全文获取类型
收费全文 | 469篇 |
免费 | 47篇 |
国内免费 | 44篇 |
专业分类
化学 | 340篇 |
晶体学 | 1篇 |
力学 | 37篇 |
综合类 | 4篇 |
数学 | 42篇 |
物理学 | 136篇 |
出版年
2024年 | 1篇 |
2023年 | 10篇 |
2022年 | 10篇 |
2021年 | 21篇 |
2020年 | 26篇 |
2019年 | 14篇 |
2018年 | 26篇 |
2017年 | 20篇 |
2016年 | 23篇 |
2015年 | 28篇 |
2014年 | 28篇 |
2013年 | 36篇 |
2012年 | 26篇 |
2011年 | 38篇 |
2010年 | 30篇 |
2009年 | 14篇 |
2008年 | 27篇 |
2007年 | 13篇 |
2006年 | 14篇 |
2005年 | 11篇 |
2004年 | 8篇 |
2003年 | 8篇 |
2002年 | 17篇 |
2001年 | 26篇 |
2000年 | 8篇 |
1999年 | 10篇 |
1998年 | 8篇 |
1997年 | 6篇 |
1996年 | 3篇 |
1995年 | 3篇 |
1994年 | 5篇 |
1993年 | 4篇 |
1992年 | 7篇 |
1991年 | 6篇 |
1990年 | 3篇 |
1989年 | 4篇 |
1988年 | 1篇 |
1986年 | 3篇 |
1985年 | 5篇 |
1984年 | 2篇 |
1981年 | 1篇 |
1980年 | 2篇 |
1976年 | 1篇 |
1974年 | 1篇 |
1971年 | 1篇 |
1970年 | 1篇 |
排序方式: 共有560条查询结果,搜索用时 31 毫秒
1.
2.
单扫描示波极谱测定痕量银 总被引:1,自引:0,他引:1
本文首次提出了运用单扫描极谱直接测定银的方法。在含N-烯丙基-N′-对苯磺酸钠硫脲及四乙烯五胺的硼砂缓冲液中,银离子在-0.66V(相对饱和甘汞电极)有一灵敏还原波。运用经典极谱或单扫描极谱,此波均可用于微量银的定量测定。“银波”的单扫描示波极谱波可在5×10~(-7)~3×10~(-5)mol/L范围内检测银。方法已用于废定影液中银含量的分析,结果满意。 相似文献
3.
此文报道了H+、H+2和H+3离子通过碳膜后,在其中产生的各种微量产物的测量结果.讨论了离子与碳膜作用中的电荷交换过程.分析了这些微量产物的形成机理.实验证明在产物的形成中电荷交换过程起关键作用.研究了离子与碳膜作用中的团簇效应和尾流效应. 相似文献
4.
S—R分解定理的唯一性,存在性和客观性 总被引:3,自引:0,他引:3
对于连续体的一切物理可能的变形场,其变形梯度张量F可被分解为一个对称张量S和一个正交张量R的直和,这便是S-R分解定理.本文通过矩阵方法和张量方法证明了S-R分解定理的唯一性、存在性和客观性. 相似文献
5.
An intensity-modulated optical fibre sensor system is described which employs a single LED source to provide the measurand and the reference signals with two separate wavelength bands. The allocated wavelength bands are selected to minimize any differential intensity effects that may arise from LED thermal variations. The sensor system, comprising a transceiver unit connected to an optical displacement sensor using a single optical fibre, provides an output fully referenced for all major common-mode variations that are likely to occur. Performance characteristics for the prototype system are reported which show a linear displacement range of over 20 mm. 相似文献
6.
Based on the method of ε-NTU, a mathematical modeling of ester-interchange reaction for dimethyl terephthalate (DMT) with ethylene glycol (EG) by acetate system was simulated, and, in addition, the corresponding kinetic equation is obtained by using the theoretical method of simulation. That is,-(dc)/(dt)=kc(c+k')where:-(dc)/(dt)= the reaction rate of the monomer, C -concentration of the monomer, θ-Suitable parameterk,k'-constant (k'=θ/k)The experimental results have showed that the ester-interchange reaction is a reaction neither first order or second order nor third order,but it is a reaction of secondary linear type. Yamanis[2] doubted the correctness of the method that has been proved.Moreover,we have suggested the physical meaning of parameters. 相似文献
7.
Mian Chang Jiayou Yu Shaojun Wang Liping Yang Yi Yang Shihao Cai Shouheng Shi Yan Wang P. W. Zhu 《中国科学B辑(英文版)》1997,40(5):529-534
A synthetical equation is proposed to characterize the essential features of the inverse “S” type curve on the basis of summing-up
simulation approach of “S” type curve. The two physical variables in the model obtained are discussed and the detailed method
used to determine the parameters is given. The model is then presented to describe the crystallization of poly(caryleher ether
ketone) (PEEK) and thermal decomposition of poly(amide-imide) (PAI) respectively. It is found that some thermal characteristic
parameters can be well estimated from the model simu-lated in computer. 相似文献
8.
A new crystal-engineering motif has been developed where a ditopic receptor 1 shows a novel syn-syn hydrogen-bonded polymeric supramolecular complex (Fig. 4b) (instead of a 1:1 dimeric syn-syn or polymeric syn-anti complex) giving rise to a hydrogen-bonded stair-like polymeric ribbon structure between the binding groups of the receptor pyridine amide and the carboxyl groups of the guest substrate. 相似文献
9.
Mechanical properties of BPDA-ODA polyimide fibers 总被引:1,自引:0,他引:1
An aromatic polyimide was synthesized via a one-step polycondensation reaction between biphenyltetracarboxylic dianhydride (BPDA) and 4,4′-oxydianiline (ODA) in p-chlorophenol. The polyimide (BPDA-ODA) solution dopes were spun into fibers by means of dry-jet wet spinning. The as-spun fibers were drawn and treated in heating tubes for improving the mechanical properties. The thermal treatment on the fibers resulted in a relatively high tensile strength and modulus. Thermal mechanical analysis (TMA) was employed to study the linear coefficient of thermal expansion (CTE). Thermal gravimetry analysis (TGA) spectra showed that the BPDA-ODA fibers possessed an excellent property of thermo-oxidative degradation resistance. The sonic modulus Es of the polyimide fibers was measured. 相似文献
10.
Joseph R. Lakowicz Zakir Murtaza Wayne E. Jones Jr. Kihan Kim Henryk Szmacinski 《Journal of fluorescence》1996,6(4):245-249
We report the first observation of polarized emission from a rhenium-phenanthroline complex, Re(CO)3(phen)Cl. Highly luminescent rhenium complexes are known, with quantum yields near 0.5 and lifetimes in excess of 10 s. The detection of polarized emission suggests the use of rhenium complexes as probes of the hydrodynamics of large macromolecular complexes and for use in fluorescence polarization immunoassays with gated detection. 相似文献