排序方式: 共有56条查询结果,搜索用时 31 毫秒
1.
Xiangke Wang Jinzhou Du Zuyi Tao Zhongxiu Fan 《Journal of Radioanalytical and Nuclear Chemistry》2003,258(1):133-138
The migration of radionuclides 85+89Sr2+, 134Cs+, 125I- and 75SeO3
2- in calcareous soil from Yuzhong county of Gansu Province (China) at pH 7.8±0.2 and 152+154Eu(III) in red earth from Yingtan county of Jiangxi Province (China) at pH 4.6±0.2, in presence of CaCl2 was studied using column experiments. Results indicate that the negative anions, iodide and selenide are mobile nuclides while the migration of positive cations is related to the sorption capacity for the element. Iodide can be assumed to be non-reactive in calcareous soil. The breakthrough curves (BTCs) were fitted to the analytical solution or numerical solution of one-dimensional convection-dispersion transport models. Good agreements were obtained between the measured and predicted concentration profiles. 相似文献
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Du Jinzhou Dong Wenming Wang Xiangke Tao Zuyi 《Journal of Radioanalytical and Nuclear Chemistry》1996,203(1):31-36
The effect of different solid components of calcareous soil on the retention of Sr was investigated by using batch technique and selective extraction method. The sorption and desorption isotherms of Sr on the untreated calcareous soil and the three treated soils were determined at 20°C, pH 7.8±0.2 and in the presence of 0.001 M CaCl2. It was found that all isotherms are linear and that the sorption of Sr on the calcareous soil can be described by a reversible sorption process and the sorption mechanism is mainly ion exchange. 相似文献
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探寻绿色清洁的资源与材料以维持高效的社会经济增长是未来数十年人们面临的最大挑战之一. 可持续资源与绿色材料的开发是降低传统化石能源与材料比重的最有前途的方案. 纤维素作为一种可持续发展、 可生物再生、 储量丰富且低成本的天然高分子聚合物, 在众多领域中具有广泛的应用, 并且纤维素可以加工成各种构型, 包括气凝胶、 泡沫、 海绵和薄膜等. 本文介绍了不同形态的纤维素及其衍生物组装而成的功能膜在能源与环境中的应用, 综述了微纳米纤维素及其衍生物在先进功能化储能器件方面的最新进展和制备方案, 以及在用于水处理的膜分离技术中的应用, 其中重点讨论了微纳米纤维素及其衍生物功能膜在电池、 电容器及水处理等领域中的作用, 如隔膜、 柔性电极膜和分离膜等. 此外, 还对纤维素及其衍生物功能膜的未来发展进行了总结和展望. 相似文献
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Zhihua Zhao Xiaoqing Shen Hongchang Yao Jianshe Wang Jinzhou Chen Zhongjun Li 《Journal of Sol-Gel Science and Technology》2014,70(1):72-80
Alumina nanofibers were fabricated by calcination of the polyvinylpyrrolidone (PVP)/pseudo-boehmite nanocomposite precursor fibers formed by electrospinning PVP/ethanol solution of dispersed pseudo-boehmite nanoparticles with and without additive of silica. The evolution of the phase, mechanical property and morphological features of the calcined fibers were studied and the effect of adding SiO2 on the phase transformation of alumina was discussed. Adding SiO2 can retard the phase transformation of γ-Al2O3 to α-Al2O3 and therefore inhibit the growth of alumina grains during calcination. Upon calcining the precursor fibers with 4 wt% SiO2 additive at 1,300 °C, continuous alumina nanofibers with diameter ranging from 300 to 800 nm were obtained. These continuous nanofibers exhibited good flexibility and could be very promising for applications in filtration and catalyst support. 相似文献
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Deng Binbin Zhong Qiangqiang Wang Qiugui Du Jinzhou Zhang Xiaocheng 《Journal of Radioanalytical and Nuclear Chemistry》2020,323(3):1135-1143
