全文获取类型
收费全文 | 388篇 |
免费 | 4篇 |
专业分类
化学 | 195篇 |
晶体学 | 2篇 |
力学 | 18篇 |
数学 | 81篇 |
物理学 | 96篇 |
出版年
2023年 | 3篇 |
2021年 | 12篇 |
2020年 | 9篇 |
2019年 | 3篇 |
2018年 | 7篇 |
2017年 | 4篇 |
2016年 | 16篇 |
2015年 | 12篇 |
2014年 | 8篇 |
2013年 | 25篇 |
2012年 | 16篇 |
2011年 | 21篇 |
2010年 | 9篇 |
2009年 | 10篇 |
2008年 | 8篇 |
2007年 | 21篇 |
2006年 | 24篇 |
2005年 | 17篇 |
2004年 | 17篇 |
2003年 | 16篇 |
2002年 | 12篇 |
2001年 | 10篇 |
2000年 | 14篇 |
1999年 | 4篇 |
1998年 | 5篇 |
1997年 | 2篇 |
1996年 | 11篇 |
1995年 | 5篇 |
1994年 | 4篇 |
1993年 | 2篇 |
1992年 | 5篇 |
1991年 | 3篇 |
1990年 | 3篇 |
1989年 | 5篇 |
1986年 | 2篇 |
1983年 | 5篇 |
1981年 | 5篇 |
1980年 | 2篇 |
1979年 | 3篇 |
1978年 | 3篇 |
1977年 | 5篇 |
1975年 | 2篇 |
1974年 | 3篇 |
1970年 | 2篇 |
1942年 | 2篇 |
1939年 | 1篇 |
1936年 | 1篇 |
1935年 | 1篇 |
1931年 | 1篇 |
1909年 | 1篇 |
排序方式: 共有392条查询结果,搜索用时 125 毫秒
1.
Ozonolysis of a Series of Methylated Alkenes: Reaction Rate Coefficients and Gas‐Phase Products 下载免费PDF全文
Tristan Braure Véronique Riffault Alexandre Tomas Romeo Iulian Olariu Cecilia Arsene Yuri Bedjanian Patrice Coddeville 《国际化学动力学杂志》2015,47(9):596-605
The gas‐phase ozonolysis of three methylated alkenes, i.e., trans‐2,2‐dimethyl‐3‐hexene (22dM3H), trans‐2,5‐dimethyl‐3‐hexene (25dM3H), and 4‐methyl‐1‐pentene (4M1P), has been investigated in the presence of sufficient hydroxyl radical scavenger in a laminar flow reactor at ambient temperature (296 ± 2 K) and P = 1 atm of dry air (RH ≤ 5%). Ozone levels in the reactor were monitored by an automatic analyzer. Alkene and gas‐phase product concentrations were determined via online sampling either on three‐bed adsorbent cartridges followed by thermodesorption and GC/FID‐MS analysis or on 2,4‐dinitrophenylhydrazine (DNPH) cartridges for subsequent HPLC/UV analysis. Reaction rate coefficients of (3.38 ± 0.12) × 10?17 for 22dM3H and (2.71 ± 0.26) × 10?17 for 25dM3H, both in cm3 molecule?1 s?1 units, have been obtained under pseudo–first‐order conditions. Primary carbonyl products have been identified for the three investigated alkenes, and branching ratios are reported. In the case of 4M1P ozonolysis, the yield of a Criegee intermediate was indirectly determined. Kinetics and product study results are compared to those of literature when available. This work represents the first investigation of reaction products in the ozonolysis of 22dM3H, 25dM3H, and 4M1P in a flow reactor. 相似文献
2.
In this paper we propose time-optimal convex hull algorithms for two classes of enhanced meshes. Our first algorithm computes the convex hull of an arbitrary set ofn points in the plane inO (logn) time on a mesh with multiple broadcasting of sizen×n. The second algorithm shows that the same problem can be solved inO (1) time on a reconfigurable mesh of sizen×n. Both algorithms achieve time lower bounds for their respective model of computation.This work was supported by NASA under grant NCCI-99.Additional support by the National Science Foundation under grant CCR-8909996 is gratefully acknowledged. 相似文献
3.
