全文获取类型
收费全文 | 547篇 |
免费 | 27篇 |
国内免费 | 4篇 |
专业分类
化学 | 412篇 |
晶体学 | 4篇 |
力学 | 10篇 |
数学 | 75篇 |
物理学 | 77篇 |
出版年
2023年 | 7篇 |
2022年 | 2篇 |
2021年 | 10篇 |
2020年 | 18篇 |
2019年 | 12篇 |
2018年 | 11篇 |
2017年 | 11篇 |
2016年 | 16篇 |
2015年 | 21篇 |
2014年 | 27篇 |
2013年 | 42篇 |
2012年 | 34篇 |
2011年 | 55篇 |
2010年 | 22篇 |
2009年 | 33篇 |
2008年 | 24篇 |
2007年 | 25篇 |
2006年 | 32篇 |
2005年 | 30篇 |
2004年 | 26篇 |
2003年 | 34篇 |
2002年 | 24篇 |
2001年 | 8篇 |
2000年 | 9篇 |
1999年 | 6篇 |
1998年 | 8篇 |
1997年 | 1篇 |
1996年 | 3篇 |
1995年 | 3篇 |
1994年 | 5篇 |
1993年 | 2篇 |
1992年 | 2篇 |
1990年 | 1篇 |
1987年 | 1篇 |
1985年 | 1篇 |
1984年 | 5篇 |
1982年 | 1篇 |
1979年 | 1篇 |
1978年 | 2篇 |
1977年 | 1篇 |
1973年 | 1篇 |
1969年 | 1篇 |
排序方式: 共有578条查询结果,搜索用时 18 毫秒
1.
The problem of nonparametric stationary distribution function estimation by the observations of an ergodic diffusion process is considered. The local asymptotic minimax lower bound on the risk of all the estimators is found and it is proved that the empirical distribution function is asymptotically efficient in the sense of this bound. 相似文献
2.
This work is aimed at the optimization of the yield and purity of non-symmetrical trialkyl sulfonium halide salts. The effects of parameters such as solvent, temperature and concentration were studied. The products were carefully analyzed and the crystal structure of [{n-CH3(CH2)15}(CH3)2S]Br determined. The overall aim of the present study is future syntheses of low-dimensional magnetic materials. 相似文献
3.
Ilia Krasikov 《Results in Mathematics》2004,45(1-2):59-66
We consider a problem of bounding the maximal possible multiplicity of a zero of some expansions Σ aiFi(x), at a certain point c, depending on the chosen family {imi}. The most important example is a polynomial with c = 1. It is shown that this question naturally leads to discrete orthogonal polynomials. Using this connection we derive some new bounds, in particular on the multiplicity of the zero at one of a polynomial with a prescribed norm. 30C15, 33C47 相似文献
4.
For a general K3 surface S of genus g, with 2 ≤ g ≤ 10, we prove that the intermediate Jacobians of the family of prime Fano threefolds of genus g containing S as a hyperplane section, form generically an algebraic completely integrable Hamiltonian system.
The first author is partially supported by grant MI1503/2005 of the Bulgarian Foundation for Scientific Research. 相似文献
5.
We construct tau-function solutions to the q-KP hierarchy as deformations of classical tau functions. 相似文献
6.
The Pd(OAc)(2)/pyridine catalyst system is one of the most convenient and versatile catalyst systems for selective aerobic oxidation of organic substrates. This report describes the catalytic mechanism of Pd(OAc)(2)/pyridine-mediated oxidation of benzyl alcohol, which has been studied by gas-uptake kinetic methods and (1)H NMR spectroscopy. The data reveal that turnover-limiting substrate oxidation by palladium(II) proceeds by a four-step pathway involving (1) formation of an adduct between the alcohol substrate and the square-planar palladium(II) complex, (2) proton-coupled ligand substitution to generate a palladium-alkoxide species, (3) reversible dissociation of pyridine from palladium(II) to create a three-coordinate intermediate, and (4) irreversible beta-hydride elimination to produce benzaldehyde. The catalyst resting state, characterized by (1)H NMR spectroscopy, consists of an equilibrium mixture of (py)(2)Pd(OAc)(2), 1, and the alcohol adduct of this complex, 1xRCH(2)OH. These in situ spectroscopic data provide direct support for the mechanism proposed from kinetic studies. The catalyst displays higher turnover frequency at lower catalyst loading, as revealed by a nonlinear dependence of the rate on [catalyst]. This phenomenon arises from a competition between forward and reverse reaction steps that exhibit unimolecular and bimolecular dependences on [catalyst]. Finally, overoxidation of benzyl alcohol to benzoic acid, even at low levels, contributes to catalyst deactivation by formation of a less active palladium benzoate complex. 相似文献
7.
A Cartesian decomposition of a coherent configuration is defined as a special set of its parabolics that form a Cartesian decomposition of the underlying set. It turns out that every tensor decomposition of comes from a certain Cartesian decomposition. It is proved that if the coherent configuration is thick, then there is a unique maximal Cartesian decomposition of ; i.e., there is exactly one internal tensor decomposition of into indecomposable components. In particular, this implies an analog of the Krull–Schmidt theorem for the thick coherent configurations. A polynomial-time algorithm for finding the maximal Cartesian decomposition of a thick coherent configuration is constructed. 相似文献
8.
9.
The effect of the micelles on the dynamic surface tension of micellar surfactant solutions is studied experimentally by means of the maximum bubble pressure method. Different frequencies of bubbling ranging approximately between 1 and 30 s–1 are applied. The time dependence of the surface tension is calculated using a dead time correction. Water solutions of two types of surfactants with different concentrations are investigated: sodium dodecyl sulfate and nonylphenol polyglycol ether. The surface tension relaxes more quickly in the presence of micelles. The characteristic times of relaxation of the surface tension seem to be in the millisecond range. The time constants observed experimentally are explained in terms of the theory of surfactant diffusion affected by micellization kinetics. 相似文献
10.
The reaction of spirobisilafluorene (1) with lithium in dimethoxyethane produces lithium 1-methyl-spirobisilafluorenide (2), a stable pentacoordinate silicon compound with five carbon ligands, and lithium 2-methoxyethoxide, which was identified by trapping with Ph3SiCl to give Ph3Si-OCH2CH2OCH3 (4). The X-ray crystal structure of 2 shows that the geometry at silicon is an idealized trigonal bipyramid, slightly distorted toward a square pyramid. Methanolysis of 2 cleaves a Si-aryl bond producing a methyl biphenylsilafluorene, 3. Crystal structures are reported for 3 and 4. 相似文献