全文获取类型
收费全文 | 402篇 |
免费 | 12篇 |
国内免费 | 1篇 |
专业分类
化学 | 284篇 |
晶体学 | 11篇 |
力学 | 3篇 |
数学 | 6篇 |
物理学 | 111篇 |
出版年
2023年 | 1篇 |
2022年 | 2篇 |
2021年 | 1篇 |
2020年 | 7篇 |
2019年 | 11篇 |
2018年 | 5篇 |
2017年 | 1篇 |
2016年 | 8篇 |
2015年 | 13篇 |
2014年 | 13篇 |
2013年 | 22篇 |
2012年 | 16篇 |
2011年 | 23篇 |
2010年 | 15篇 |
2009年 | 19篇 |
2008年 | 22篇 |
2007年 | 26篇 |
2006年 | 20篇 |
2005年 | 20篇 |
2004年 | 15篇 |
2003年 | 12篇 |
2002年 | 11篇 |
2001年 | 5篇 |
2000年 | 12篇 |
1999年 | 6篇 |
1997年 | 5篇 |
1996年 | 1篇 |
1995年 | 1篇 |
1994年 | 8篇 |
1993年 | 10篇 |
1992年 | 3篇 |
1991年 | 3篇 |
1990年 | 5篇 |
1988年 | 4篇 |
1987年 | 10篇 |
1986年 | 2篇 |
1985年 | 6篇 |
1984年 | 8篇 |
1983年 | 3篇 |
1982年 | 10篇 |
1981年 | 4篇 |
1980年 | 5篇 |
1979年 | 4篇 |
1978年 | 5篇 |
1976年 | 3篇 |
1975年 | 3篇 |
1974年 | 1篇 |
1973年 | 3篇 |
1972年 | 1篇 |
1966年 | 1篇 |
排序方式: 共有415条查询结果,搜索用时 15 毫秒
1.
为阐述放射性9C束流应用于治癌的物理基础, 运用一个球形生物组织等效正比计数器测量了9C束流不同贯穿深度上的线能谱, 得到了沿束流贯穿深度上的剂量平均线能分布. 将实验测量得到的线能谱转换成为不同传能线密度在吸收剂量中所占份额的分布, 得到了该9C束流在不同贯穿深度上的剂量平均传能线密度分布. 将生物组织等效正比计数器测量得到的与先前通过平行板正比计数器测量得到的该9C束流的剂量平均传能线密度分布进行比较, 发现: 在束流入射通道上, 两者测量数据符合很好, 而在束流Bragg峰附近9C离子的沉积区域, 由组织等效正比计数器测量得到的剂量平均传能线密度值大于由平行板正比计数器测量得到的值. 相似文献
2.
3.
4.
In this paper, the NO-to-NO
2
conversion in various gaseous mixtures is experimentally investigated. Streamer coronas are produced with a dc-superimposed high-frequency ac power supply (10–60 kHz). According to NO
x
removal experiments in N
2
+NO
x
and N
2
+O
2
+NO
x
gaseous mixtures, it is supposed that the reverse reaction NO
2
+ONO+O
2
may not only limit NO
2
production in N
2
+NO
x
mixtures, but also increase the energy cost for NO removal. Oxygen could significantly suppress reduction reactions and enhance oxidation processes. The reduction reactions, such as N+NON
2
+O, induce negligible NO removal provided the O
2
concentration is larger than 3.6%. With adding H
2
O into the reactor, the produced NO
2
per unit removed NO can be significantly reduced due to NO
2
oxidation. NH
3
injection could also significantly decrease the produced NO
2
via NH and NH
2
- related reduction reactions. Almost 100% of NO
2
can be removed in gaseous mixtures of N
2
+O
2
+H
2
O+NO
2
with negligible NO production. 相似文献
5.
6.
Sadahito Aoshima Tomohide Yoshida Arihiro Kanazawa Shokyoku Kanaoka 《Journal of polymer science. Part A, Polymer chemistry》2007,45(10):1801-1813
Our recent extensive research on Lewis acid catalysts with a weak base for the cationic polymerization of vinyl ethers led to unprecedented living reaction systems: fast living polymerization within 1–3 s; a wide choice of metal halides containing Al, Sn, Fe, Ti, Zr, Hf, Zn, Ga, In, Si, Ge, and Bi; and heterogeneously catalyzed living polymerization with Fe2O3. The use of added bases for the stabilization of the propagating carbocation and the appropriate selection of Lewis acid catalysts were crucial to the success of such new types of living polymerizations. In addition, the base‐stabilized living polymerization allowed the quantitative synthesis of star‐shaped polymers with a narrow molecular weight distribution via polymer‐linking reactions and the precision synthesis and self‐assembly of stimuli‐responsive block copolymers. © 2007 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 45: 1801–1813, 2007. 相似文献
7.
Goto S Masuda K Miura M Kanazawa K Sasaki M Masui M Shiramizu M Terada H Chuman H 《Chemical & pharmaceutical bulletin》2002,50(4):445-449
We measured the affinity of more than 20 sugars with concanavalin A (ConA) by an optical biosensor (surface plasmon resonance sensor) using asialofetuin (ASF) as an immobilized binding partner of ConA. We determined kinetic parameters of the effects of sugars on the dissociation of ConA from ASF quantitatively, and the structural requirements of the functional groups of sugars for binding with ConA. We found that the affinity of ConA for sugars is dependent on its conformation induced by interaction with the binding partner. In addition, the results showed that optical biosensor system is well mimics the interaction of ConA with sugars in biomembrane. 相似文献
8.
Akihiko Kanazawa Tomiki Ikeda Takeshi Endo 《Journal of polymer science. Part A, Polymer chemistry》1993,31(2):335-343
Various polymeric phosphonium salts and the corresponding low-molecular-weight model compounds were prepared and their antibacterial activities against Staphylococcus aureus and Escherichia coli were explored by the viable cell counting method in sterile distilled water. Antibacterial activity of the polymers was found to be higher than that of the corresponding model compounds, particularly against S. aureus. Furthermore, the polymeric phosphonium salt exhibited a higher activity by 2 orders of magnitude than the polymeric quaternary ammonium salt with the same structure except the cationic part. Compounds with the longest alkyl chain (octyl) studied were found to exhibit particularly high activity, and this finding may be ascribed to the contribution of the increased hydrophobicity of the compounds to the cidal activity. © 1993 John Wiley & Sons, Inc. 相似文献
9.
A simple relationship is derived which expresses the change in oscillation frequency of a quartz crystal in contact with a fluid in terms of material parameters of the fluid and the quartz. The relationship is Δf = ?f0(ηL?L/πμQ?Q), where f0 is the oscillation frequency of the free (dry) crystal, ηL and ?L are the absolute viscosity and density of the liquid, respectively, and μQ and ?Q are the elastic modulus and density of the quartz. This relation is obtained from a simple physical model which couples the shear wave in the quartz to a damped shear wave in the fluid. Quantitative comparisons with two test cases, aqueous solutions of glucose and ethanol at various concentrations, demonstrate the accuracy of this model. 相似文献
10.
I. Kanazawa 《Journal of Radioanalytical and Nuclear Chemistry》1996,210(2):451-455
We introduce the effective Lagrangian with spontaneously broken density in the Sethna-Sachdev-Nelson formula, and propose one explanation for the increase of the positron diffusion lengthL
+ in the liquid metal phase with temperature. It is shown that the effective mass of the positron in the liquid metal phase will decrease due to the restoration of the spontaneously broken density around the positron, when temperature increases. 相似文献