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1.
2.
A. Ferreira da Silva I. Pepe S.A. Tomás W.M. de Azevedo R. Ahuja 《Applied Surface Science》2006,252(15):5365-5367
In this paper we present spectroscopic properties of doped and undoped titanium dioxide (TiO2) as nanofilms prepared by the sol-gel process with rhodamine 6G doping and studied by photoacoustic absorption, excitation and emission spectroscopy. The absorption spectra of TiO2 thin films doped with rhodamine 6G at very low concentration during their preparation show two absorption bands, one at 2.3 eV attributed to molecular dimmer formation, which is responsible for the fluorescence quenching of the sample and the other at 3.0 eV attributed to TiO2 absorption, which subsequently yields a strong emission band at 600 nm. The electronic band structure and optical properties of the rutile phase of TiO2 are calculated employing a fully relativistic, full-potential, linearized, augmented plane-wave (FPLAPW) method within the local density approximation (LDA). Comparison of this calculation with experimental data for TiO2 films prepared for undoped sol-gels and by sputtering is performed. 相似文献
3.
Supply Chain Management (SCM) is an important activity in all producing facilities and in many organizations to enable vendors,
manufacturers and suppliers to interact gainfully and plan optimally their flow of goods and services. To realize this, a
dynamic modelling approach for characterizing supply chain activities is opportune, so as to plan efficiently the set of activities
over a distributed network in a formal and scientific way. The dynamical system will result so complex that it is not generally
possible to specify the functional forms and the parameters of interest, relating outputs to inputs, states and stochastic
terms by experiential specification methods. Thus the algorithm that will presented is Data Driven, determining simultaneously
the functional forms, the parameters and the optimal control policy from the data available for the supply chain. The aim
of this paper is to present this methodology, by considering dynamical aspects of the system, the presence of nonlinear relationships
and unbiased estimation procedures to quantify these relations, leading to a nonlinear and stochastic dynamical system representation
of the SCM problem. Moreover, the convergence of the algorithm will be proved and the satisfaction of the required statistical
conditions demonstrated. Thus SCM problems may be formulated as formal scientific procedures, with well defined algorithms
and a precise calculation sequence to determine the best alternative to enact. A “Certainty equivalent principle” will be
indicated to ensure that the effects of the inevitable uncertainties will not lead to indeterminate results, allowing the
formulation of demonstrably asymptotically optimal management plans. 相似文献
4.
Andrea Bianco Giacomo Iardino Chiara Bertarelli Luciano Miozzo Giuseppe Zerbi 《Applied Surface Science》2007,253(20):8360-8364
Polyamide 6 (PA6) nanofibers were prepared from formic acid solutions by using electrospinning technique. The fibers were smooth, defects free and with diameters smaller than 200 nm. Small amounts of a perfluorinated acridine were added as dopant to the feed solution to modify the wettability of the fibers. The effect of doping on the contact angle values is well apparent. The contact angle values go from 50° of pure PA6 to 120° when 6% of acridine is added. A comparison between fibers and films of pure and doped polyamide 6 was carried out in order to determine the effect of morphology on wettability. Thermal annealing near the Tg of the polymer promoted the segregation of the molecules to the surface, reaching contact angles of 131° with smaller amounts (4%) of acridine. The surface segregation was also promoted by time aging. 相似文献
5.
Valentina Domenici Carlo Alberto Veracini Katalin Fodor-Csorba Giacomo Prampolini Ivo Cacelli Andrjia Lebar Bostjan Zalar 《Chemphyschem》2007,8(16):2321-2330
The orientational properties of the banana-shaped liquid crystal 4-chloro-1,3-phenylenebis{4-[4'-(10-undecenyloxy)]benzoyloxy} benzoate (ClPbis11BB) are reported in the nematic phase under the effect of an external magnetic field. A new hypothesis, which states that the central ring of the aromatic core is oriented perpendicularly to the external magnetic field, is proposed. In support of this hypothesis, a series of studies based on (2)H NMR spectroscopy, both in the bulk and in solution, are discussed. (2)H NMR measurements on three selectively deuterium-labelled isotopomers are presented, together with DFT results from B3LYP/cc-pvDz calculations performed on the aromatic core. The rather flat shape of the investigated intramolecular energy surface allows for several different conformations to be populated, the computed magnetic susceptibilities of which are consistent with the proposed hypothesis of peculiar orientation of banana-shaped molecules. Moreover, the orientation of the magnetic susceptibility tensor is shown to be strongly dependent on the internal conformation of the banana-shaped molecules. 相似文献
6.
Bossée A Afonso C Fournier F Tasseau O Pepe C Bellier B Tabet JC 《Journal of mass spectrometry : JMS》2004,39(8):903-912
Peptide metallation with Cu2+ was explored in the negative ESI mode using an ion trap mass spectrometer. Under these conditions, the [(M-3H) + CuII]- species formed were investigated under low-energy collision-induced dissociation conditions. MS2 experiments indicate a very different behavior of CuII metallated complexes compared with [M-H]- species. CuII induces an easy loss of CO2 and specific side-chain cleavages (by radical losses) at the C-terminal residue, as observed previously by prompt 'in source' dissociation experiments. The loss of CO2 yields an unstable carbylide that leads to further dissociations involving the migration of a proton or a hydrogen radical (through the reduction of CuII). Multistage MS3 experiments were carried out to rationalize this behavior. Fragmentation pathways are proposed in order to explain the product ions observed. The side-chain radical loss at the C-terminus was demonstrated to be a consecutive process. Finally, evidence is provided that the specific side-chain cleavages can be used for the differentiation of Leu/Ile and Gln/Lys residues when they are located at the C-terminus. The existence of a zwitterionic form in the case of the anionic YGGFK-CuII complex is proposed. 相似文献
7.
