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SUN Wen-Hua YANG Shi-Yan WANG Han-Qing YUAN Dong-Feng HOU Zhi-Qiang CHEN Yu-QingState Key Laboratory of Structural Chemistry State Key Laboratory of Oxo Synthesis SelectiveOxidation Lanzhou Institute of Chemical Physics Chinese Academy of Sciences Lanzhou Gansu ChinaYU Kai-BeiChengdu Center of Analysis Measurement Chinese Academy of Sciences Chengdu Sichuan China 《中国化学》1994,12(2):123-128
Tris)(η 5-cyclopentadienyl-μ-carbonyl-iron)-μ3-nitrosyl cluster was obtained from the reaction of cyclopentadienyl dicarbonyliron dimer with nitrogen monoxide in xylene. The cluster was characterized by elemental analyses, IR, MS and 1H NMR. The crystal structure of [(η5-C5H5)(μ-CO)Fe]3(μ3-NO).C4H8O was determined by X-ray diffraction analysis. It crystallizes in the orthorhombic space group Pnma, a=9.053(2), 6=10.545(2), c=22.525(4) A, V=2150.3(7) A3, Z=4,Dc=1.68 g.cm-3; structure solution and refinement based on 1141 reflections with I > 3.0 (I) (MoKa, A=0.71073 A) converged at R=0.0540. The infrared absorption band at 1325 cm-1 of the μ3-NO in the cluster, which is red shifted, shows that μ3-NO is activated. 相似文献
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