全文获取类型
收费全文 | 1337篇 |
免费 | 52篇 |
国内免费 | 5篇 |
专业分类
化学 | 978篇 |
晶体学 | 9篇 |
力学 | 24篇 |
数学 | 146篇 |
物理学 | 237篇 |
出版年
2023年 | 11篇 |
2022年 | 8篇 |
2021年 | 37篇 |
2020年 | 34篇 |
2019年 | 43篇 |
2018年 | 21篇 |
2017年 | 15篇 |
2016年 | 37篇 |
2015年 | 40篇 |
2014年 | 41篇 |
2013年 | 83篇 |
2012年 | 74篇 |
2011年 | 108篇 |
2010年 | 46篇 |
2009年 | 53篇 |
2008年 | 76篇 |
2007年 | 71篇 |
2006年 | 74篇 |
2005年 | 80篇 |
2004年 | 55篇 |
2003年 | 42篇 |
2002年 | 51篇 |
2001年 | 23篇 |
2000年 | 20篇 |
1999年 | 15篇 |
1998年 | 9篇 |
1997年 | 10篇 |
1996年 | 8篇 |
1995年 | 11篇 |
1994年 | 12篇 |
1993年 | 11篇 |
1992年 | 7篇 |
1991年 | 14篇 |
1990年 | 9篇 |
1989年 | 5篇 |
1988年 | 6篇 |
1986年 | 13篇 |
1985年 | 11篇 |
1984年 | 18篇 |
1983年 | 11篇 |
1982年 | 8篇 |
1981年 | 10篇 |
1980年 | 7篇 |
1979年 | 9篇 |
1978年 | 9篇 |
1977年 | 8篇 |
1975年 | 6篇 |
1974年 | 5篇 |
1973年 | 4篇 |
1970年 | 4篇 |
排序方式: 共有1394条查询结果,搜索用时 15 毫秒
1.
Edward G. Sheetz Zhao Zhang Alyssa Marogil Minwei Che Dr. Maren Pink Dr. Veronica Carta Prof. Dr. Krishnan Raghavachari Prof. Dr. Amar H. Flood 《Chemistry (Weinheim an der Bergstrasse, Germany)》2022,28(60):e202201584
The recognition of boron compounds is well developed as boronic acids but untapped as organotrifluoroborate anions (R−BF3−). We are exploring the development of these and other designer anions as anion-recognition motifs by considering them as substituted versions of the parent inorganic ion. To this end, we demonstrate strong and reliable binding of organic trifluoroborates, R−BF3−, by cyanostar macrocycles that are size-complementary to the inorganic BF4− progenitors. We find that recognition is modulated by the substituent's sterics and that the affinities are retained using the common K+ salts of R−BF3− anions. 相似文献
2.
3.
Sergio Ayala‐Mar Javier Donoso‐Quezada Roberto C. Gallo‐Villanueva Victor H. Perez‐Gonzalez Jos Gonzlez‐Valdez 《Electrophoresis》2019,40(23-24):3036-3049
Exosomes are nanovesicles secreted by most cellular types that carry important biochemical compounds throughout the body with different purposes, playing a preponderant role in cellular communication. Because of their structure, physicochemical properties and stability, recent studies are focusing in their use as nanocarriers for different therapeutic compounds for the treatment of different diseases ranging from cancer to Parkinson's disease. However, current bioseparation protocols and methodologies are selected based on the final exosome application or intended use and present both advantages and disadvantages when compared among them. In this context, this review aims to present the most important technologies available for exosome isolation while discussing their advantages and disadvantages and the possibilities of being combined with other strategies. This is critical since the development of novel exosome‐based therapeutic strategies will be constrained to the effectiveness and yield of the selected downstream purification methodologies for which a thorough understanding of the available technological resources is needed. 相似文献
4.
5.
