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New complexes {M(CO)4[Ph2P(S)P(S)Ph2]} (M = Cr, Mo and W), (1a)–(3a), [(1a), M = Cr; (2a), M = Mo; (3a), M = W] and {M2(CO)10[-Ph2P(S)P(S)Ph2]} (M = Cr, Mo, W), [(1b)–(3b) [(1b), M = Cr; (2b), M = Mo; (3b), M = W]] have been prepared by the photochemical reaction of M(CO)6 with Ph2P(S)P(S)Ph2 and characterized by elemental analyses, f.t.-i.r. and 31P-(1H)-n.m.r. spectroscopy and by FAB-mass spectrometry. The spectra suggest cis-chelate bidentate coordination of the ligand in {M(CO)4[Ph2P(S)P(S)Ph2]} and cis-bridging bidentate coordination of the ligand between two metals in (M = Cr, Mo and W). 相似文献
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?zdemir ümmühan Karacan Nurcan ?entürk Ozan Sanlι Sert Sema U?ur Fadime 《Transition Metal Chemistry》2003,28(4):443-446
Five new complexes, [M(CO)5(apmsh)] [M = Cr; (1), Mo; (2), W; (3)], [Re(CO)4Br(apmsh)] (4) and [Mn(CO)3(apmsh)] (5) have been synthesized by the photochemical reaction of metal carbonyls [M(CO)6] (M = Cr, Mo and W), [Re(CO)5Br], and [Mn(CO)3Cp] with 2-hydroxyacetophenone methanesulfonylhydrazone (apmsh). The complexes have been characterized by elemental analysis, mass spectrometry, f.t.-i.r. and 1H spectroscopy. Spectroscopic studies show that apmsh behaves as a monodentate ligand coordinating via the imine N donor atom in [M(CO)5(apmsh)] (1–4) and as a tridentate ligand in (5). 相似文献
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Positivity - Many researchers have been interested in the concept of statistical convergence because of the fact that it is stronger than the classical convergence. Also, the concepts of... 相似文献
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Fadime Üney-Yüksektepe 《Central European Journal of Operations Research》2014,22(3):553-565
In data mining, binary classification has a wide range of applications. Cutting Decision Tree (CDT) induction is an efficient mathematical programming based method that tries to discretize the data set on hand by using multiple separating hyperplanes. A new improvement to CDT model is proposed in this study by incorporating the second goal of maximizing the distance of the correctly classified instances to the misclassification region. Computational results show that developed model achieves better classification accuracy for Wisconsin Breast Cancer database and Japanese Banks data set when compared to existing piecewise-linear models in literature. Furthermore, remarkable results are obtained for the well-known benchmarking data sets (Buba Liver Disorders, Blood Tranfusion and Pima Indian Diabetes) when compared to the original CDT model. 相似文献
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Sevda Yldz Fadime Dirik Kamil Demirci 《Mathematical Methods in the Applied Sciences》2019,42(16):5371-5382
In this paper, we study the Korovkin type approximation theorem for Ka‐ convergence, which is an interesting convergence method on weighted spaces. We also study the rate of Ka?convergence by using the weighted modulus of continuity and afterwards, we present a nontrivial application. 相似文献
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Positivity - We prove a Korovkin-type approximation theorem using the relative uniform convergence of a sequence of functions at a point, which is a method stronger than the classical ones. We give... 相似文献
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Mustafa Germec Fadime Demirel Nurullah Tas Ali Ozcan Cansu Yilmazer Zeynep Onuk Irfan Turhan 《Cellulose (London, England)》2017,24(10):4337-4353
Microwave-assisted pretreatment can be used for fermentable sugar production from lignocellulosic biomass. In this study, the optimum hydrolysis conditions of barley husk, oat husk, wheat bran, and rye bran were determined in power level, treatment time, solid-to-liquid ratio and dilute acid ratio as follows: 700 W, 6.92 min, 1:18.26 w/v, and 3.67% for barley husk, 600 W, 6.96 min, 1:17.22 w/v, and 3.47% for oat husk, 600 W, 6.92 min, 1:16.69 w/v, and 1.85% for wheat bran, and 460 W, 6.15 min, 1:17.14 w/v, and 2.72% for rye bran. The fermentable sugar concentrations were 37.21 (0.68 g/g), 38.84 (0.67 g/g), 49.65 (0.83 g/g), and 36.27 g/L (0.62 g/g) under optimum conditions, respectively. The results showed that microwave-assisted pretreatment is a promising technology which can be successfully implemented for the hydrolysis of lignocellulosic biomass for high sugar yield. On the other hand, hydrolysates included some inhibitors such as organic acids, furans, and phenolic compounds. Lignocellulosic biomass used in this study can be employed as good feedstocks for value-added product production in the fermentation process, after the inhibitors have been detoxified/removed with different detoxification methods. 相似文献
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The new complexes fac-[Re(CO)3Br{Ph2P(CH2)
n
PPh2}] (1a–3a) [(1a), n = 1; (2a), n = 2; (3a), n = 3] and [Re2(CO)8Br2{-Ph2P(CH2)
n
PPh2}] (1b–3b) [(1b), n = 1; (2b), n = 2; (3b), n = 3] have been prepared by the photochemical reaction of Re(CO)5Br with Ph2P(CH2)
n
PPh2 (n = 1, dppm; 2, dppe; 3, dppp). The complexes have been characterized by elemental analysis, mass spectroscopy, f.t.-i.r. and 31P-[1H]-n.m.r. spectrometry. The spectroscopic studies suggest cis-chelate bidentate coordination of the ligand in fac-[Re(CO)3Br{Ph2P(CH2)
n
PPh2}] (1a–3a) and cis-bridging bidentate coordination of the ligand between two metals in [Re2(CO)8Br2{cis--Ph2P(CH2)
n
PPh2}] (1a–3a). 相似文献