Composition spread metal thin film fabrication technique based on ion beam sputter deposition

A composition spread metal thin film fabrication technique based on ion beam sputter deposition method was developed. The technique enables us to fabricate any desired part or a complete binary/ternary composition spread metal thin films onto a single substrate by sequentially sputtering different target materials. Composition spread metal thin films can be deposited directly on a dielectric film in patterned electrode shape for C-V and I-V measurements. The system could be especially useful in the search for new multi-component metal gate materials.     

Ammonium chiral borate salt catalyzed asymmetric Friedel-Crafts alkylation of indoles with α,β-disubstituted enals

In the presence of a catalytic amount of ammonium chiral borate salt, asymmetric Friedel-Crafts alkylation of indoles with α,β-disubstituted enals proceeded to give the corresponding 1,4-addition products with moderate enantioselectivities.     

Production of Acetone–Butanol–Ethanol (ABE) in Direct Fermentation of Cassava by Clostridium saccharoperbutylacetonicum N1-4

In this work, acetone–butanol–ethanol (ABE) fermentation characteristics of cassava starch and cassava chips when using Clostridium saccharoperbutylacetonicum N1-4 was presented. The obtained results in batch mode using a 1-L fermenter showed that C. saccharoperbutylacetonicum N1-4 was a hyperamylolytic strain and capable of producing solvents efficiently from cassava starch and cassava chips, which was comparable to when glucose was used. Batch fermentation of cassava starch and cassava chips resulted in 21.0 and 19.4 g/L of total solvent as compared with 24.2 g/L of total solvent when using glucose. Solvent productivity in fermentation of cassava starch was from 42% to 63% higher than that obtained in fermentation using corn and sago starches in the same condition. In fermentation of cassava starch and cassava chips, maximum butanol concentration was 16.9 and 15.5 g/L, respectively. Solvent yield and butanol yield (based on potential glucose) was 0.33 and 0.41, respectively, for fermentation of cassava starch and 0.30 and 0.38, respectively for fermentation using cassava chips.     

Non-decoupling effects in supersymmetric Higgs sectors

A wide class of Higgs sectors is investigated in supersymmetric standard models. When the lightest Higgs boson (h  ) looks the standard model one, the mass (mh$m_h$) and the triple Higgs boson coupling (the hhh   coupling) are evaluated at the one-loop level in each model. While mh$m_h$ is at most 120–130 GeV in the minimal supersymmetric standard model (MSSM), that in models with an additional neutral singlet or triplet fields can be much larger. The hhh coupling can also be sensitive to the models: while in the MSSM the deviation from the standard model prediction is not significant, that can be 30–60% in some models such as the MSSM with the additional singlet or with extra doublets and charged singlets. These models are motivated by specific physics problems like the μ-problem, the neutrino mass, the scalar dark matter and so on. Therefore, when h   is found at the CERN Large Hadron Collider, we can classify supersymmetric models by measuring mh$m_h$ and the hhh coupling accurately at future collider experiments.     

Doubly-charged scalar bosons from the doublet

We consider the extended Higgs models, in which one of the isospin doublet scalar fields carries the hypercharge Y=3/2. Such a doublet field Φ3/2 is composed of a doubly charged scalar boson as well as a singly charged one. We first discuss a simple model with Φ3/2 (Model I), and study its collider phenomenology at the LHC. We then consider a new model for radiatively generating neutrino masses with a dark matter candidate (Model II), in which Φ3/2 and an extra Y=1/2 doublet as well as vector-like singlet fermions carry the odd quantum number for an unbroken discrete Z₂ symmetry. We also discuss the neutrino mass model (Model III), in which the exact Z₂ parity in Model II is softly broken. It is found that the doubly charged scalar bosons in these models show different phenomenological aspects from those which appear in models with a Y=2 isospin singlet field or a Y=1 triplet one. They could be clearly distinguished at the LHC.     

Unconventional Magnetic and Resistive Hysteresis in an Iodine‐Bonded Molecular Conductor

Simultaneous manipulation of both spin and charge is a crucial issue in magnetic conductors. We report on a strong correlation between magnetism and conductivity in the iodine‐bonded molecular conductor (DIETSe)₂FeBr₂Cl₂ [DIETSe=diiodo(ethylenedithio)tetraselenafulvalene], which is the first molecular conductor showing a large hysteresis in both magnetic moment and magnetoresistance associated with a spin‐flop transition. Utilizing a mixed‐anion approach and iodine bonding interactions, we tailored a molecular conductor with random exchange interactions exhibiting unforeseen physical properties.     

Use of ring-repeller, double-skimmer electrodes for efficient ion focusing in mass spectrometry.

The design and construction of a new type of time-of-flight mass spectrometer is described. The instrument was designed to improve the ionization efficiency and to efficiently detect ions. The system performance was evaluated using the SIMION software, and was compared with the experimental results. The shapes of the repeller, extraction, and ground electrodes had a strong effect on the trajectory of ions in the processes of ion acceleration and focusing. The major difference between the theory and the experiment can be attributed to space-charge effects.     

无水肼水含量标准物质分装技术研究

为寻找高效、安全、少污染的无水肼水含量标准物质分装方法，对无水肼水含量标准物质的灌装技术和封口技术进行了分析，比较了3种封口技术的优缺点，对压制封口垫片与无水肼的相容性及渗透情况进行了试验。综合考虑无水肼的特殊性、分装过程的安全性、密封性、实用性等，确定采用压制封口技术，使用M242橡胶材料作为垫片。