Diego Di Girolamo Francesco Di Giacomo Fabio Matteocci Andrea Giacomo Marrani Danilo Dini Antonio Abate 《Chemical science》2020,11(30):7746
The power conversion efficiency (PCE) of NiO based perovskite solar cells has recently hit a record 22.1% with a hybrid organic–inorganic perovskite composition and a PCE above 15% in a fully inorganic configuration was achieved. Moreover, NiO processing is a mature technology, with different industrially attractive processes demonstrated in the last few years. These considerations, along with the excellent stabilities reported, clearly point towards NiO as the most efficient inorganic hole selective layer for lead halide perovskite photovoltaics, which is the topic of this review. NiO optoelectronics is discussed by analysing the different doping mechanisms, with a focus on the case of alkaline and transition metal cation dopants. Doping allows tuning the conductivity and the energy levels of NiO, improving the overall performance and adapting the material to a variety of perovskite compositions. Furthermore, we summarise the main investigations on the NiO/perovskite interface stability. In fact, the surface of NiO is commonly oxidised and reactive with perovskite, also under the effect of light, thermal and electrical stress. Interface engineering strategies should be considered aiming at long term stability and the highest efficiency. Finally, we present the main achievements in flexible, fully printed and lead-free perovskite photovoltaics which employ NiO as a layer and provide our perspective to accelerate the improvement of these technologies. Overall, we show that adequately doped and passivated NiO might be an ideal hole selective layer in every possible application of perovskite solar cells.The power conversion efficiency of NiO based perovskite solar cells has recently hit a record 22.1%. Here, the main advances are reviewed and the role of NiO in the next breakthroughs is discussed. 相似文献
8.
Sandra Ristori Grard Gebel Giacomo Martini 《Colloids and surfaces. A, Physicochemical and engineering aspects》1993,80(2-3):113-120
The aggregation properties of ammonium perfluorooctanoate (NH4-PFO) in concentrated aqueous phases have been investigated by magnetic resonance techniques and have been compared with the aggregation properties in dilute solutions. Magnetic resonance methods indicated that NH4-PFO—water systems with surfactant concentrations below 45% (w/w) behaved as isotropic purely micellar solutions in the temperature range 285–340 K. For higher concentrations the system exhibited a rather complex structure, having both isotropic and anisotropic components. The nematic nature of the anisotropic fraction was demonstrated by 19F NMR studies. The 19F NMR and EPR of nitroxides (TempTMA+, 5- and 16-DXSA) inserted as paramagnetic probes into the concentrated NH4-PFO—water systems allowed us to establish that the lamellar phase could be mechanically oriented between quartz slides. The EPR investigation also gave details concerning the dynamics of both the oriented and non-oriented structures. 相似文献
9.
AISI 304 Stainless Steel is widely used in different industrial fields because of its mechanical and corrosion properties.
However, its tendency to corrosion in presence of halide ions limits the applications. One strategy to improve the corrosion
resistance is the use of coatings barriers containing corrosion inhibitors in their formulation. The lanthanides present attractive
green and corrosion properties for the substitution of chromates, which are the most common substances used as corrosion protection.
However, these compounds are highly toxic, and an intense effort is being undertaken to replace them. Cerium is a good alternative
because of its relatively low cost and abundance. It fulfils the basics requirements for being considered an alternative inhibitor:
the ions form insoluble hydroxides and they present low toxicity. Inorganic and hybrid sol-gel coatings have been developed
to increase the corrosion resistance of metals and they provide an excellent vehicle for the incorporation of secondary phases
including particles and metal ions as cerium ions.
The aim of this work was to study the influence of the incorporation of cerium ions in hybrid silica sol-gel coatings deposited
on AISI 304 stainless steel as substrate as a potential replacement of chromate treatments. This system should combine the
barrier protection effect of silica coating with the corrosion inhibitor effect of the cerium ions inside the coatings. After
7 days of immersion in NaCl, coated substrates showed lower current densities than the bare steel, although the coatings produced
from Ce (III) salts experience a slight weakening in time and those obtained from Ce (IV) chemicals evidence an enhance in
the coating performance, probably due to the plugging of corrosion products in the defective areas of the film. 相似文献
10.
Mechanical properties decay and morphological behaviour of biodegradable films for agricultural mulching in real scale experiment 总被引:1,自引:0,他引:1
Giacomo Scarascia-Mugnozza Giuliano Vox Barbara Immirzi 《Polymer Degradation and Stability》2006,91(11):2801-2808
The use of plastic materials in agriculture causes the serious drawback of huge quantities of waste. The introduction of biodegradable materials, which can be disposed directly into the soil, can be one possible solution to this problem. Biodegradable materials are actually innovative materials; therefore, their physical properties must be evaluated in relation to their functionality during the use in field. In the present research results of experimental tests carried out on biodegradable films used in strawberries protected cultivation are presented. The decay of some relevant physical parameters of biodegradable films during the cultivation period was monitored by laboratory tests (SEM analysis, mechanical tensile tests and infrared reflectance spectroscopy). Infrared spectroscopy clearly indicated that the mechanical degradation starts from the starch component of the material. Tensile tests showed that the value of elongation at break of biodegradable materials decreased in some cases by 300% after 10 days of field application. 相似文献