The MPEG-1 Layer 3 compression schema of audio signal, commonly known as mp3, has caused a great impact in recent years as it has reached high compression rates while conserving a high sound quality. Music and speech samples compressed at high bitrates are perceptually indistinguishable from the original samples, but very little was known about how compression acoustically affects the voice signal. A previous work with normal voices showed a high fidelity at high-bitrate compressions both in voice parameters and the amplitude-frequency spectrum. In the present work, dysphonic voices were tested through two studies. In the first study, spectrograms, long-term average spectra (LTAS), and fast Fourier transform (FFT) spectra of compressed and original samples of running speech were compared. In the second study, intensities, formant frequencies, formant bandwidths, and a multidimensional set of voice parameters were tested in a set of sustained phonations. Results showed that compression at high bitrates (96 and 128 kbps) preserved the relevant acoustic properties of the pathological voices. With compressions at lower bitrates, fidelity decreases, introducing some important alterations. Results from both works, Gonzalez and Cervera and this paper, open up the possibility of using MPEG-compression at high bitrates to store or transmit high-quality speech recordings, without altering their acoustic properties. 相似文献
6.
Jayanth R. Banavar Oscar Gonzalez John H. Maddocks Amos Maritan 《Journal of statistical physics》2003,110(1-2):35-50
Physical strands or sheets that can be modelled as curves or surfaces embedded in three dimensions are ubiquitous in nature, and are of fundamental importance in mathematics, physics, biology, and engineering. Often the physical interpretation dictates that self-avoidance should be enforced in the continuum model, i.e., finite energy configurations should not self-intersect. Current continuum models with self-avoidance frequently employ pairwise repulsive potentials, which are of necessity singular. Moreover the potentials do not have an intrinsic length scale appropriate for modelling the finite thickness of the physical systems. Here we develop a framework for modelling self-avoiding strands and sheets which avoids singularities, and which provides a way to introduce a thickness length scale. In our approach pairwise interaction potentials are replaced by many-body potentials involving three or more points, and the radii of certain associated circles or spheres. Self-interaction energies based on these many-body potentials can be used to describe the statistical mechanics of self-interacting strands and sheets of finite thickness. 相似文献
7.
A new sample business survey for agriculture, the REA survey, and a project of integration with the FADN network (RICA in
Italy) have significantly changed the production of statistical information nowadays available with reference to the agricultural
sector. On the basis of this relevant information, new economic analyses are being developed on farms’ performance, agricultural
households’ income and the Common Agricultural Policy (CAP). In this paper the authors estimate the relationship between the
levels of variables of interest and their sampling errors using models in order to improve the accessibility of the information
on estimates accuracy to the final users (agricultural analysts, policy makers).
The paper is the result of a joint research of the three authors. Sections 1–3 and 6 by Pizzoli, Sects. 4 and 5 by Rondinelli,
Sect. 7 by Filiberti, conclusions joint to the three authors. 相似文献
8.
Veronica Felli Susanna Terracini 《Calculus of Variations and Partial Differential Equations》2006,27(1):25-58
This paper deals with a class of nonlinear elliptic equations involving a critical power-nonlinearity as well as a potential featuring multiple inverse square singularities. When the poles form a symmetric structure, it is natural we wonder how the symmetry affects such mutual interaction. The present paper means to study this aspect from the point of view of the existence of solutions inheriting the same symmetry properties as the set of singularities.
Mathematics Subject Classification (2000) 35J60, 35J20, 35B33 相似文献
9.
Mathematische Annalen - 相似文献
10.
Rastislav Varga Arcady Zhukov Michail Ipatov Juan Maria Blanco Julian Gonzalez Valentina Zhukova Pavol Vojtanik 《Journal of magnetism and magnetic materials》2006
The effect of the glass coating on the single domain wall potential in amorphous glass-coated Fe-based microwire has been studied by the switching field distribution technique. The thermoactivated mechanism model is used to describe the thermally activated switching through the complex energy barrier in amorphous FeSiB microwires. Glass removal leads to the increase of the probability of the thermally activated switching pointing to the decrease of the energy barrier. 相似文献