Multi-Interactions in Ionic Liquids for Natural Product Extraction

Natural products with a variety of pharmacological effects are important sources for commercial drugs, and it is very crucial to develop effective techniques to selectively extract and isolate bioactive natural components from the plants against the background of sustainable development. Ionic liquids (ILs) are a kind of designable material with unique physicochemical properties, including good thermal stability, negligible vapor pressure, good solvation ability, etc. ILs have already been used in pharmaceuticals for extraction, purification, drug delivery, etc. It has been reported that multi-interactions, like hydrogen bonding, hydrophobic interactions, play important roles in the extraction of bioactive components from the plants. In this review, recent progress in the understanding of scientific essence of hydrogen bonding, the special interaction, in ILs was summarized. The extraction of various natural products, one important area in pharmaceutical, by conventional and functional ILs as well as the specific roles of multi-interactions in this process were also reviewed. Moreover, problems existing in bioactive compound extraction by ILs and the future developing trends of this area are given, which might be helpful for scientists, especially beginners, in this field.     

Two cubane-like [M4O4] {M = nickel(II), cobalt(II)} complexes: syntheses,crystal structures and magnetic properties

Transition Metal Chemistry - Two cubane-like complexes, namely [Ni4L4(HOEt)4] (1), [Co4L4(HOEt)4] (2) (H2L?=?(E)-2-((3-hydroxypropylimino)methyl)-6-methoxyphenol), were prepared under...     

自旋-轨道耦合系统中的自旋流定义

通常的自旋流定义在描述自旋-轨道耦合系统中的自旋输运是不完整的与非物理的。文章作者提出在这类系统中自旋流的恰当定义。新定义的自旋流克服了通常定义下的本质缺点，可通过实验直接观测。     

石英亚沸蒸馏器蒸馏浓缩富集FAAS法同时测定自来水中的铅和镉

把分析测试工作中常用来制备高纯水的石英亚沸蒸馏器用于浓缩富集自来水中的铅、镉,并用火焰原子吸收光谱法对铅、镉进行测定.     

模糊对向传播网络数据融合目标识别方法

重点研究了模糊对向传播网络 (FCPN)模型。针对数据融合和目标识别的特点 ,提出了基于模糊对向传播网络的融合目标识别方法和改进的模糊对向传播网络 (MFCPN)融合结构。利用仿真数据对网络的训练算法和融合结构进行了实验研究。结果表明 ,模糊对向传播网络较误差后向传播网络 (BPN)能够有效地实现融合识别 ;改进的模糊对向传播网络融合结构是可行的。同时还对FCPN和MFCPN应用于前视红外 (FLIR)和可见光摄像机目标跟踪系统进行了应用研究。     

聚焦慢速高荷态重离子束微束斑X射线源

利用电子束离子源(EBIS)或者电子束离子陷阱(EBIT)产生的慢速高电荷态重离子束轰击金属靶面,离子束与靶面作用并复合辐射特征X射线;并将高荷态离子束采用离子光学系统会聚为微细束后再与靶面作用,能够辐射出微米甚至亚微米级、纳米级的微束斑X射线.本文介绍这一新型微束斑X射线源的结构、机理及其特性等.     

三缺位杂多阴离子PW_9(O_(34))~(9-) 的二苯基硅衍生物的合成和表征

以Na8 H[PW9O3 4 ]·nH2 O与Ph2 SiCl2 为原料于乙腈中合成了三缺位杂多阴离子的二苯基硅衍生物(TBA)3[α-A -PW9O3 4 (Ph2 Si)3 ](TBA为四丁基铵盐的缩写)(记为I),并由元素分析、红外光谱、紫外光谱对化合物进行了表征,结果表明,二苯基硅通过六个Si-O -W桥键填充到三缺位杂多阴离子的骨架上,形成了开环的饱和笼形结构.热分析结果表明,该化合物的热分解温度在 4 95.2℃左右     

Effect of Nonradiative Recombination on Carrier Dynamics in GaInNAs/GaAs Quantum Wells

The nonradiative recombination effect on carrier dynamics in GalnNAs/GaAs quantum wells is studied by timeresolved photoluminescence （TRPL） and polarization-dependent TRPL at various excitation intensities. It is found that both recombination dynamics and spin relaxation dynamics strongly depend on the excitation intensity. Under moderate excitation intensities the PL decay curves exhibit unusual non-exponential behaviour. This result is well simulated by a rate equation involving both the radiative and non-radiative recombinations via the introduction of a new parameter of the effective concentration of nonradiative recombination centres in the rate equation. In the spin dynamics study, the spin relaxation also shows strong excitation power dependence. Under the high excitation power an increase of spin polarization degree with time is observed. This new finding provides a useful hint that the spin process can be controlled by excitation power in GaInNAs systems.     

掺铒光纤放大器中上转换过程的影响

掺杂浓度的提高影响了掺铒光纤放大器(EDFA)的性能,对经典Giles模型提出了新的要求。首先研究了高掺杂下铒离子距离较小引起的上转换过程的机理,通过优化速率方程模型分析了上转换过程对EDFA的影响,得出了在泵浦光和信号光远远大于ASE光的假设下泵浦光和信号光沿光纤长度变化的近似表达式,并将该近似分析解与解析解进行了比较。仿真结果表明上转换过程会降低随光纤传输的信号光和泵浦光,影响EDFA的放大性能,并得出了当掺铒浓度大于2.95×1025m-3时,上转换过程的影响不能忽略的结论。     

基于DIGNET网络的数据融合方法

针对数据融合和目标识别的特点,提出了基于DIGNET自组织聚类人工神经网络的数据融合方法。考虑到多传感器系统测量多个参量的特点,用并行的子网络结构代替中间隐层,实现了基于决策层的信息融合目标识别。利用仿真数据对基于DIGNET的数据融合方法进行了实验研究。实验结果表明,该方法具有数据正确分类率高和抗噪能力强等优点,有效地实现了融合识别。将该方法应用于前视红外和可见光双传感器目标跟踪系统的数据融合识别是可行的。