We report on various integration schemes of infrared microbolometers with microstrip antennas. The first integration design consists of two gold (Au) rectangular microstrip patches coupled along the radiating edges by a narrow niobium (Nb) strip. Devices using silicon oxide are compared to devices using amorphous silicon as antenna substrate. An extension of the twin-patch detector design is the microstrip dipole antenna-coupled microbolometer. Two ways of connecting the device to the contact pads via narrow dc leads are presented and compared. The contribution of the dc leads to the detector response is eliminated by directly connecting the dipole to the contact pads. The thermal isolation of the microbolometer from the silicon wafer is improved by incorporating air into the antenna dielectric substrate. This leads to higher detector responsivity and shifts the resonance towards longer antennas. The implementation of a bridge microstrip dipole antenna structure is also discussed. 相似文献
4.
The thermal decomposition of some mixed uranyl complexes with Schiff bases and DMSO, EtOH or (Ph)3PO as neutral ligand, were investigated and the corresponding activation energy, E*a, and enthalpy of dissociation, ΔHd, values were calculated.
The results obtained indicate that for the same neutral ligand, the thermal stability of the uranyl complexes is influenced by the Schiff base used; for the same Schiff base, the presence of (Ph)3PO results in a greater thermal stability of the mixed complexes than when the other two neutral ligands are present. 相似文献
5.
Treatment of 2,3-diketo-cholestane (1) with thallium triacetate in acetic acid afforded mainly 3α-carbomethoxy-A-nor-5α-cholestan-2-one (2). Under similar conditions, the 3,4-diketo steroids (3 and 4) underwent extensive rearrangement affording spiro-lactones (9 and 10), in low yields. The structural assignment of the spiro-cholestane derivative was supported by crystallographic X-ray analysis. This product was the result of A and B-ring contractions followed by acid-catalysed cyclization of an unsaturated carboxy intermediate. 相似文献
6.
Antonino Mazzaglia Domenico Garozzo Raffaello Romeo 《Journal of organometallic chemistry》2005,690(8):1978-1985
MALDI and ESI-MS have been applied to the characterization of the reaction products between the labile cis-[Pt(DMSO)2Cl2] (1) and trans-[Pt(DMSO)2Cl(CH3)] (2) complexes with the simplest poly(amidoamine) ligand (PAMAM, G = 0, 1,2-diaminoethane as core). The comparison of the mass spectra of the starting G0 and those of the metallo-dendrimers formed upon mixing of the reagents in an equimolecular ratio, and the analysis of the isotopic distribution in the ESI spectra, have revealed the formation of cationic and neutral mononuclear complexes with PAMAM as ligand, e.g., cis-[Pt(DMSO)(PAMAM)Cl]Cl or trans-(C,N)[Pt(DMSO)(PAMAM)Cl(CH3)], together with various minor components, which have been identified as derivatives from defective structures of PAMAM. The geometry of the main products has been deduced from the values of the protons coupling constants with the isotopically abundant 195Pt. The metal-to-ligand bond is restricted to the peripheral amino groups of PAMAM which shows sufficient flexibility to involve either one or two branches in the coordination bonding. 相似文献
7.
8.
Ficarra P. Ficarra R. Chimirri A. Romeo G. Tommasini S. Calabrò M. L. Costantino D. Monforte A. M. Carulli M. 《Chromatographia》1994,38(1-2):57-61
Summary Anti-HIV enantiomeric 1H, 3H-thiazolo[3, 4-a] benzimidazoles have been stereospecifically analyzed by elution on a column of cellulose tris-(4-methyl-phenylbenzoate)ester adsorbed on macroporous silica (ChiralcelR OJ).The enantiomeric resolution of the compounds examined is linked to a complex and competitive contribution of different factors. 相似文献
9.
10.
R. Ficarra M. L. Calabrò S. Tommasini D. Costantino M. Carulli S. Melardi M. R. Di Bella F. Casuscelli R. Romeo P. Ficarra 《Chromatographia》1996,43(7-8):365-368
Summary A high-performance liquid chromatographic method is reported for the resolution of the enantiomers of a series of fused -lactams (2,7-diaza-3-oxo[3.3.0]octan-6-ones) with probable anti-HIV and anticancer activity. Resolution was achieved on a Chiralcel® OD column, cellulose tris-(3,5-dimethylphenyl carbamate) adsorbed on macroporous silica gel; mixtures ofn-hexane and isopropyl alcohol in different proportions were used as the mobile phase. The analysis was studied at different temperatures. 相似文献