The microstructure and optical transmittance thermal analysis of sodium borosilicate bio-glasses

The conditions to fabricate the bulk porous specimens have been studied on account of sodium borosilicate (NBS) glasses. Glass composition, heat treatment at phase separation and TiO₂ addition have been considered in this study. Original glass samples of composition in mol%: sample A: 9.19 Na₂O - 23.58 B₂O₃ - 67.23 SiO₂, sample B: 9.29 Na₂O - 3.17 TiO₂ - 23.82 B₂O₃ - 63.72 SiO₂ were prepared by melting reagent grade chemicals (Na₂CO₃, HBO₃, SiO₂ and AgNO₃) in platinum crucibles at 1480°C for 1 h in air. The melts were poured onto stainless steel plates and were annealed at 500°C for 0.5 h after cooling. Thus, obtained samples were phase separated at 700°C for 2, 15, 25 and 50 h to study their microstructure by scanning electron microscope (SEM). Besides the direct study of the microstructure by SEM, information on glass structural changes of samples are provided by measuring in situ changes by the optical transmittance thermal analysis. The isothermal measurements were carried out at 700, 720 and 740°C. The temperature of phase separation, the leaching and nucleator addition (TiO₂), significantly influence the microstructure of the resulting leached product. TiO₂ additive seems to suppress crystallization of cristobalite: especially at the extended above heat treatment phase separation runs. The phase-separated domains of glasses containing above 80 moles of SiO₂ are so small that it is very hard to observe them by SEM. The glass composition in our case was selected in a way to have relatively large phase separated areas easily observed by SEM at magnification 20 000·. The influence of TiO₂ is not too pronounced. It seems to suppress the cristobalite crystallization, especially of longer heating runs. The image analysis of leached glasses shows the prevailing content of the skeletal phase in a comparison to pores. The TiO₂ content diminishes the content of the skeletal phase. This revised version was published online in July 2006 with corrections to the Cover Date.     

Collisionless Plasma Processes at Magnetospheric Boundaries: Role of Strong Nonlinear Wave Interactions

JETP Letters - The sunward Poynting flux throughout the magnetosheath and foreshock (directly measured by INERBALL-1, CLUSTER-4, and DOUBLE STAR TC1) and its correlation and bi-correlation with the...     

Turbulent boundary layer at the border of geomagnetic trap

A new phenomenon was discovered on the basis of analysis of the Interball project data. A hot plasma flow is thermalized through the formation of “long-operating” vortex streets and local discontinuities and solitons in a distributed region over polar cusps. Plasma percolation through the structured boundary and secondary reconnection of fluctuating magnetic fields in a high-latitude turbulent boundary layer account for the main part of solar wind plasma inflow into the magnetospheric trap. Unlike local shocks, the ion thermalization is accompanied by the generation of coherent Alfvén waves on the scales ranging from ion gyroradius to the radius of curvature of the averaged magnetic field, as well as by the generation of diamagnetic bubbles with a demagnetized heated plasma inside. This “boiling” plasma has a frequency region where the spectrum is different from the Kolmogorov law (with slopes 1.2 and 2.4 instead of 5/3 or 3/2). The fluctuation self-organization in the boundary layer (synchronization of three-wave decays) was observed on certain frequency scales.     

Selenium status of South Bohemia seniors characterized by INAA of blood serum

To estimate the status of selenium in seniors of the South Bohemia region, Czech Republic, 481 serum samples from seniors living in 17 Asylum Houses for seniors in the age between 60 and 99 years were obtained. Samples were analyzed by instrumental neutron activation analysis with concurrent analysis of 4 reference materials for quality assurance. Average concentration of serum Se, arithmetic means in individual Asylum Houses, frequency distribution of serum Se concentrations as well as five years running monitoring of serum Se concentrations of one group of seniors proved selenium deficiency of the elderly population of the region South Bohemia.     

On nonlinear cascades and resonances in the outer magnetosphere

The paper addresses nonlinear phenomena that control the interaction between plasma flow (solar wind) and magnetic barrier (magnetosphere). For the first time we demonstrate that the dominant solar wind kinetic energy: (i) excites boundary resonances and their harmonics which modulate plasma jets under the bow shock; (ii) produces discrete three-wave cascades, which could merge into a turbulent-like one; (iii) jet produced cascades provide the effective anomalous plasma transport inside and out of the magnetosphere; (iv) intermittency and multifractality characteristics for the statistic properties of jets result in a super-ballistic turbulent transport regime. Our results could be considered as suggestive for the space weather predictions, for turbulent cascades in different media and for the laboratory plasma confinement (e.g., for fusion devices).     

Effect of selenium supplementation on thyroid antibodies

Selenium is an essential component of selenoproteins, enzymes with extensive regulatory and protective effect in organism. Immunological effects of Se are documented and are distinct even above concentrations necessary for maximal activity of selenoenzymes. Therefore, we investigated effect of supplementation by 100 μg of yeast-bound Se on concentrations of thyroid autoantibodies TPOAb and TgAb in the group of 253 seniors living in the Asylum Houses of South Bohemia. Increase of serum selenium from 59 to 150 μg Se/L serum in supplemented group and from 59 to 72 μg Se/L serum in group with placebo were detected by Instrumental Neutron Activation Analysis (INAA) and proved increased Se intake during the trial. Autoantibodies were analyzed by ELISA at the beginning of the trial and after 1 year. Statistical evaluation of results in whole groups (regardless of increased autoantibodies) by ANOVA manifested significant decrease of TPOAb and TgAb in non-supplemented group while supplementation did not effect serum autoantibodies concentrations. Evaluation of groups of seniors created from those with increased autoantibodies, ANOVA demonstrated decrease of TPOAb in both groups but Se supplementation did not affect the decrease. In opposite, TgAb increased significantly and Se supplementation led to higher increase of TgAb. Recent results of possibility to decrease serum concentration of TPOAb proved this effect only for high TPOAb concentrations and for higher Se supplements. From this point of view, it is necessary to conduct subsequent trials with the patients with autoimmune thyreoiditis with different levels of autoantibodies and detect also serum Se levels.     

High energy jets in the Earth’s magnetosheath: Implications for plasma dynamics and anomalous transport

High energy density jets in the magnetosheath near the Earth magnetopause were observed by Interball-1 [1]. In this paper, we continue the investigation of this important physical phenomenon. New data provided by Cluster show that the magnetosheath kinetic energy density during more than one hour exhibits an average level and a series of peaks far exceeding the kinetic energy density in the undisturbed solar wind. This is a surprising finding because the kinetic energy of the upstream solar wind in equilibrium should be significantly diminished downstream in the magnetosheath due to plasma braking and thermalization at the bow shock. We suggest resolving the energy conservation problem by the fact that the nonequilibrium jets appear to be locally superimposed on the background equilibrium magnetosheath, and, thus, the energy balance should be settled globally on the spatial scales of the entire dayside magnetosheath. We show that both the Cluster and Interball jets are accompanied by plasma superdiffusion and suggest that they are important for the energy dissipation and plasma transport. The character of the jet-related turbulence strongly differs from that of known standard cascade models. We infer that these jets may represent the phenomenon of the general physical occurrence observed in other natural systems, such as heliosphere, astrophysical, and fusion plasmas [2–10]. The text was submitted by the authors in English.