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The method was proposed for the preparation of composite iron-fluoropolymeric magnetic needles up to 20 mm in length by self-assembly of carbonyl iron microparticles in a solution of the LF-32L fluoroorganic varnish in a vertical magnetic field. The resistance of the generated structures toward aqueous solutions of acids increases in the series HCl—HNO3—H2SO4. The structures withstand heating to 200 °С. The dissolution of iron results in to formation of porous fluoropolymeric shells curling or retaining the linear shape after the loss of the filler. The properties of the needles and shells were studied by IR spectroscopy, scanning electron microscopy, atomic force microscopy, and optical microscopy.  相似文献   
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Russian Chemical Bulletin - A simple method for the preparation of the vertically located flexible iron—polysiloxane magnetic needles up to 12 mm long by the self-organization of iron...  相似文献   
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Crystallography Reports - The interaction of an aqueous suspension of fine-grained iron with one equivalent of (1-hydroxy-ethylidene)diphosphonic acid (H4L) leads to the formation of poorly soluble...  相似文献   
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A thin cobalt layer has been formed on the surface of p-aminobenzoic acid whiskers by chemical vapor deposition (CVD). The metallized crystals have been oriented in liquid polydimethylsiloxane rubber by applying a dc magnetic field. After vulcanization, the filler has been removed by processing in an alcohol solution of trifluoroacetic acid. The cobalt deposition on the surface of the organic compound and the properties of metallized whiskers are investigated by optical microscopy, scanning electron microscopy (SEM), and atomic force microscopy (AFM).  相似文献   
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