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1.
Xinjiang Chen Goh Matsuo Bunsho Ohtani Kaoru Tsujii 《Journal of polymer science. Part A, Polymer chemistry》2007,45(21):4891-4900
A racemic amphiphilic monomer, n‐dodecyl glyceryl itaconate (DGI), forms bilayer membranes in water in the presence of small amount of ionic cosurfactant and shows iridescent color. A chiral DGI, S‐DGI, also shows an iridescent property, but with a rather red shift in the color, which can be ascribed to the increased packing density of the monomer in the bilayer membranes. Chrial DGI has a more compact packing density than racemic one owing to closer distance between the monomer molecules; the conversion rate, however, is slower than that of racemic one when H2O2 is used as an initiator. When the initiator is changed to an amphiphilic one, 4‐(2‐hydroxyethoxy) phenyl‐(2‐hydroxy‐2‐propyl) ketone (Irgacure 2959), the chiral DGI shows even a little faster conversion rate than that of racemic one. The NMR chemical shift results of protons in benzene ring show that the molecules of Irgacure 2959 insert into the bilayer membranes. The molecular weights of the corresponding polymers prove that the initiation by H2O2 is restricted compared to that by Irgacure 2959. It is concluded that the decelerated polymerization behavior of chiral DGI initiated by H2O2 is a result of limited diffusion of the initiator into the lamellar bilayer structures. © 2007 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 45: 4891–4900, 2007 相似文献
2.
We investigated the waveguide formation in Lithium Niobate with Femtosecond laser pulse writing directly. The output optical field through waveguide has been observed and refractive-index change was characterized by using grating method. 相似文献
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对文献[1]中提出的两质点两滑轮组成的两自由度问题,现采用简化物理模型,用牛顿力学方法分析绳中张力随右边B球摆角θ的变化,进而列出左边A球所受合外力随θ角变化的表达式,作出图像,可较为合理地解释其实验现象。 相似文献
6.
Jien Wu Xiao-Fang Cheng Leslie J. Harrison Swee-Hock Goh Keng-Yeow Sim 《Tetrahedron letters》2004,45(52):9657-9659
Examination of the aerial parts of a Chinese herbal medicine yielded a novel metabolite, perforatumone 1, which is characterized by its unique carbon skeleton. Its structure was determined by detailed spectroscopic analysis. 相似文献
7.
Supramolecular side chain liquid crystalline polymers (SCLCPs) based on poly(3-carboxypropylmethylsiloxane-co-dimethylsiloxane) (PSIX, X=100, 76, 60, 41 or 23, denoting the mole percentage of 3-carboxypropylmethylsiloxane unit in the polymer) and stilbazole derivatives have been obtained through intermolecular hydrogen bonding (H-bonding) interactions between the carboxylic acid and the pyridyl moieties. The formation of H-bonding and self-assembly results in the formation of new mesogenic units, in which H-bonds function as molecular connectors. FTIR shows the existence of H-bonding in the complexes. The polymeric complexes behave as single component liquid crystalline polymers and exhibit stable and enantiotropic mesophases. The liquid crystalline properties of the supramolecular SCLCPs were studied using differential scanning calorimetry, polarizing optical microscopy and X-ray diffraction, and were found to exhibit smectic A phases with focal-conic textures. The thermal stability of the SCLCP increases on increasing the carboxylic acid content in the polysiloxane and the concentration of the stilbazole derivative in the complex. However, the thermal stability decreases on increasing the chain length of the stilbazole derivative. The crystal phase was not formed even on cooling to the glass transition temperature of the polymeric complex. 相似文献
8.
Preparation of Papers 总被引:8,自引:0,他引:8
We motivate the study of a vector variational inequality by a practical flow equilibrium problem on a network, namely a generalization of the well-known Wardrop equilibrium principle. Both weak and strong forms of the vector variational inequality are discussed and their relationships to a vector optimization problem are established under various convexity assumptions. 相似文献
9.
提出了一种非刚性点匹配的算法并把其运用于医学图像配准.该算法采用信号滤波的方法来获得点集间的匹配信息,并运用松弛标记法将各点邻域关系对模糊的匹配信息进行迭代获得明确的匹配关系.在此基础上,利用高斯径向基函数来描述点模式间的弹性形变,在基本的迭代框架下实现问题的求解.实验结果显示在形变程度为5%、出格点比率50%和噪声标准差为5%的情况下该算法的匹配误差能控制在0.13以下,表明了该算法的鲁棒性和有效性,较好地解决了医学非刚性形变的点匹配问题. 相似文献
10.
用脉冲回波重叠法测量了钛合金(TC-6)的二阶、三阶弹性常数。实验中发现dμ/dp<0(p<0.17 GPa),dμ/dp>0(p>0.17 GPa)。 相似文献