大孔树脂吸附法处理含苯肼工业废水的研究

以Hz-841大孔树脂为吸附剂,95%乙醇为脱附剂处理含苯肼4000~5000mg/L的工业废水,取得了理想的分离效果,苯肼吸附率>99.8%,树脂工作吸附量40~50g/L。     

Phosphorylation of graphehe oxide to improve adsorption of U(VI) from aquaeous solutions

Journal of Radioanalytical and Nuclear Chemistry - The graphene oxide (GO) was functionalized with phosphate groups and applied as an effective adsorbent for the removal of uranium from aqueous...     

PtRu bimetallic nanoparticles embedded in MOF-derived porous carbons for efficiently electrochemical sensing of uranium

Journal of Solid State Electrochemistry - PtRu bimetallic nanoparticles embedded in MOF-derived porous carbons (PtRu-PCs) were synthesized by first loading PtRu bimetallic nanoparticles into a...     

CF3SO2Na as a Bifunctional Reagent: Electrochemical Trifluoromethylation of Alkenes Accompanied by SO2 Insertion to Access Trifluoromethylated Cyclic N-Sulfonylimines

An unprecedented electrochemical trifluoromethylation/SO₂ insertion/cyclization process has been achieved in an undivided cell in an atom-economic fashion. The protocol relies on tandem cyclization of N-cyanamide alkenes by using Langlois’ reagent as a source of both CF₃ and SO₂ under direct anodically oxidative conditions, in which two C−C bonds, two C−X bonds (N−S and S−C), and two rings were formed in a single operation. This transformation enabled efficient construction of various trifluoromethylated cyclic N-sulfonylimines from readily accessible materials.     

Subspace Barzilai-Borwein Gradient Method for Large-Scale Bound Constrained Optimization

An active set subspace Barzilai-Borwein gradient algorithm for large-scale bound constrained optimization is proposed. The active sets are estimated by an identification technique. The search direction consists of two parts: some of the components are simply defined; the other components are determined by the Barzilai-Borwein gradient method. In this work, a nonmonotone line search strategy that guarantees global convergence is used. Preliminary numerical results show that the proposed method is promising, and competitive with the well-known method SPG on a subset of bound constrained problems from CUTEr collection. This work was supported by the 973 project granted 2004CB719402 and the NSF project of China granted 10471036.     

Biosorption studies of uranium (VI) on cross-linked chitosan: isotherm,kinetic and thermodynamic aspects

The cross-linked chitosan (CS) gels synthesized by using glutaraldehyde (GLA), epichlorohydrin (EC), and ethylene glycol diglycidyl ether (EGDE) as cross-linkers respectively were used to investigate the adsorption of U(VI) ions in an aqueous solution. The pure chitosan (PCS) and the cross-linked chitosan gels were characterized by FTIR and SEM analysis. The kinetic, thermodynamic adsorption and adsorption isotherms of U(VI) ions onto unmodified and modified cross-linked chitosan were studied in a batch adsorption experiments. The effect of pH, contact time and temperature on the adsorption capacity were also carried out. At the optimum pH, the maximum adsorbed amount of PCS, GLACS, ECCS and EGDECS were 483.05, 147.05, 344.83 and 67.56 mg/g, respectively. The uranium (VI) adsorption process of PCS and ECCS followed better with pseudo-second-order kinetic model, while GLACS and EGDECS followed pseudo-first-order kinetic model well. The results obtained from the equilibrium isotherms adsorption studied of U(VI) ions were analyzed in two adsorption models, namely, Langmuir and Freundlich isothms models, the results showed that the Langmuir isotherm had better conformity to the equilibrium data. The thermodynamic parameters such as enthalpy (ΔHo), entropy (ΔSo), and Gibbs free energy (ΔGo) showed that the adsorption process was both spontaneous and endothermic.     

Optical image encryption based on two beams’ interference

We proposed a method for optical image encryption on the basis of interference theory. An optical image can be produced by the interference of two beams passed two different masks. One of the masks can only modulate the phase of the beam and another can only modulate the amplitude of the beam. The encryption method is quite simple and does not need iterative algorithm. The results of simulation coincide with our method and demonstrate the feasibility of this method.     

兰州重离子加速器控制系统DSP组件设计

针对重离子加速器部分电源的控制要求,进行了分析研究,提出并实现了一种实时、高效、多功能的控制系统。该系统基于数字信号处理器（DSP）和两片现场可编程门阵列（FPGA）芯片相结合的核心处理构架,在系统后端利用PXI总线接口配合FPGA来与工控机箱中的系统控制器和其他控制组件进行大批量数据交互;系统前端利用直接数字频率合成器、模数转换器和数模转换器等器件结合DSP和FPGA中的控制算法及相应控制机制来实现对不同电源控制参数的处理和功率的输出;平台中两组光纤模块也与FPGA相配合实现对同步触发事例等实时数据的收发和调试。     

Primal and dual alternating direction algorithms for ℓ 1-ℓ 1-norm minimization problems in compressive sensing

In this paper, we propose, analyze and test primal and dual versions of the alternating direction algorithm for the sparse signal reconstruction from its major noise contained observation data. The algorithm minimizes a convex non-smooth function consisting of the sum of ? ₁-norm regularization term and ? ₁-norm data fidelity term. We minimize the corresponding augmented Lagrangian function alternatively from either primal or dual forms. Both of the resulting subproblems admit explicit solutions either by using a one-dimensional shrinkage or by an efficient Euclidean projection. The algorithm is easily implementable and it requires only two matrix-vector multiplications per-iteration. The global convergence of the proposed algorithm is established under some technical conditions. The extensions to the non-negative signal recovery problem and the weighted regularization minimization problem are also discussed and tested. Numerical results illustrate that the proposed algorithm performs better than the state-of-the-art algorithm YALL1.     

Synthesis and antifungal activity of carvacrol and thymol esters with heteroaromatic carboxylic acids

Aiming to obtain the more effective pathogen inhibitive ingredients and explore the influence of introducing different heterocyclic units to carvacrol and thymol esters, twenty ester derivatives with different heterocyclic units were synthesized. And the in vitro antifungal activity of title compounds against five plant pathogenic fungi was evaluated by mycelium growth rate method. The results showed that some carvacrol and thymol esters showed good to excellent antifungal activity, and compound 9d (4-bromo-5-isopropyl-2-methylphenyl picolinate) exhibited a broad antifungal spectrum. Preliminary study indicated that the introduction of furan, thiophene and pyridine unit could enhance the antifungal activity of carvacrol and thymol esters against Botrytis cinerea and a bromine atom on the para position of benzene moiety could enhance their antifungal activity.