排序方式: 共有12条查询结果,搜索用时 265 毫秒
1.
G. Račiukaitis S. Grubinskas P. Gečys M. Gedvilas 《Applied Physics A: Materials Science & Processing》2013,110(1):93-98
Selectiveness of the laser processing is the top-most important for applications of the processing technology in thin-film electronics, including photovoltaics. Coupling of laser energy in multilayered thin-film structures, depending on photo-physical properties of the layers and laser wavelength was investigated experimentally and theoretically. Energy coupling within thin films highly depends on the film structure. The finite element and two-temperature models were applied to simulate the energy and temperature distributions inside the stack of different layers of a thin-film solar cell during a picosecond laser irradiation. Reaction of the films to the laser irradiation was conditioned by optical properties of the layers at the wavelength of laser radiation. Simulation results are consistent with the experimental data achieved in laser scribing of copper-indium-gallium diselenide (CIGS) solar cells on a flexible polymer substrate using picosecond-pulsed lasers. Selection of the right laser wavelength (1064 nm or 1572 nm) enabled keeping the energy coupling in a well-defined volume at the interlayer interface. High absorption at inner interface of the layers triggered localized temperature increase. Transient stress caused by the rapid temperature rise facilitating peeling of the films rather than evaporation. Ultra-short pulses ensured high energy input rate into absorbing material permitting peeling of the layers with no influence on the remaining material. 相似文献
2.
P. Ge?ys G. Ra?iukaitis M. Ehrhardt K. Zimmer M. Gedvilas 《Applied Physics A: Materials Science & Processing》2010,101(2):373-378
Continuous growth of the thin-film electronics market stimulates the development of versatile technologies for large-scale
patterning of thin-film materials on rigid and flexible substrates, and laser technologies are a promising method to accomplish
the scribing processes. Lasers with picosecond pulse duration were applied in scribing of complex multilayered CuIn
x
Ga(1−x)Se2 (CIGS) solar cells deposited on a polyimide substrate. The ablative properties of the films were examined as a function of
the wavelength of laser radiation, pulse energy, and the irradiation dose. The selective removal of ITO and CIGS layers was
achieved with 355 nm irradiation without any significant damage to the underlying layers in the ITO/CIGS/Mo/PI solar cell
system. The 355 nm wavelength was also found to be favorable for scribing of absorber layer in a ZnO/CIGS/Mo/PI solar cell
system. 266 nm radiation significantly modified the film structure due to high absorption. Extensive melt formation in the
CIGS layer was found when 532 nm radiation was applied, though the trenches were smooth and crack-free. 相似文献
3.
Tucker Melvin P. Mitri Ragheed K. Eddy Fannie P. Nguyen Q. A. Gedvilas Lynn M. Webb John D. 《Applied biochemistry and biotechnology》2000,84(1-9):39-50
The process of converting renewable lignocellulosic biomass to ethanol requires a number of steps, and pretreatment is one
of the most important. Pretreatment usually in volves a hydrolysis of the easily hydrolyzed hemicellulosic component of biomass
using some form of thermal/chemical/mechanical action that results in a product that can be further hydrolyzed by cellulase
enzymes (the cellulosic portion). The sugars produced can then befermented to ethanol by fermentative microorganisms. If the
pretreatment step is not severe enough, the resultant residue is not as easily hydrolyzed by the cellulase enzyme. More severe
pretreatment conditions result in the production of degradation products that are toxic to the fermentative microorgan ism.
In this article, wereport the quantitative analysis of glucose, mannose, xylose, and acetic acid using Fourier transform infrared
(FTIR) spectroscopy on liquors from dilute-acid-pretreated softwood and hard wood slurries. Comparison of FTIR and high-performance
liquid chromatography quantitative analyses of these liquorsare reported. Recent developments in infrared probe technology
has enabled the rapid quantification of these sugars by FTIR spectroscopy in the batch reactor during optimization of the
pretreatment conditions, or interfaced to the computer controlling a continuous reactor for on-line monitoring and control. 相似文献
4.
K?stutis Regelskis Gediminas Ra?iukaitis Mindaugas Gedvilas 《Applied Surface Science》2007,253(15):6584-6587
The beam of a nanosecond pulse laser tightly focused to a line was applied for the back-side ablation of the chromium thin film on a glass substrate. The stripe ablated with a single laser pulse had sharp edges on both sides and ridges of the melted metal around it. The partially overlapping pulses formed a wide cleaned area with a complicated structure made of the metal remaining from the ridges. Regular structures, ripples, were developed when laser fluence was slightly above the single-pulse removal threshold and the shift between pulses was less than half width of the line ablated with a single laser pulse. The ripples were located periodically (∼4 μm) and were orientated perpendicularly to the long axis of the beam spot. Their orientation did not depend on the laser beam polarization. Different models of the ripple formation in the thin metal film were considered, and instability of the moving vapor-liquid-solid contact line during evaporation of thin liquid films appears to be the most probable process responsible for the observed phenomena. Formation of regular gratings with the unlimited line length was experimentally implemented by using the above-mentioned technique. 相似文献
5.
