Characteristics investigation on heat transfer growth of sonochemically synthesized ZnO-DW based nanofluids inside square heat exchanger

Journal of Thermal Analysis and Calorimetry - In recent decades, the growth of heat transfer using nanomaterials in the conventional base fluid has caught the attention of researchers...     

The effect of rapid rotation on a vertical bridgman furnace at large Rayleigh number

In quasi-steady operation, convection currents in a Bridgmandevice, used for producing a semi-conductor crystal, createinhomogeneities that may make the crystal unusable. It has oftenbeen suggested that additional forces due to rotation or magnetismmight be efficacious in reducing the segregation of the elementsof the alloy. It has been found that, over a wide range of rotationrates, there is no improvement in performance due to rotationabout the vertical axis. However, numerical results that havebeen obtained previously (Lee & Pearlstein, J. Crys. Growth240, 2002) indicate that, when effects of centrifugal buoyancyare introduced, a substantial reduction in segregation is achieved.In the work reported here, by contrast, in which we extend previouslarge-Rayleigh-number asymptotic analysis to include centrifugalbuoyancy, we find no improvement in radial segregation, butrather increasing segregation with increasing rotation rate.     

Automated separation and measurement of radioxenon for the Comprehensive Test Ban Treaty

A fully automatic radioxenon sampler/analyzer (ARSA) has been developed and demonstrated for the collection and quantitative measurement of the four xenon radionuclides,^131mXe(11.9 d),^133mXe(2.2 d),¹³³Xe(5.2 d), and¹³⁵Xe(9.1 hr), in the atmosphere. These radionuclides are important signatures in monitoring for compliance to a Comprehensive Test Ban Treaty (CTBT). Activity ratios of these radionuclides permit source attribution. Xenon, continuously and automatically separated from the atmosphere, is automatically analyzed by electron-photon coincidence spectrometry providing a lower limit of detection of about 100 μBq/m³. The demonstrated detection limit is about 100 times better than achievable with reported laboratory-based procedures for the short-time collection intervals of interest.     

Kinetic Analysis of the Reactions between GG-Containing Oligonucleotides and Platinum Complexes. 1. Reactions of Single-Stranded Oligonucleotides with cis-[Pt(NH(3))(2)(H(2)O)(2)](2+) and [Pt(NH(3))(3)(H(2)O)](2+)

Using concentration measurements based on high performance liquid chromatography, we have investigated the kinetics of reaction between single-stranded oligonucleotides containing a d(GpG) sequence, i.e., d(GG), d(TGG), d(TTGG), and d(CTGGCTCA), and the platinum complexes cis-[Pt(NH(3))(2)(H(2)O)(2)](2+) (1) and [Pt(NH(3))(3)(H(2)O)](2+) (2). The rate constants for the substitution of one aqua ligand of platinum in 1 or 2 by each guanine of the oligonucleotides were individually measured, as well as, for 1, those for the subsequent conversion of the monoadducts to the diadduct. For the platination of d(GG) and d(TGG), the rate constants are similar for the 5'- and 3'-guanines. The longer oligonucleotides d(TTGG) and d(CTGGCTCA) are platinated slightly faster on the 5'-G than on the 3'-G. 2 shows a similar slight preference for the 5'-guanine, but it reacts by a factor of 4-10 more slowly than 1. For both complexes, the platination rate constants increase with increasing oligonucleotide length. Platination of the 5'-G by 1 is 1 order of magnitude faster on d(CTGGCTCA) than on d(GG). Concerning the chelation step giving the GG diadduct of 1, the longer the oligonucleotide, the larger is the ratio between the rates of the cyclization of the 3'- and 5'-monoadducts k(3)(')(c) and k(5)(')(c): k(3)(')(c)/k(5)(')(c) equals 1.4 for d(GG) and 3.3 for d(CTGGCTCA).     

Processes of flats induced by higher dimensional processes III

Stationary processes of k-flats in ^d can be thought of as point processes on the Grassmannian _k ^d of k-dimensional subspaces of ^d . If such a process is sampled by a (d–k+ j)-dimensional space F, it induces a process of j-flats in F. In this work we will investigate the possibility of determining the original k-process from knowledge of the intensity measures of the induced j-processes. We will see that this is impossible precisely when 1<k<d–1 and j=0,...,2[r/2]–1, where r is the rank of the manifold _k ^d . We will show how the problem is equivalent to the study of the kernel of various integral transforms, these will then be investigated using harmonic analysis on Grassmannian manifolds.The research of the first and third authors was supported in part by NSF grants DMS-9207019 and DMS-9304284. The research of the second author was supported in part by NFR contract number R-RA 4873-306 and the Swedish Academy of Sciences.     

Synthetic and mechanistic studies of the retro-Claisen rearrangement. 4. An application to the total synthesis of (+)-Laurenyne

[formula: see text] A novel asymmetric total synthesis of marine natural product (+)-Laurenyne has been achieved. The key elements of the strategy are the sequential metal ion-templated SN2' cyclization affording a highly functionalized chiral vinyl cyclobutane and a retro-Claisen rearrangement for the construction of an eight-membered ring ether.     

Beta-delayed two-proton decay of39Ti

The beta-delayed two-proton decay of theT _z =–5/2 nuclide³⁹Ti has been observed. The³⁹Sc isobaric analog state has been calculated to lie at 8.82 MeV using the measured two-proton sum energy of 4750±40 keV for its decay to the³⁷K ground state. Combining this excitation energy with a Coulomb displacement energy calculation has lowered the energy available for ground state two-proton emission of³⁹Ti from 760 to 530 keV.This work was supported by Director, Office of Energy Research, Division of Nuclear Physics of the Office of High Energy and Nuclear Physics of the U.S. Depeartment of Energy under Contracts DE-AC03-76SF00098 with Lawrence Berkeley Laboratory, DE-AC02-76CH00016 with Brookhaven National Laboratory and DE-AC06-76RL0 1830 with Pacific Northwest Laboratories.     

Wind-generated ambient noise in a topographically isolated basin: a pre-industrial era proxy

During the mid-1980s, calibrated measurements of ambient noise and wind speed were made in the Tongue of the Ocean in the Bahamas to quantify the spectra and statistics of wind-generated noise. This deep basin is topographically isolated from the Atlantic Ocean and, therefore, largely acoustically decoupled from the Atlantic Ocean deep sound channel. The quantitative effects of contaminating (non-surface wind-generated) noise sources within the basin were eliminated by careful measurement and robust statistical analysis methodologies. Above 500 Hz, the spectral slopes are approximately -5 dB per octave and independent of wind speed. Below 500 Hz, the ambient noise is no longer a linear function of wind speed. Below 100 Hz and for wind speeds greater than 18.5 knots (kt), the ambient noise is independent of frequency. The minimum observed ambient noise level falls 13 dB below Urick's "light shipping" level at 30 Hz and 2-5 dB below Wenz's sea state zero level through the wind-dominated portion of the spectrum. The basin's geographical isolation and the rigorous measurement and analysis methodologies employed make this two-decade-old data set a reasonable and justified proxy for pre-industrial era ocean noise levels in the 20 Hz to 20 kHz frequency band.