Journal of Radioanalytical and Nuclear Chemistry - This study monitored 210Pb levels of the atmospheric aerosol in Shanghai from January 2016 to February 2017. 210Pb levels were found to be low in... 相似文献
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TANG Ke HONG Xin ZHAO YongHua SONG LiJuan & SUN ZhaoLin School of Material Chemical Engineering Liaoning Institute of Technology Jinzhou China College of Petrochemical Engineering Liaoning University of Petroleum & Chemical Technology Fushun 《中国科学:化学》2010,(1)
Gallium atoms have been introduced into the framework of Y zeolite by treating the zeolite with an aqueous solution of ammonium hexafluoro gallate.Desulfurization of various model fuels containing about 500 μg/g sulfur has been studied over the synthesized Y zeolite(GaAlY).The sulfur adsorption capacity is 7.0,17.4,14.5,16.9,6.9 and 5.8 mg(S)/g adsorbent for thiophene,tetrahydrothiophene(THT),4,6-dimethyldibenzothiophene(4,6-DMDBT),dibenzophiophene(DBT),benzothiophene(BT) and 4-methyldibenzothiophene(4-MDBT... 相似文献
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噻吩甲酰基吡唑啉酮缩β-丙氨酸配合物的合成、表征及极谱行为 总被引:5,自引:0,他引:5
在非水溶剂中 ,β 丙氨酸与 1 苯基 3 甲基 4 (2 噻吩甲酰基 )吡唑啉酮 5反应合成新型酰基吡唑啉酮席夫碱化合物 1 苯基 3 甲基 4 (2 噻吩甲酰基 )吡唑啉酮 5缩 β 丙氨酸 (HL) .通过回流席夫碱和金属硝酸盐合成了UO2 (Ⅱ )、Cu(Ⅱ )、Co(Ⅱ )和Fe(Ⅱ )金属配合物 .在乙酸 乙酸钠 (pH =4 .6 )缓冲溶液 饱和甘汞电极体系中 ,测量电位 - 1.2 4V处 ,测得铜配合物的极谱波 .元素分析及摩尔电导值表明 ,新配合物的组成为 [UO2 L2 ]·H2 O ,[CuL2 ]·2H2 O ,[CoL2 ]·2H2 O和 [FeL2 ]·2H2 O .运用红外光谱、紫外光谱、核磁共振谱、热谱和磁矩对配合物进行了表征 .结果表明 ,配合物的中心离子 (除UO2 2 + 以外 )均为 6配位 .铜配合物的Cu2 + 还原产生峰电流 ,其电极反应转移 1个电子 . 相似文献
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Jun Ren Jinzhou Yang Wei Wang Hailong Guo Zhijun Zuo Jianying Lin Zhong Li 《International journal of quantum chemistry》2015,115(13):853-858
The activity and selectivity of heterogeneous catalysts can be significantly improved by dispersion of another active component in the metal substrate. The impact of Rh promoter on the formation of dimethyl carbonate (DMC) via oxidative carbonylation of methanol on Cu–Rh/AC (activated carbon) catalyst was investigated by density functional theory calculations. The most stable configurations of reacting species (CO, OH, CH3O, monomethyl carbonate, and DMC) adsorbed on the Cu0(zero‐valent copper)/AC and Cu–Rh/AC surfaces were determined on the basis of the calculated results. The reaction energy and activation energy of the rate‐limiting steps on the Cu–Rh/AC and Cu0/AC surfaces were compared. The activation energies of the rate‐limiting step of CO insertion into dimethoxide are 206.3 and 304.8 kJ mol?1 on the Cu–Rh/AC and Cu0/AC surfaces, respectively. The activation energies of the rate‐limiting step of CO insertion into methoxide are 78.5 and 92.7 kJ/mol on the Cu–Rh/AC and Cu0/AC surfaces, respectively. The calculated results indicate that the addition of Rh atom has a significant effect on decreasing the active energy the main pathway for DMC formation. © 2015 Wiley Periodicals, Inc. 相似文献
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作者将含有MoS_2和石墨的不同配方的固体润滑涂料刷涂在几种国产汽车刮水胶条上,并分别于干摩擦和水润滑的两种刮刷状态下,就固体润滑剂改善刮水胶条的擦拭性能进行了试验研究,指出这是使刮水胶条降低擦拭阻力、提高刮刷效果的可行途径,同时强调配制涂料时应当选用颗粒细小而均匀的固体润滑剂粉末。 相似文献