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排序方式: 共有83条查询结果,搜索用时 46 毫秒
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Ozlem Yazici M. Reyhan Moroglu Husnu Cankurtaran Ozlem Cankurtaran Ferdane Karaman 《Mikrochimica acta》2008,160(4):441-445
The composites of graphite with Ardel?D-100 which is a trademark of a polyester of bisphenol-A with terephthalic and isophthalic acid were used as a sensing material
in a conductometric vapor sensor. The magnitudes of responses are increased in the order of benzene, isobutyl acetate, isoamyl
acetate, ethyl benzene and chloro benzene. This suggests that Ardel?D-100 can be used as a sensing material for chlorobenzene, ethyl benzene and isoamyl acetate. On the other hand, specific
retention volumes of the sensed vapors on Ardel?D-100 coated on graphite were determined by inverse gas chromatography at temperatures between 200 and 260 °C. The distribution
coefficient, K
s of the vapors between stationary and mobile phases in the column was obtained. It was revealed for the first time that the
logarithm of K
s of the solvents varies almost linearly with their responses based on conductometric resistance of the sensing polymer composite.
Subsequently, the study suggests that gas chromatographic retention data can be used in prediction of the conductometric responses
of a polymeric sensor to vapors.
Correspondence: Ferdane Karaman, Department of Chemistry, Yildiz Technical University, 34220 Istanbul-Esenler, Turkey 相似文献
5.
Karaman R 《Journal of computer-aided molecular design》2010,24(12):961-970
DFT calculation results for intramolecular proton transfer reactions in Kirby’s enzyme models 1–7 reveal that the reaction rate is quite responsive to geometric disposition, especially to distance between the two reactive
centers, r
GM, and the angle of attack, α (the hydrogen bonding angle). Hence, the study on the systems reported herein could provide a
good basis for designing aza nucleoside prodrug systems that are less hydrophilic than their parental drugs and can be used,
in different dosage forms, to release the parent drug in a controlled manner. For example, based on the calculated log EM,
the cleavage process for prodrug 1ProD is predicted to be about 1010 times faster than that for prodrug 7ProD and about 104 times faster than prodrug 3ProD: rate
1ProD
> rate
3ProD
> rate
7ProD
. Hence, the rate by which the prodrug releases the aza nucleoside drug can be determined according to the structural features
of the linker (Kirby’s enzyme model). 相似文献
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Vagif Sabir Guliyev Turhan Karaman Rza Chingiz Mustafayev Ayhan Şerbetçi 《Czechoslovak Mathematical Journal》2014,64(2):365-386
In this paper, the boundedness of a large class of sublinear commutator operators T b generated by a Calderón-Zygmund type operator on a generalized weighted Morrey spaces \({M_{p,\varphi }}(w)\) with the weight function w belonging to Muckenhoupt’s class A p is studied. When 1 < p < ∞ and b ∈ BMO, sufficient conditions on the pair (φ 1, φ 2) which ensure the boundedness of the operator T b from \({M_{p,\varphi 1}}(w)\) to \({M_{p,\varphi 2}}(w)\) are found. In all cases the conditions for the boundedness of T b are given in terms of Zygmund-type integral inequalities on (φ 1, φ 2), which do not require any assumption on monotonicity of φ 1(x, r), φ 2(x, r) in r. Then these results are applied to several particular operators such as the pseudo-differential operators, Littlewood-Paley operator, Marcinkiewicz operator and Bochner-Riesz operator. 相似文献
8.
V. V. Bivol S. V. Robu A. M. Prisacari A. Yu. Meshalkin L. A. Vlad M. I. Karaman 《High Energy Chemistry》2006,40(3):178-181
Sensitometric and holographic properties of photoresist layers made from carbazolylalkyl methacrylate copolymers and polyepoxypropylcarbazole sensitized with triiodomethane and, additionally, spiropyran photochromic compounds were studied. It was found that the introduction of photochromic 6′-bromo-8′-nitro-1,3,3-trimethylindolylspirobenzopyran (8–12%) into photoresist layers increased their photographic sensitivity by a factor of 2.5–3 up to the values of 10?3–10?4 J cm?2 and shifted their spectral sensitivity to the blue-green region. The feasibility of recording quality holograms in the photoresist layers using coherent He-Cd laser light (λ = 420 nm), as well as argon laser light (λ = 490 nm), was shown. Diffraction gratings with an efficiency of 15–20% and a resolution of 2000 mm?1 were obtained. 相似文献
9.
Novel ethyl 2-oxo-4,6-diaryl-1,2,3,4-tetrahydropyridine-3-carboxylate and 4,6-diaryl-3,4-dihydropyridine-2(1H)-one derivatives have been synthesized from the cyclization of adducts of diethylmalonate to chalcones with ammonium acetate. The structures were established on the basis of extensive spectroscopic methods and further confirmed by X-ray crystallographic analysis. Antibacterial activity of obtained pyridones was investigated against four human pathogen microorganisms and the compounds showed poor activity.
[Supplementary materials are available for this article. Go to the publisher's online edition of Synthetic Communications® for the following free supplemental resource(s): Full experimental and spectral details.] 相似文献
10.
V. P. Ambros M. I. Karaman V. P. Mushinskii L. I. Palaki 《Russian Physics Journal》1972,15(9):1298-1301
The excitation and radiation spectra of-Ga2As3 crystals have been studied. The radiation spectrum consists of two overlapping bands (1.44 and 1.61 eV) and a very weak band in the 2.8–2.9 eV region. The temperature dependence of the halfwidth of the luminescence bands was studied and the position of the levels responsible for the luminescence were determined: E1,v = 0.84 eV and E2,v = 0.59 eV. These luminescence bands in -Ga2As3 crystals undergo thermal quenching. The kinetics of the photoconductivity and the photoluminescence were studied and it was shown that the recombination of nonequilibrium carriers occurs by two channels: via fast s levels and slow r levels, the trapping cross section of the latter being
.Translated from Izvestiya Vysshikh Uchebnykh Zavedenii, Fizika, No. 9, pp. 72–75, September, 1972. 相似文献