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Rapid determination of volatile constituents of Michelia alba flowers by gas chromatography-mass spectrometry with solid-phase microextraction 总被引:12,自引:0,他引:12
The volatile constituents of Michelia alba flowers, including fresh flowers, frozen flowers and withered flowers, were investigated by GC-MS. The volatiles in a simulated natural environment were sampled by solid-phase microextraction (SPME), with a 100 microm polydimethylsiloxane fiber at 25+/-5 degrees C for 4 h. The fibers were desorbed in a GC injection liner at 250 degrees C for 3 min. With headspace SPME-GC-MS analysis, 61 peaks were separated. The main compounds in headspace of fresh Michelia alba flowers included alpha-myrcene, (S)-limonene, (R)-fenchone, linalool, camphor, caryophyllene, germacrene D, etc., a greater number of compounds than for frozen flowers and withered flowers. At the same time, the biomarkers of fresh flowers were compared with the frozen flowers and withered flowers. In this study, headspace SPME-GC-MS afforded a simple and more sensitive sampling method for fresh Michelia alba flowers and other fresh flowers. 相似文献
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A high-repetition-rate eye-safe optical parametric oscillator (OPO), using a non-critically phase-matched KTP crystal intracavity pumped by a passively Q-switched Nd:GdVO4/Cr^4+ :YAG laser, is experimentally demonstrated. The conversion efficiency for the average power is 7% from pump diode input to OPO signal output and the slope efficiency is up to 10.3%. With an incident pump power of 7,3 W, the compact intracavity OPO (IOPO) cavity, operating at 15 kHz, produces an average power of 0.57 W at 1570 nm with a pulse width as short as 6 ns. The peak power at 1570 nm is higher than 6.3 kW. 相似文献
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以二阶的情形讨论了Poincar差分方程y(n+m)十(a1+p1(m))y(n+m-1)+…+(an+pn(m))y(m)=0当其常系数部分x(n+m)+a1x(n+m-1)+…+anx(m)=0的特征方程有相同的根时,解的渐近性质.通过不动点方法给出了Poincar差分方程的解渐近于其常系数方程解的条件,并给出了渐近式高阶项的估计. 相似文献
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Ordered mesoporous organic-inorganic hybrid materials containing microporous functional calix[8]arene amides have been synthesized and characterized for the first time, and are shown to be effective in removal of trace humic acid contaminant from water. 相似文献
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We have prepared a new family of periodic hybrid polymers containing microporous cavities provided by covalently bound organic hosts. Cyclodextrin (CD) or calixarene (CX) hosts are attached to four or more trialkoxysilyl groups, which are polymerized to form a polysilsesquioxane matrix. Structural integrity is provided by copolymerization with tetraethoxysilane, which produces a polysilicate co-matrix. Periodic order is created by carrying out the polymerization in the presence of a surfactant, cetyltrimethylammonium bromide. The resulting as-synthesized polymers from these three starting materials were characterized by solid-state nuclear magnetic resonance spectroscopy. The (13)C and (29)Si spectra provided evidence for intact polysilsesquioxane, polysilicate, organic host, and surfactant. Removal of the surfactant by washing produced a polymer containing cavities of mesoporous dimensions, in addition to the microporous host cavities. The purpose of introducing mesoporosity is to allow enhanced access of guests to the microporous hosts. Transmission electron microscopy demonstrated that both as-synthesized and solvent-extracted polymers have a periodic structure. All polymers are completely insoluble in water. The as-synthesized CD-containing polymers extracted up to >99% of 4-nitrophenol from aqueous solution, and the solvent-extracted CX-containing polymers extracted up to 67% of Fe(3+) and lesser amounts of other metal cations from aqueous solution, with interesting selectivity patterns. Simple filtration then removes the polymer containing the extracted organic molecule or metal cation. These extraction abilities are superior to previous materials. 相似文献
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The novel efficient procedure has been developed for the conjugate addition of amines to electron deficient alkenes using
the novel SO3H functionalized ionic liquid as catalyst. The results showed that the novel catalyst owned high activities for the reactions
with excellent yields within several minutes. Various amines and electron deficient alkenes were successfully transformed
to the corresponding products in the catalytic system. Operational simplicity, without need of any solvent, low cost of the
catalyst used, room temperature, high yields, reusability, excellent chemoselectivity and wide applicability are the key features
of this methodology. 相似文献
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用J─LD2转动惯量测试仪的波纹法测试转动惯量的实验方法,测量精度差,操作不方便.利用实验室现有的仪器改进成光电法测试转动惯量的方法,简单易行,测量精度高,操作方使,实践效果良好. 相似文献