和苯的吸附热等重要物理量. 相似文献
9.
Vitamin D analogues, characterized by a decalin CD-ring fragment are described. 相似文献
10.
Carbenes3a-e add to the α-side of the first double bond of dienamine2 (title compound) to give 1 : 1 adducts4a-e, Chlorofluorocarbene3e gives, in addition, ketone7, corresponding to β-addition at the second double bond of2, and a 2 : 1 adduct8. The reaction of2 with dichlorocarbene3a yields, besides4a, novel ring-expansion products5 and6 corresponding to addition of two moles of3a. Ethoxycarbonylcarbene3f reacts with the dienamine (2) to give isomeric esters9 and10a,b. The structure assignments and the mechanism of formation of the reaction products are discussed. 相似文献