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排序方式: 共有8281条查询结果,搜索用时 312 毫秒
1.
Hui Li Jian Liu Juan Zhao Huiting He Dr. Dabo Jiang Prof. Steven Robert Kirk Prof. Qiong Xu Dr. Xianxiang Liu Prof. Dulin Yin 《ChemistryOpen》2021,10(4):477-485
A series of tetraimidazolium salts with different anions was prepared and applied in the isomerization of β-pinene oxide. After examining the activity of different catalysts, a remarkable enhancement of the selectivity of perillyl alcohol (47 %) was obtained over [PEimi][HNO3]4 under mild reaction conditions and using DMSO as the solvent. Furthermore, noncovalent interactions between solvent molecules and the catalyst were found by FT-IR spectroscopy and confirmed by computational chemistry. The homogeneous catalyst showed excellent stability and was reused up to six times without significant loss. 相似文献
2.
Crosslinked poly(ethylene oxide) containing siloxanes fabricated through thiol‐ene photochemistry 下载免费PDF全文
Victor A. Kusuma Elliot A. Roth William P. Clafshenkel Steven S. Klara Xu Zhou Surendar R. Venna Erik Albenze David R. Luebke Meagan S. Mauter Richard R. Koepsel Alan J. Russell David Hopkinson Hunaid B. Nulwala 《Journal of polymer science. Part A, Polymer chemistry》2015,53(13):1548-1557
Homogenous amphiphilic crosslinked polymer films comprising of poly(ethylene oxide) and polysiloxane were synthesized utilizing thiol‐ene “ click ” photochemistry. A systematic variation in polymer composition was Carried out to obtain high quality films with varied amount of siloxane and poly(ethylene oxide). These films showed improved gas separation performance with high gas permeabilities with good CO2/N2 selectivity. Furthermore, the resulting films were also tested for its biocompatibility, as a carrier media which allow human adult mesenchymal stem cells to retain their capacity for osteoblastic differentiation after transplantation. The obtained crosslinked films were characterized using differential scanning calorimetry, dynamic mechanical analysis, thermogravimetric analysis, FTIR, Raman‐IR , and small angle X‐ray scattering. The synthesis ease and commercial availability of the starting materials suggests that these new crosslinked polymer networks could find applications in wide range of applications. © 2015 Wiley Periodicals, Inc. J. Polym. Sci., Part A: Polym. Chem. 2015 , 53, 1548–1557 相似文献
3.
4.
Physical aging in amorphous poly(ethylene furanoate): Enthalpic recovery,density, and oxygen transport considerations 下载免费PDF全文
Steven K. Burgess Christopher R. Mubarak Robert M. Kriegel William J. Koros 《Journal of Polymer Science.Polymer Physics》2015,53(6):389-399
The current work utilizes three separate techniques to study the physical aging process in amorphous poly(ethylene furanoate) (PEF), which is a recently introduced engineering thermoplastic with enhanced properties compared to petroleum‐sourced poly(ethylene terephthalate). Differential scanning calorimetry aging experiments were conducted at multiple aging temperatures and times, and the resultant enthalpic recovery values compared to the theoretical maximum enthalpy loss evaluated from calculations involving extrapolation of the equilibrium liquid line. Density measurements reveal densification of the matrix for the aged versus unaged samples, and provide an estimate for the reduction in free volume for the aged samples. Complementary oxygen permeation and pressure‐decay sorption experiments provide independent verification of the free volume reduction mechanism for physical aging in glassy polymers. The current work provides the first detailed aging study for PEF. © 2014 Wiley Periodicals, Inc. J. Polym. Sci., Part B: Polym. Phys. 2015 , 53, 389–399 相似文献
5.
In two dimensional electron systems with Coulomb or dipolar interactions, a direct transition, whether first or second order, from a liquid to a crystalline state is forbidden. As a result, between these phases there must be other (micro-emulsion) phases which can be viewed as a meso-scale mixture of the liquid and crystalline phases. We investigate the transport properties of these new electronic phases and present arguments that they are responsible for the various transport anomalies that have been seen in experiments on the strongly correlated 2DEG in high mobility semiconductor devices with low electron densities. 相似文献
6.
Steven D. Bull Simon W. Epstein Nadeam Mujtaba Edward D. Savory Juan A. Tamayo 《Tetrahedron》2006,62(33):7911-7925
Enolates of (S)-N,N′-bis-(p-methoxybenzyl)-3-iso-propylpiperazine-2,5-dione exhibit high levels of enantiodiscrimination in alkylations with (RS)-1-aryl-1-bromoethanes and (RS)-2-bromoesters, affording substituted diketopiperazines containing two new stereogenic centres in high de. Deprotection and hydrolysis of the resultant substituted diketopiperazines provides a route to the asymmetric synthesis of homochiral methyl 2-amino-3-aryl-butanoates and 3-methyl-aspartates in high de and ee. 相似文献
7.
