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Margaret W. Geiger Margaret M. Elliot Velissarios D. Karacostas Thomas J. Moricone Jesse B. Salmon Vincent L. Sideli Martha A. St . Onge 《Photochemistry and photobiology》1984,40(4):545-548
Abstract A series of ring-substituted phenyl and naphthyl azides have been prepared. Electronic absorption spectral properties and quantum yields of disappearance have been determined in aqueous solution. For phenyl azide derivatives, the wavelengths of maximum absorption vary systematically, correlating with electronic effects of the ring substituents. Quantum yield values of 0.1–0.7 are obtained and are independent of a number of experimental conditions, including concentration. There is no simple correlation of the quantum yields of azide disappearance with electronic effects, except that the naphthyl azides have higher photochemical efficiencies than the phenyl azide derivatives. A series of potential protein photolabels has been identified based on electronic absorption characteristics and photochemical efficiencies. 相似文献
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