Optimization of the synthesis of non-symmetrical alkyl dimethyl sulfonium halides |
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| Authors: | Ilia Sokka Andreas FischerLars Kloo |
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| Institution: | Inorganic Chemistry, School of Chemical Sciences and Engineering, Teknikringen 30, Royal Institute of Technology, Stockholm S-10044, Sweden |
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| Abstract: | This work is aimed at the optimization of the yield and purity of non-symmetrical trialkyl sulfonium halide salts. The effects of parameters such as solvent, temperature and concentration were studied. The products were carefully analyzed and the crystal structure of {n-CH3(CH2)15}(CH3)2S]Br determined. The overall aim of the present study is future syntheses of low-dimensional magnetic materials. |
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| Keywords: | Trialkyl sulfonium Alkylation Polar solvent Solvent enhancement |
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