Steven R. Corman 《Computational & Mathematical Organization Theory》2006,12(1):35-49
The predominant idea for using network concepts to fight terrorists centers on disabling key parts of their communication
networks. Although this counternetwork strategy is clearly a sound approach, it is vulnerable to missing, incomplete, or erroneous
information about the network. This paper describes a different and complementary application of network concepts to terrorist
organizations. It is based on activity focus networks (AFNs), which represent the complex activity system of an organization.
An activity focus is a conceptual or physical entity around which joint activity is organized. Any organization has a number
of these, which are in some cases compatible and in some cases incompatible. The set of foci and their relations of compatibility
and incompatibility define the AFN. A hypothetical AFN for a terrorist organization is specified and tested in a simulation
called AQAS. It shows that certain activity foci, and in particular one combination, have high potential as pressure points
for the activity system. The AFN approach complements the counternetwork approach by reducing the downside risk of incomplete
information about the communication network, and enhancing the effectiveness of counternetwork approaches over time.
Steven R. Corman is Professor in the Hugh Downs School of Human Communication at Arizona State University and Chair of the Organizational
Communication Division of the International Communication Association. His research interests include communication networks
and activity systems, high-resolution text and discourse analysis, and modeling and simulation of human communication systems. 相似文献
8.
Omer Ozturk Steven N. MacEachern 《Annals of the Institute of Statistical Mathematics》2004,56(4):701-720
We develop a method of randomizing units to treatments that relies on subjective judgement or on possible coarse modeling
to produce restrictions on the randomization. The procedure thus fits within the general framework of ranked set sampling.
However, instead of selecting a single unit from each set for full measurement, all units within a set are used. The units
within a set are assigned to different treatments. Such an assignment translates the positive dependence among units within
a set into a reduction in variation of contrasting features of the treatments.
A test for treatment versus control comparison, with controlled familywise error rate, is developed along with the associated
confidence intervals. The new procedure is shown to be superior to corresponding procedures based on completely randomized
or ranked set sample designs. The superiority appears both in asymptotic relative efficiency and in power for finite sample
sizes. Importantly, this test does not rely on perfect rankings; rather, the information in the data on the quality of rankings
is exploited to maintain the level of the test when rankings are imperfect. The asymptotic relative efficiency of the test
is not affected by estimation of the quality of rankings, and the finite sample performance is only mildly affected. 相似文献
9.
D. I. Naiduss W. W. Kiesewetter S. L. Dikanskaja J. Schapiro R. Meurice J. Cartiaux E. F. Posorski G. N. Murthy S. Mihaéloff A. D. Rich J. J. Vollertsen Gh. Ghimicescu G. Kotsis C. T. Townsend J. A. Esty F. C. Baselt R. Dubrisay J. Gascon E. R. Scheggia K. M. Renner E. S. Miller C. A. Mitchell A. G. Sossin und S. E. Spektor 《Fresenius' Journal of Analytical Chemistry》1939,118(1-2):48-51
Ohne Zusammenfassung 相似文献
10.
M. Missous C. Mitchell J. Sly K. T. Lai R. Gupta S. K. Haywood 《Physica E: Low-dimensional Systems and Nanostructures》2004,20(3-4):496
Highly strained quantum cascade laser (QCL) and quantum well infrared photodetector (QWIPs) structures based on InxGa(1−x)As−InyAl(1−y)As (x>0.8,y<0.3) layers have been grown by molecular beam epitaxy. Conditions of exact stoichiometric growth were used at a temperature of 420°C to produce structures that are suitable for both emission and detection in the 2–5 μm mid-infrared regime. High structural integrity, as assessed by double crystal X-ray diffraction, room temperature photoluminescence and electrical characteristics were observed. Strong room temperature intersubband absorption in highly tensile strained and strain-compensated In0.84Ga0.16As/AlAs/In0.52Al0.48As double barrier quantum wells grown on InP substrates is demonstrated. Γ–Γ intersubband transitions have been observed across a wide range of the mid-infrared spectrum (2–7 μm) in three structures of differing In0.84Ga0.16As well width (30, 45, and 80 Å). We demonstrate short-wavelength IR, intersubband operation in both detection and emission for application in QC and QWIP structures. By pushing the InGaAs–InAlAs system to its ultimate limit, we have obtained the highest band offsets that are theoretically possible in this system both for the Γ–Γ bands and the Γ–X bands, thereby opening up the way for both high power and high efficiency coupled with short-wavelength operation at room temperature. The versatility of this material system and technique in covering a wide range of the infrared spectrum is thus demonstrated. 相似文献