A nucleophilic 1,3-rearrangement leading to 3,4-disubstituted 3,4-dihydroquinolines

A new nucleophilic 1,3-rearrangement is observed when treating 2-methoxyquinolino-3-lithium with an α-C substituted deoxybenzoin,and this rearrangement yielded an unusual 3,4-disubstituted 3,4-dihydroquinoline.Several similar reactions were designed and executed to investigate this novel 1,3-rearrangement,and a mechanism involving a nucleophilic addition and a following 1,3-rearrangement with an unusual dearomatization on the quinoline ring is proposed.     

Entanglements induced by cavity interacting with two-coupled atoms

We consider a quantum optics model where the cavity interacts with two-coupled atoms. The atom-atom entanglement, atoms-cavity entanglement and the mixture for the two atoms are investigated, and discuss the effects of the initial conditions, atom-atom coupling and the mean number of photons on the entanglements and mixture. We find that atom-atom coupling plays an important role in the entanglement and mixture. Numerical results show that under some conditions the phenomena of “entanglement sudden death” and “entanglement collapse and revival” emerge.     

一种新的手性多齿配体的合成

反-二苯乙烯;叔丁基二甲基氯硅烷;(1R;2R)-二苯基乙二醇;手性多齿配体     

Linear entropy dynamics of the field in the Jaynes－Cummings model with an intensity-dependent coupling in the dispersive approximation

We present the linear entropy dynamics of the field state in the dispersive cavity in the Jaynes－Cummings model with an intensity-dependent coupling in the dispersive approximation, and investigate the influence of dissipation on entanglement between the field and the atoms. We show that the coherence properties of the field are also affected by the cavity when the nonlinear process of the field interacting with the atoms with an intensity-dependent coupling is involved, and find that the dissipation constant, the intensity of the field and the atomic distribution angle have different influence on the coherence properties of the field.     

Entanglement death and teleportation pre-emption in a dissipative system of two coupled qubits

We discuss the entanglement of two coupled qubits each of which is interacting with a multi-mode squeezed vacuum field reservoir and the possibility to use them in a teleportation protocol. The entanglement sudden death (ESD) and teleportation pre-emption (TPE) are discovered in this system. We consider the interplay between the coupling strength and the squeezing parameter, and find that they play competing roles in entanglement as well as in teleportation. We show in detail how the entanglement decay affects the teleportation. It is interesting to show that TPE precedes ESD in general, and for given measurement result and squeeze parameter all output states of teleportation for a long time arrive at a fixed asymptotic point in the Bloch sphere.     

对TiO2亲水特性有决定性影响的物理因素

影响TiO2薄膜亲水性的三种物理特性有——表面形貌、表面粗糙度、表面颗粒大小。本文中使用电子束蒸发法制备TiO2薄膜,使用AFM、静态接触角检测对不同厚度的TiO2薄膜的物理特性以及亲水特性进行了分析。结果显示,相较于薄膜表面的颗粒尺寸及表面粗糙度,薄膜表面形貌对TiO2薄膜亲水特性有着更重要的影响。     

Thermal entanglement versus mixture in a spin chain: Generation of maximally entangled mixed states

We study the two-body entanglement and mixture in a three-qubit XXZ spin chain in thermal equilibrium state at temperature T with an external magnetic field B. The effects of the magnetic field, the anisotropy and the temperature on the entanglement and mixture are considered. We show that the ground states in this system are fully characterized and distinguished by both entanglement and mixture. Thermal entanglement versus the mixture of all two-spin states is investigated. All pairwise states provide an upper bound on the entanglement for a fixed mixture, and some part of the boundary reaches the boundary allowed by physics. As a result, maximally entangled mixed states can be generated by controlling magnetic field and temperature. Especially, in the ground state of the whole system, the explicit forms of maximally entangled mixed states are given. The results provide a new way to generate maximally entangled mixed states and control entanglement.     

Entanglement and teleportation through thermal equilibrium state of spins in the XXZ model

We study the pairwise entanglement of a three-qubit spins in the XXZ model, and teleport an unknown state using the spin chain in the thermal equilibrium as a quantum channel. The effects of coupling strength, magnetic field, the anisotropy and temperature on the entanglement and fidelity are investigated. We find that the ferromagnetic spin chain is suitable for quantum teleportation, while the anti-ferromagnetic one is not. We give the maximal average fidelity, and the condition under which the maximal average fidelity is obtained. In addition, the relation between the entanglement and fidelity is studied, and we find that the considered entanglement cannot completely reflect the fidelity.     

结构缺陷对量子波导腔中热导的调控

利用散射矩阵方法和标量模型,研究了低温下可调缺陷对量子波导腔的热导的影响. 改变缺陷的参数能控制热导,缺陷的尺寸和位置能导致热导的改变,而且不同种类的缺陷也能导致热导随温度的变化. 关键词： 声学声子输运 热导 量子结构     

Entropy squeezing for a two-level atom in the Jaynes－Cummings model with an intensity-depend coupling

We study the squeezing for a two-level atom in the Jaynes－Cummings model with intensity-dependent coupling using quantum information entropy, and examine the influences of the initial state of the system on the squeezed component number and direction of the information entropy squeezing. Our results show that, the squeezed component number depends on the atomic initial distribution angle, while the squeezed direction is determined by both the phases of the atom and the field for the information entropy squeezing. Quantum information entropy is shown to be a remarkable precision measure for atomic squeezing.