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In this research article, we describe the synthesis and characterization of mononuclear and dinuclear Cu complexes bound by a family of tridentate redox-active ligands with tunable H-bonding donors. The mononuclear Cu-anion complexes were oxidized to the corresponding “high-valent” intermediates by oxidation of the redox-active ligand. These species were capable of oxidizing phenols with weak O−H bonds via H-atom abstraction. Thermodynamic analysis of the H-atom abstractions, which included reduction potential measurements, pKa determination and kinetic studies, revealed that modification of the anion coordinated to the Cu and changes in the H-bonding donor did not lead to major differences in the reactivity of the “high-valent” CuY complexes (Y: hydroxide, phenolate and acetate), which indicated that the tridentate ligand scaffold acts as the H+ and e− acceptor. 相似文献
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L. Tong Y. Tian Q. Y. Wang Y. S. Ling 《International Journal of Infrared and Millimeter Waves》2006,27(9):1307-1314
The paper introduces a special system calibration technology in s-parameters measurement of microwave and millimeter wave
devices. The 8-term errors module is built by analyzing the signals flowing in the measurement system. Then the calibration
technology using non-standard kits is designed on the base. Finally, the experiment using the calibration technology is introduced. 相似文献
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WANG Mingwei LI Bo FENG Kun RAO Jun KANG Zihua LI Xiujuan LILi WANG Minghong FAN Mingjie 《核工业西南物理研究院年报(英文版)》2004,(1):77-79
in order to study non-indutive plasma current production, the lower hybrid current drive(LHCD) experiment on the HL-2A tokamak is carried out. Simultaneously a microcomputer has been used to control the whole LHCD system. During the experiment this year, we can monitor and protect the LHCD system by use of the microcomputer control system, which will imediately switch off the microwave power to be launched into the tokamak if the plasma is disrupted. All this ensure that the microwave is injected into the equipment correctly. 相似文献
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A lithium(I) coordination polymer has been formed from LiClO4 and the 2,2′‐bipyrimidine (bpym) ligand in which each square pyramidal lithium(I) atom is coordinated in the basal plane by four nitrogen donor atoms derived from two bpym ligands and one water molecule at the apical position. These are connected into a layer structure via hydrogen‐bonding interactions involving the perchlorate anions. Copyright © 2004 John Wiley & Sons, Ltd. 相似文献
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We measure and calculate the aerial image modulation (AIM) of human retina for visible wavelengths based on the individual eye model. By employing the optical design software ZEMAX, we obtain the modulation transfer function (MTF) of human eye in visible wavelengths. Using CSV-1000 and VAF-1000, the contrast sensitivity function (CSF) and the visual acuity (VA) for the same eye are measured. Then the AIM of human retina could be acquired by the relations between MTF and CSF and between MTF and VA. The AIM of human retina is independent of MTF, and the values of AIM for normal eyes (without retina disease) are similar, so the assembly average for large numbers of normal eyes can be a standard AIM curve, which is helpful for the diagnosis of diseases in the retina system. 相似文献
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In this paper, based on the natural boundary reduction advanced by Feng and Yu, we couple the finite element approach with the natural boundary element method to study the weak solvability and Galerkin approximation of a class of nonlinear exterior boundary value problems. The analysis is mainly based on the variational formulation with constraints. We prove the error estimate of the finite element solution and obtain the asymptotic rate of convergence. Finally, we also give a numerical example.
相似文献