Identifying several biased coins encountered by a hidden random walk

Suppose that attached to each site z ∈ ? is a coin with bias θ(z), and only finitely many of these coins have nonzero bias. Allow a simple random walker to generate observations by tossing, at each move, the coin attached to its current position. Then we can determine the biases {θ(z)}_z∈?, using only the outcomes of these coin tosses and no information about the path of the random walker, up to a shift and reflection of ?. This generalizes a result of Harris and Keane. © 2004 Wiley Periodicals, Inc. Random Struct. Alg., 2004     

The speed of biased random walk on percolation clusters

 We consider biased random walk on supercritical percolation clusters in ℤ². We show that the random walk is transient and that there are two speed regimes: If the bias is large enough, the random walk has speed zero, while if the bias is small enough, the speed of the random walk is positive. Received: 20 November 2002 / Revised version: 17 January 2003 Published online: 15 April 2003 Research supported by Microsoft Research graduate fellowship. Research partially supported by the DFG under grant SPP 1033. Research partially supported by NSF grant #DMS-0104073 and by a Miller Professorship at UC Berkeley. Mathematics Subject Classification (2000): 60K37; 60K35; 60G50 Key words or phrases: Percolation – Random walk     

One-step electrochemical synthesis of pure poly(2,5-dicyano-p-phenylenevinylene) films

In this communication we describe the electrochemical synthesis of poly(2,5-dicyano-p-phenylenevinylene) (DCNPPV) polymer films on indium tin oxide substrates. We investigate the purity, morphology, absorption and emission properties of the film. The purity was checked by infrared spectroscopy. The film formed presented spectroscopic purity equivalent to the chemically prepared PPV that was dialyzed for one week. Scanning electron microscopy of the surface revealed a grain-like morphology. The absorption and emission spectra showed absorption and emission bands at 420 nm and 575 nm, respectively, with the absorption onset at 422 nm, which corresponds to an energy gap of 2.25 eV. The electrochemical determination of the energy gap gives 2.05 eV, thus quite close to the optical energy gap at the onset of absorption. The EA and IP were determined by electrochemical measurements and are 3.46 eV and 5.51 eV, respectively.

Mécanisme de la réaction de cyclisation en milieu aqueux de carbanilates de propargyle en méthylène-4 oxazolidinones-2

The alkaline hydrolysis of propargyl 3-chlorocarbanilates was investigated kinetically using uv spectropotometry. The cyclization to 4-methoylene-2-oxazolisinones proceeds via the numcleophilic attack of the substrate anion concomitantly with that of the hydroxide ion on the triple bond. The nucleophilic attack leads directly to the heterocycle whereas the hydroxide ion attack gives rise to a ketocarbamate which is then cyclized to the oxazolidione.     

Recursive definition for elements of reality

Elements of reality are defined as in the work of Einstein, Podolsky, and Rosen. It is further assumed that the sum or product of twocommuting elements of reality also is an element of reality. An algebra contradiction ensues.Dedicated to Sir Karl Popper, on the occasion of his 90th birthday.     

Irradiated UAmO2 transmutation discs analyses: from dissolution to isotopic analyses

Journal of Radioanalytical and Nuclear Chemistry - This paper details the different steps for the isotopic determination of UAmO2 discs from analytical irradiation. MARIOS and DIAMINO irradiations...