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1.
Ahmed A. El-Asmy Yehia M. Shaibi Abdallah S. Babaqi Mohamed Mounir Salah A. Ashour 《Transition Metal Chemistry》1988,13(5):332-335
Summary The interaction of 1-benzoin-4-phenylthiosemicarbazone (H2 BPS) with some transition metal ions has been investigated. The ligand can function as a tridentate chelating agent, giving M(HBPS)2 and M(BPS). Potentiometric studies proved that the mechanism of chelation is based on hydrogen ion liberation. Spectral studies in solution show that the ligand could be used for the microdetermination of CuIIions. On the basis of magnetic and spectral data, an octahedral structure is proposed for the CoII and NiII complexes and a square-planar structure for the CuII complex. The corrosion inhibition of aluminium in Cl3CCO2H using H2BPS is studied. The electrical conductivity of H2BPS and of its complexes have been measured. The ligand shows an activation energy in the range of semiconducting materials. The antimicrobial activity of all compounds has also been demonstrated. 相似文献
2.
Ashour A. Ahmed Oliver Kühn Rifaat H. Hilal Mohamed F. Shibl 《International journal of quantum chemistry》2013,113(9):1394-1400
Geometry and energetics of low energy conformers of sodium dihydrogen triacetate (SDHTA) and its anion are studied using density functional theory (DFT) at the Becke, Lee‐Yang‐Parr hybrid functional (BLYP) and Becke, three‐parameter, Lee‐Yang‐Parr hybrid functional (B3LYP) levels. For both cases, two structures of comparable energy are found, which have different symmetry with respect to the two hydrogen bonds (HBs). DFT‐based Born–Oppenheimer molecular dynamics simulations are performed for SDHTA, which show that both structures are visited at room temperature conditions. The trajectory analysis further reveals that the two HBs behave anticooperative, that is, on average elongation of one HB is accompanied by a compression of the other one. This is in accord with nuclear magnetic resonance (NMR) experimental studies for a similar counter ion–dihydrogen triacetate complex. © 2012 Wiley Periodicals, Inc. 相似文献
3.
Nageh K. Allam Ahmed Abdel Nazeer Elsayed A. Ashour 《Journal of Solid State Electrochemistry》2012,16(1):353-360
One of the major challenges in material design is the achievement of reasonable operational efficiency through understanding
the factors affecting the material’s performance particularly strength and service lifetime characteristics. In this work,
the electrochemical behavior of 72Cu–28Zn α-brass alloy in Na2MoO4-containing electrolytes was investigated using potentiodynamic polarization and electrochemical frequency modulation techniques
complemented with scanning electron microscopy. Also, stress corrosion cracking behavior of the alloy under both open-circuit
potential and anodic applied potentials, using the slow strain rate technique, was evaluated. The results drawn from the different
techniques are comparable. 相似文献
4.
5.
Sheikha S. Ashour 《Journal of Saudi Chemical Society》2010,14(1):47-53
Steam-activated carbons DS2 and DS5 were prepared by gasifying 600 °C-date pits carbonization products with steam at 950 °C to burn-off = 20 and 50%, respectively. The textural properties of these carbons were determined from the nitrogen adsorption at ?196 °C. The chemistry of the carbon surface was determined from the surface pH and from neutralization of the surface carbon–oxygen groups of basic and acidic type. The kinetic and equilibrium adsorption of MB and RY on DS2 and DS5 was determined at 27 and 37 °C and at initial sorption solution pH 3–7.DS2 and DS5 have expanded surface area, large total pore volume and contain both micro and mesoporosity. They have on their surface basic and acidic groups of different strength and functionality. This enhanced the sorption of the cationic dye (MB) and of the anionic dye (RY). The adsorption of MB and RY on DS2 and DS5 involves intraparticle diffusion and followed pseudo-second order kinetics. The adsorption isotherms were applicable to the Langmuir isotherm and high monolayer capacities for MB and RY dyes were evaluated indicating the high efficiencies of the carbons for dye adsorption. 相似文献
6.
