排序方式: 共有29条查询结果,搜索用时 23 毫秒
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Free-standing frequency-selective surfaces consisting of approximately 10-microm-thick copper films with cross-aperture arrays are found to be tunable toward lower frequencies by means of wet chemical etching. Center frequencies were tuned from 1.57 to 1.53 THz while maintaining high transmittance. Wet etching also adjusts bandwidth, peak transmittance, and sidelobe transmittance. The advantage of the wet-etch technique is demonstrated by employment of these devices as bandpass filters for difluoromethane-based terahertz lasers. Adjustment in aperture dimensions because of etching results in suppression of a competing laser line (133.93 microm) by 15 dB while maintaining high transmittance at the operating wavelength of 192.06 microm. 相似文献
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制备了甘氨酸-壳聚糖复合膜修饰玻碳电极(Gly-CTS/GCE),研究了抗坏血酸(AA)和尿酸(UA)在该修饰电极上的电化学行为。结果表明在pH=5.59的磷酸盐缓冲溶液中,AA、UA在Gly-CTS/GCE上均产生灵敏的不可逆氧化峰,其峰电流与浓度在一定范围内呈良好的线性关系。对AA和UA混合溶液平行测定7次,相对标准偏差分别为4.6%、2.9%,表明该电极重现性和稳定性良好。AA、UA在Gly-CTS/GCE电极上的氧化峰峰电位相差340mV,据此可实现对二者的同时检测,并可应用于实际样品测定。 相似文献
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C70X2(X=H,F, Cl)的稳定性和电子光谱 总被引:1,自引:0,他引:1
用INDO方法研究C70H2四种异构体的稳定性, 表明其最稳定异构体为1, 9-C70H2和7, 8-C70H2, 两者能量差为16.3KJ.mol^-^1, 与实验值及ab initio计算值接近; 光谱计算表明, 其特征吸收峰与实验值一致。在此基础上预测C70F2和C70Cl2的稳定性和电子光谱, 表明C70F2四种异构体的稳定性顺序与C70H2一致, 而C70Cl2则以21, 42-异构体最为稳定。二者的电子光谱与C70H2极其相似只是在500nm以上有细微差别。 相似文献
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The combination of directed C-H activation, batch-wise addition of tetraalkyltin reagents, and rate enhancement by benzoquinone and microwave irradiation provides a promising strategy for the direct coupling of C-H bonds with organometallic reagents. A variety of tetraalkyltins were coupled to C-H bonds to give the alkylated products in good yields by using 5 mol % Pd(OAc)2 as the catalyst. Benzoquinone was shown to be essential for the C-H activation when substrates containing non-pi-conjugated chelating groups are used. Monitoring the formation and reductive elimination of the Pd(Ar)(Me)L2 complex also revealed that benzoquinone promotes the reductive elimination step. Microwave irradiation enhances the reaction rate drastically. The versatility of this protocol was demonstrated by using substrates containing either oxazoline or pyridine as directing groups. 相似文献
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Adams DC Inampudi S Ribaudo T Slocum D Vangala S Kuhta NA Goodhue WD Podolskiy VA Wasserman D 《Physical review letters》2011,107(13):133901
We present a comprehensive study of enhanced light funneling through a subwavelength aperture with realistic (lossy) epsilon-near-zero (ENZ) materials. We realize experimentally an inclusion-free ENZ material layer operating at optical frequencies and characterize its performance. An analytical expression describing light funneling through several structures involving ENZ coupling layers is developed, validated with numerical solutions of Maxwell equations, and utilized to relate the performance of the ENZ coupling systems to their main limiting factor, material losses. 相似文献
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Gorham PW Barwick SW Beatty JJ Besson DZ Binns WR Chen C Chen P Clem JM Connolly A Dowkontt PF DuVernois MA Field RC Goldstein D Goodhue A Hast C Hebert CL Hoover S Israel MH Kowalski J Learned JG Liewer KM Link JT Lusczek E Matsuno S Mercurio B Miki C Miocinović P Nam J Naudet CJ Ng J Nichol R Palladino K Reil K Romero-Wolf A Rosen M Ruckman L Saltzberg D Seckel D Varner GS Walz D Wu F;ANITA Collaboration 《Physical review letters》2007,99(17):171101
We report on observations of coherent, impulsive radio Cherenkov radiation from electromagnetic showers in solid ice. This is the first observation of the Askaryan effect in ice. As part of the complete validation process for the ANITA experiment, we performed an experiment at the Stanford Linear Accelerator Center in June 2006 using a 7.5 metric ton ice target. We measure for the first time the large-scale angular dependence of the radiation pattern, a major factor in determining the solid-angle acceptance of ultrahigh-energy neutrino detectors. 相似文献
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