Martensite Transformation in Nanoparticles and Nanomaterials

Journal of Nanoparticle Research - It was shown that the thermoelastic martensite transformation B2 ? B19 inside nanoparticles surrounded by amorphous matrix in Ni–Ti–Cu alloys as...     

Convexity Bias in the Pricing of Eurodollar Swaps

The traditional use of LIBOR futures prices to obtain surrogates for the Eurodollar forward rates is proved to yield a systematic bias in the pricing of Eurodollar swaps when one assumes that the yield curve is well described by the Heath-Jarrow-Morton model. The resulting theoretical inequality is consistent with the empirical observations of Burghardt and Hoskins (1995), and it provide a theoretical basis for price anomalies that are suggested by more recent empirical data.     

Simulation of operation modes of a centrifugal conductive magnetohydrodynamic pump

A mathematical model of a centrifugal conductive magnetohydrodynamic (MHD) pump that calculates the distributions of velocity, current density, and pressure along the channel is developed. The viscous forces in the original system of MHD equations are taken into account on the basis of the known square law of the drag for a turbulent flow in a pipe, generalized for the case of plane flows in a channel. Dependences of the drag coefficient on the main governing parameters (metal flow rate, current intensity, and intensity of magnetic induction), which provide the agreement of the calculated and experimental data on the pressure at the pump outlet for different operation modes, are obtained. It is shown that these dependences have a universal character and the proposed model can be used to design pumps of this type and to manage their operation in production industry.     

Intermolecular interactions between natural humic substances and tricyclic antidepressants

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Immunomodulatory properties of silver-containing nanocomposite on the basis of polyvinyltriazole

Russian Chemical Bulletin - The water-soluble nanocomposite with the uniform distribution of silver nanoparticles in polymer matrix was synthesized on the basis of poly-1-vinyl-1,2,4-triazole....     

Photochemistry of iron(iii)-lactic acid complex in aqueous solutions

Photochemistry of a 1: 1 Fe^III-lactic acid complex, [Fe(Lact)]⁺, in aqueous solutions was studied by stationary photolysis, nanosecond laser flash photolysis (355 nm, 6 ns), and femtosecond pump-probe spectroscopy (400 nm, 200 fs). The quantum yield of photolysis of [Fe(Lact)]⁺ upon excitation at 355 nm is 0.4 and 0.22 in the deoxygenated and air-saturated solutions, respectively. Weak transient absorption in the range 500–750 nm was observed in the nanosecond experiments. It was assigned to a [Fe^II...-O-CH(Me)-COO^·]⁺ radical complex. The spectral properties of the ligand-to-metal charge transfer excited state and the characteristic time of formation of the radical complex (1.5 ps) were determined in the femtosecond spectroscopy experiments. A reaction mechanism was proposed, which involves inner-sphere electron transfer in the excited complex with the formation of a radical complex [Fe^II...-O-CH(Me)-COO^·]⁺ and its subsequent transformation to the end product of the photochemical reaction.