Ahmed A. Abdel-Khalek M. M. Ali Radwa M. Ashour A. F. Abdel-Magied 《Journal of Radioanalytical and Nuclear Chemistry》2011,289(2):353-359
The activity concentration of beryllium-7 (7Be), a naturally occurring cosmogenic radionuclide produced in the upper atmosphere, was measured in plants on the Loess plateau
of China during the growing season of 2005. The 7Be mass activity concentration on July 27 ranged from 34.8 to 147.1 Bq kg−1 in herbaceous plants, from 47.6 to 116.1 Bq kg−1 in subshrubs, and from 15.7 to 56.8 Bq kg−1 in crop plants. The 7Be mass and areal activity concentrations of a mixture of herbaceous plants increased from 66.8 to 288.7 Bq kg−1 and from 0.7 to 46.5 Bq m−2, respectively, during the growing season. On an areal basis, the fraction of 7Be in plants in the soil–plant system increased from 0.4 to 8.4% during the growing season. Positive linear correlations were
found between the increases of 7Be mass and areal activity concentrations in the inter-sampling intervals and the amount of precipitation. 相似文献
7.
Ahmed Ashour Yhiya Amen Toshinori Nakagawa Yasuharu Niwa Amira Mira Koichiro Ohnuki 《Natural product research》2020,34(12):1750-1755
AbstractAn aliphatic ester of hydroxysalicylic acid (6), reported for the first time from a natural source in addition to five known compounds were isolated from the fermented Carica papaya L. preparation, a commercialized functional food. The known compounds were identified as 5-hydroxymethylfurfuraldehyde (1), trans-caffeic acid (2), butyl 4-hydroxybenzoate (butylparaben) (3), lycopene (4), benzyl isothiocyanate (5). Compounds 1 and 3 were reported for the first time from Papaya fruits through this study. The new compound showed a moderate antioxidant activity and a potent hair growth stimulating activity in vitro. 相似文献
8.
Yhiya Amen Qinchang Zhu Hai-Bang Tran Mohamed S. Afifi Ahmed F. Halim Ahmed Ashour 《Natural product research》2018,32(16):1955-1959
Rho-kinase enzymes are one of the most important targets recently identified in our bodies. Several lines of evidence indicate that these enzymes are involved in many diseases and cellular disorders. ROCK inhibitors may have clinical applications for cancer, hypertension, glaucoma, etc. Our study aims to identify the possible involvement of Rho-kinase inhibition to the multiple biological activities of adlay seeds and provide a rationale for their folkloric medicines. Hence, we evaluated Rho-kinase I and II inhibitory activity of the ethanol extract and 28 compounds derived from the seeds. A molecular docking assay was designed to estimate the binding affinity of the tested compounds with the target enzymes. The results of our study suggest a possible involvement of Rho-kinase inhibition to the multiple biological activities of the seeds. Furthermore, the results obtained with the tested compounds revealed some interesting skeletons as a scaffold for design and development of natural Rho-kinase inhibitors. 相似文献
9.
Nada M. Mostafa Mohamed L. Ashour Omayma A. Eldahshan 《Natural product research》2016,30(18):2093-2100
A novel biflavonoid [kaempferol (6→8″) apigenin] was isolated from the leaves of Jacaranda acutifolia. The structure was elucidated based on chemical evidence, 1D and 2D spectroscopic analyses as well as spectrometric techniques. The compound showed promising cytotoxic activity against breast cancer cell line MCF-7. The anticancer activity was explained via virtual docking of the isolated compound to the main sites in the human cyclin-dependent kinase2 (CDK2) crystal structure. 相似文献
10.
A. S. Ashour 《ARI - An International Journal for Physical and Engineering Sciences》1999,51(4):254-257
The wave motion in a fluid-filled fracture embedded in an anisotropic medium is investigated using the technique of partial waves. A model is derived to calculate the complex dispersion relation of the Stoneley-wave mode in a fluid layer between two infinite transversely isotropic half-spaces. The effect of the anisotropic parameters on the Stoneley-wave in the fracture is investigated. The numerical results indicate that the velocity of the Stoneley-wave mode has significant dependence on the transversely isotropic constants. For a weakly anisotropic medium, the Stoneley-wave dispersion is almost the same as in an isotropic medium. 相似文献