Chemical composition and antioxidant activity of the coriander cake obtained by extrusion

This study was designed to examine the effect of operating conditions on essential oil composition and antioxidant activity of coriander cakes. Twenty-nine components were determined in essential oils, which were mostly alcohol monoterpenes. The highest essential oil yields (0.11%) were obtained by the nozzle diameter of 5 mm. The main components of cake essential oil linalool, γ-terpinene, geranyl acetate, linalyl acetate and camphor showed significant variations with different nozzle diameter.The total phenol contents and condensed flavonoid contents varied between different nozzle diameters; the highest values obtained of small diameters (5 and 6 mm). Significant differences were also found in total tannin contents among different nozzle diameters. The total phenol contents decreased significantly (p < 0.05) when increased the nozzle diameter to 9 mm and reached 9.11 mg GAE/g.The screening of antioxidant activity of the different coriander cakes using the di(phenyl)-(2,4,6-trinitrophenyl) iminoazanium radical (DPPH) assay showed an appreciable reduction of the stable radical DPPH, although small nozzle diameter was the most efficient method with an IC₅₀ reached of 55 μg/ml as compared with bigger diameter (IC₅₀ = 88 μg/ml).All the extracts had lower β-carotene bleaching activity than that of synthetic antioxidant BHA and BHT. Coriander cake extracts presented a very low reducing power ability (EC₅₀ ≈ 700 μg/ml) compared to ascorbic acid (EC₅₀ = 40 μg/ml).     

Strain localization analysis for planar polycrystals based on bifurcation theory

In the present paper, an efficient numerical tool is developed to investigate the ductility limit of polycrystalline aggregates under in-plane biaxial loading. These aggregates are assumed to be representative of very thin sheet metals (with typically few grains through the thickness). Therefore, the plane-stress assumption is naturally adopted to numerically predict the occurrence of strain localization. Furthermore, the initial crystallographic texture is assumed to be planar. Considering the latter assumptions, a two-dimensional single-crystal model is advantageously chosen to describe the mechanical behavior at the microscopic scale. The mechanical behavior of the planar polycrystalline aggregate is derived from that of single crystals by using the full-constraint Taylor scale-transition scheme. To predict the occurrence of localized necking, the developed multiscale model is coupled with bifurcation theory. As will be demonstrated through various numerical results, in the case of biaxial loading under plane-stress conditions, the planar single-crystal model provides the same predictions as those given by the more commonly used three-dimensional single-crystal model. Moreover, the use of the two-dimensional model instead of the three-dimensional one allows dividing the number of active slip systems by two and, hence, significantly reducing the CPU time required for the integration of the constitutive equations at the single-crystal scale. Furthermore, the planar polycrystal model seems to be more suitable to study the ductility of very thin sheet metals, as its use allows us to rigorously ensure the plane-stress state, which is not always the case when the fully three-dimensional polycrystalline model is employed. Consequently, the adoption of this planar formulation, instead of the three-dimensional one, allows us to simplify the computational aspects and, accordingly, to considerably reduce the CPU time required for the numerical predictions.     

Immobilization of E. coli bacteria in three-dimensional matrices for ISFET biosensor design

In recent years, cell-based biosensors (CBBs) have been very useful in biomedicine, food industry, environmental monitoring and pharmaceutical screening. They constitute an economical substitute for enzymatic biosensors, but cell immobilization remains a limitation in this technology. To investigate into the potential applications of cell-based biosensors, we describe an electrochemical system based on a microbial biosensor using an Escherichia coli K-12 derivative as a primary transducer to detect biologically active agents. pH variations were recorded by an ion-sensitive field effect transistor (ISFET) sensor on bacteria immobilized in agarose gels. The ISFET device was directly introduced in 100 ml of this mixture or in a miniaturized system using a dialysis membrane that contains 1 ml of the same mixture. The bacterial activity could be detected for several days. The extracellular acidification rate (ECAR) was analyzed with or without the addition of a culture medium or an antibiotic solution. At first, the microorganisms acidified their micro-environment and then they alkalinized it. These two phases were attributed to an apparent substrate preference of bacteria. Cell treatment with an inhibitor or an activator of their metabolism was then monitored and streptomycin effect was tested.     

Unbounded symmetric operators in K-homology and the Baum-Connes conjecture

Using the unbounded picture of analytical K-homology, we associate a well-defined K-homology class to an unbounded symmetric operator satisfying certain mild technical conditions. We also establish an “addition formula” for the Dirac operator on the circle and for the Dolbeault operator on closed surfaces. Two proofs are provided, one using topology and the other one, surprisingly involved, sticking to analysis, on the basis of the previous result. As a second application, we construct, in a purely analytical language, various homomorphisms linking the homology of a group in low degree, the K-homology of its classifying space and the analytic K-theory of its C^*-algebra, in close connection with the Baum-Connes assembly map. For groups classified by a 2-complex, this allows to reformulate the Baum-Connes conjecture.     

K-Theory for C*-Algebras of One-Relator Groups

We compute the K-theory groups of the reduced C*-algebra C _r ^* () of a one-relator group . We prove that every such group is K-amenable in the sense of Cuntz. For a torsion-free one-relator group =<X|r> such that r is not a product of commutators, we give a direct proof of the fact that the Baum–Connes analytical assembly map

A Cadmium Coordination Polymer Based on Phosphate Clusters: Synthesis,Crystal Structure,Electrochemical Investigation and Antibacterial Activity

A new d¹⁰ coordination polymer, \(\left\{ {\left( {{\text{C}}_{5} {\text{H}}_{14} {\text{N}}_{2} } \right)_{2} \left[ {{\text{Cd}}\left( {\left( {{\text{P}}_{6} {\text{O}}_{18} } \right)\left( {{\text{H}}_{2} {\text{O}}} \right)_{2} } \right)} \right] \cdot 6{\text{H}}_{2} {\text{O}}} \right\}_{n}\), was prepared and characterized by X-ray diffraction, IR-Raman spectroscopy, thermal analysis and cyclic voltammetry. The crystal structure determination reveals that the phosphate anions alternate with the cadmium octahedral to form an anionic coordination polymer extending along [001] direction. The double protonated homopiperazine cations and the water molecules ensure the interconnection between polymers and thus giving rise to three dimensional supramolecular networks. By means of cyclic voltammetry, it is shown that whilst the reduction of the complexed Cd²⁺ occurs with a biggest difficulty than this of its free form, the anodic oxidation of the heterocyclic N donor piperazine became quite easy, when it is displayed as a counterpart diprotonated cation, between the anionic layers of \(\left[ {{\text{Cd}}({\text{P}}_{6} {\text{O}}_{18} )({\text{H}}_{2} {\text{O}})_{2} )} \right]_{\text{n}}^{{4{\text{n}} - }}\). The antibacterial activity of the coordination polymer is also discussed.     

Material behavior of the hexagonal alpha phase of a titanium alloy identified from nanoindentation tests

This article focuses on the numerical modeling of nanoindentation tests performed on the hexagonal α phase of Ti-5553 alloy in order to identify its mechanical behavior. The main goal consists in determining the relative strength of the slip modes in the α phase of Ti-5553. This work was performed using an elastoviscoplastic crystal plasticity-based constitutive law. The difficulties in determining the slip systems that can be activated and their corresponding critical resolved shear stresses (CRSS) are discussed. Numerical predictions are compared to experimental nanoindentation curves.