全文获取类型
收费全文 | 807篇 |
免费 | 20篇 |
国内免费 | 5篇 |
专业分类
化学 | 597篇 |
晶体学 | 15篇 |
力学 | 13篇 |
数学 | 54篇 |
物理学 | 153篇 |
出版年
2023年 | 4篇 |
2021年 | 7篇 |
2020年 | 8篇 |
2019年 | 14篇 |
2018年 | 8篇 |
2017年 | 8篇 |
2016年 | 7篇 |
2015年 | 15篇 |
2014年 | 24篇 |
2013年 | 49篇 |
2012年 | 42篇 |
2011年 | 60篇 |
2010年 | 24篇 |
2009年 | 27篇 |
2008年 | 59篇 |
2007年 | 59篇 |
2006年 | 42篇 |
2005年 | 56篇 |
2004年 | 51篇 |
2003年 | 36篇 |
2002年 | 47篇 |
2001年 | 16篇 |
2000年 | 14篇 |
1999年 | 10篇 |
1998年 | 12篇 |
1997年 | 11篇 |
1996年 | 17篇 |
1995年 | 6篇 |
1994年 | 8篇 |
1993年 | 7篇 |
1992年 | 4篇 |
1990年 | 1篇 |
1989年 | 2篇 |
1988年 | 6篇 |
1987年 | 2篇 |
1986年 | 3篇 |
1985年 | 11篇 |
1984年 | 8篇 |
1983年 | 6篇 |
1982年 | 6篇 |
1981年 | 13篇 |
1980年 | 5篇 |
1979年 | 4篇 |
1978年 | 2篇 |
1976年 | 1篇 |
1975年 | 1篇 |
1973年 | 4篇 |
1969年 | 1篇 |
1968年 | 1篇 |
1960年 | 1篇 |
排序方式: 共有832条查询结果,搜索用时 78 毫秒
1.
Hirokazu Nishimura 《International Journal of Theoretical Physics》1995,34(2):211-228
The notion of a manual, introduced and investigated in detail by Foulis, Randall, and their followers, has turned out to be further reaching than its originators had envisaged. Its omnipresence is comparable with the notion of a sheaf, whose significance is well recognized by every pure and applied mathematician. The principal concern of this paper is to give an appropriate vehicle, as general as possible, by which the theory of manuals can be developed. The vehicle is called an orthogonal category, which is akin to the notion of a category with coproducts. Orthogonal categories provide also a new perspective on the notion of a sheaf over a complete Boolean algebra, deepening our comprehension of Boolean mathematics and paving the way to quantum mathematics. 相似文献
2.
Resonance-enhanced multiphoton ionization mass spectrometry using a two-color laser beam generated by stimulated Raman scattering. 总被引:2,自引:0,他引:2
Two-color (1+1') resonance-enhanced multiphoton ionization/time-of-flight mass spectrometry (REMPI/TOF-MS) combined with supersonic jet (SSJ) spectrometry has been demonstrated. The methodology uses a two-color laser beam consisting of a Stokes beam generated by stimulated Raman scattering (SRS) and a fundamental beam for the excitation and subsequent ionization of p-dichlorobenzene. The MPI signal was found to be substantially increased when a two-color laser beam was employed. This approach greatly simplifies the analytical system and reduces the cost of the instrumentation required for two-color ionization. The potential advantage of applying this method for the analysis of polychlorinated dibenzo-p-dioxin (PCDD) and polychlorinated dibenzofuran (PCDF) emitted from an incinerator is discussed. 相似文献
3.
4.
5.
Hirokazu Tezuka 《Zeitschrift fur Physik C Particles and Fields》1995,65(1):101-104
It is shown that the Dirac equation with attractive monomial vector potential cannot confine a particle. General polynomial type vector potential cannot confine a particle, either. This condition is not changed by a scalar potential smaller than the vector one. 相似文献
6.
T. Katsuki 《Russian Chemical Bulletin》2004,53(9):1859-1870
The recent development of asymmetric Baeyer—Villiger oxidation of prochiral and racemic ketones is briefly summarized, focusing on the regio- and stereocontrol of the oxidation attained by regulating the stereoelectronic demand in the step of rearrangement of the Criegee intermediate.Based on the report presented at the International Conference Modern Trends in Organoelement and Polymer Chemistry dedicated to the 50th anniversary of the A. N. Nesmeyanov Institute of Organoelement Compounds of the Russian Academy of Sciences (Moscow, May 30–June 4, 2004).Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 9, pp. 1784–1794, September, 2004. 相似文献
7.
Oishi S Kamano T Niida A Odagaki Y Hamanaka N Yamamoto M Ajito K Tamamura H Otaka A Fujii N 《The Journal of organic chemistry》2002,67(17):6162-6173
Diastereoselective synthesis of new psi[(E)-CH=CMe]- and psi[(Z)-CH=CMe]-type alkene dipeptide isosteres corresponding to dipeptides having one N-methylamino acid, and application to bioactive peptides, are described. In a key reaction introducing the chiral alpha-alkyl group of the isosteres, organocopper-mediated alkylation of syn-beta-methylated gamma-mesyloxy-alpha,beta-enoate 26a afforded E- and Z-isomers of anti-S(N)2' products in a solvent-dependent manner. The resulting two isosteres, D-Phe-psi[(E)-CH=CMe]-L-Val 27a and D-Phe-psi[(Z)-CH=CMe]-L-Val 28b, which corresponded to trans- and cis-conformers of D-Phe-L-MeVal, respectively, were utilized in a structure-activity relationship study on cyclic RGD peptides 1 and 2, in company with a psi[(E)-CH=CH]-type alkene dipeptide isostere, D-Phe-psi[(E)-CH=CH]-L-Val. The cyclic isostere-containing pseudopeptides 3, 4, and 40 were synthesized and biological activity against integrin alpha(V)beta(3) and alpha(IIb)beta(3) receptors were also evaluated. 相似文献
8.
Some novel physical ideas and mathematical techniques are described, useful in the development of effective Hamiltonian methods for studying molecular environmental effects. 相似文献
9.
Katsuki Kusakabe Kiyotaka IchikiJun-ichiro Hayashi Hideaki MaedaShigeharu Morooka 《Journal of membrane science》1996
Silica-polyimide microcomposite membranes were prepared on γ-alumina-coated α-alumina support tubes, and their gas permeation properties were evaluated with He, N2 and CO2. Smoothing of the substrate surface and hybridization of silica and polyamic acid were both effective to form defect-free thin composite membranes. The CO2 permeance of a membrane with a silica content of 68 wt% was one order of magnitude higher than that of a polyimide membrane having the same thickness. The permselectivity of CO2 to N2 was 30 at 30°C and 13 at 100°C. Contributions of the silica and polyimide phases to permeance of the composite membrane were analyzed with a two-phase permeation model. The effective thickness of the rate-controlling polyimide phase was less than one-tenth of the total thickness of the silica-polyimide membrane. 相似文献
10.
Komatsu H Citterio D Fujiwara Y Minamihashi K Araki Y Hagiwara M Suzuki K 《Organic letters》2005,7(14):2857-2859
[structure: see text] The jewel pendant ligand has multiple chromogenic units combined in a single molecule with the dyes linked to a semiselective binding site by three heteroatoms (O, N, S) having different HSAB characteristics, to indicate diverse response to individual transition metal ions. Using a single-molecular multianalyte sensor, multiple analytes could be determined with a minimal sensing system. 相似文献