R.N. Bhattacharya K. Ramanathan L. Gedvilas B. Keyes 《Journal of Physics and Chemistry of Solids》2005,66(11):1862-1864
Cu(In,Ga)Se2 (CIGS) solar cell junctions prepared by chemical-bath-deposited (CBD) ZnS(O,OH), Zn-Cd-S(O,OH), and CdS buffer layers are discussed in this paper. The device performances are compared by applying CBD ZnS(O,OH), CBD Zn-Cd-S(O,OH), and CBD CdS buffer layers on similar CIGS absorbers. The CN impurities in CBD ZnS(O,OH) are identified with Fourier transform infrared spectroscopy (FTIR) techniques. The impurities containing carbon-nitrogen bonds are most likely cyanamide (NCN2−) or thiocyanate (SCN−), which resulted from the chemical reaction of thiourea and ammonia. 相似文献
6.
Evaldas Stankevičius Mantas Garliauskas Mindaugas Gedvilas Nikolai Tarasenko Gediminas Račiukaitis 《Annalen der Physik》2017,529(12)
Here, the structuring of surfaces with gold nanoparticles by using Bessel‐like beam array is demonstrated. The experimental results show that the fabricated microring structures containing gold nanoparticles have a surface plasmon resonance in the spectral range of 520–540 nm, which can be tuned by selecting the laser treatment parameters. Fabricated microring structures exhibit a lower light transmittance comparing with the randomly distributed gold nanoparticles for wavelengths 500–570 nm due to the growth in the size of nanoparticles. In the spectral range of 600–700 nm, the light transmittance through microring structures is higher compared with the randomly distributed gold nanoparticles because of the removal of gold nanoparticles as gold has high reflectivity for wavelengths longer than 600 nm. The demonstrated method enables an easy fabrication of microring structures having tunable plasmonic properties. 相似文献
7.
8.
Modifications in thin metal films under intensive laser irradiation were studied. Gold, silver, copper, chromium and aluminum films with the thickness of 100 nm were deposited on the glass substrate. Back-side irradiation through the substrate with a burst of nanosecond pulses tightly focused to a line was applied. The film removal threshold with a single pulse Fth was estimated for every material and laser fluence was kept above it in the range of 1.5-3 Fth during experiments. Diverse behavior of the films depending on the metal, the shift between pulses and laser fluence was observed. In chromium, the regular structures were developed in a quite wide range of processing parameters. In gold, three kinds of ripples were observed: transverse (similar to ripples in chromium), longitudinal and a structure of ripples oriented at 60° to each other. The combination of physical properties facilitated the regular assembly of the molten metal in chromium and to some extent in gold. 相似文献
9.
M. Gedvilas G. Račiukaitis K. Regelskis 《Applied Physics A: Materials Science & Processing》2008,93(1):203-208
Self-organization of chromium on glass was observed during laser ablation of the metal film with partially overlapping laser
pulses. The beam of a nanosecond pulse laser tightly focused to a line was applied to the back-side ablation of the chromium
thin film on a glass substrate. While the line ablated with a single laser pulse had sharp edges on both sides with ridges
of the melted metal, the use of partially overlapping pulses formed a complicated structure made of the metal remaining from
the ridges. Regular structures of ripples were developed in a certain range of laser fluence and pulse overlap. The ripple
period could be controlled from 2.5 to 4 μm by variation of the processing parameters. Various experimental techniques were
applied to test the structures, and different models of the ripple formation in the thin metal film were considered. The initial
quasi-periodical formation started because of dewetting of thin liquid metal films on the glass substrate after its melting.
Similar to the evaporation of liquid films, the small perturbation in the ridge thickness was able to induce instability in
evaporation of the thin melted metal film. Freezing of the nonequilibrium state between laser pulses was one of the stabilizing
factors in self-organization of the metal. 相似文献
10.
Gediminas Ra?iukaitis Marijus Brikas Mindaugas Gedvilas Tomas Rakickas 《Applied Surface Science》2007,253(15):6570-6574
The results of patterning of the indium-tin oxide (ITO) film on the glass substrate with high repetition rate picosecond lasers at various wavelengths are presented. Laser radiation initiated the ablation of the material, forming grooves in ITO. Profile of the grooves was analyzed with a phase contrast optical microscope, a stylus type profiler, scanning electron microscope (SEM) and atomic force microscope (AFM). Clean removal of the ITO film was achieved with the 266 nm radiation when laser fluence was above the threshold at 0.20 J/cm2, while for the 355 nm radiation, the threshold was higher, above 0.46 J/cm2. The glass substrate was damaged in the area where the fluence was higher than 1.55 J/cm2. The 532 nm radiation allowed getting well defined grooves, but a lot of residues in the form of dust were generated on the surface. UV radiation with the 266 nm wavelength provided the widest working window for ITO ablation without damage of the substrate. Use of UV laser radiation with fluences close to the ablation threshold made it possible to minimize surface contamination and the recast ridge formation during the process. 相似文献