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H. Frunder D. Illig H. Finsterhölzl H.W. Schrōtter B. Lavorel G. Roussel J.C. Hilico J.P. Champion G. Pierre G. Poussigue E. Pascaud 《Chemical physics letters》1983,100(1):110-114
The CARS spectrum of the v1 band of 12CH4 at a pressure of 14 mbar was recorded using cw excitation in the cavity of a ring argon ion laser. The analysis of the intensity profile of the obarred spectrum led to the detection of inconsistencies with the hitherto proposed calculated positions of transitions with J = 7 to J = 10 and to a relocation of the corresponding lines. 相似文献
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Some general expressions for the modeling of absorption band shapes and Raman excitation profiles are presented. These expressions are shown to be exact representations of the “transform” theory of Hizhnyakov and Tehver. Examples of a calculation are presented which utilize closed-form analytical solutions for the absorption band shape and resonance Raman excitation profile. 相似文献
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D. Simatos G. Blond G. Roudaut D. Champion J. Perez A. L. Faivre 《Journal of Thermal Analysis and Calorimetry》1996,47(5):1419-1436
The glass transition temperatures of sorbitol and fructose were characterized by four points determined on DSC heating thermograms (onset, mid-point, peak and end-point), plus the limit fictive temperature. The variations of these temperature values, observed as functions of cooling and heating rates, were used to determine the fragility parameter, as defined by Angell [1] to characterize the temperature dependence of the dynamic behavior of glass-forming liquids in the temperature range above the glass transition. The apparent activation energy values, determined for the different temperatures studied, were similar for fructose and sorbitol. These values were compared to data obtained from other techniques, such as mechanical spectroscopy. The variations of the apparent activation values, observed in experiments involving cooling and heating at the same rate, slow cooling followed by rate-heating, or rate-cooling followed by fast heating, were explained by aging effects occurring during the heating step. 相似文献
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Advances on the Determination of the Astatine Pourbaix Diagram: Predomination of AtO(OH)2− over At− in Basic Conditions 下载免费PDF全文
Dumitru‐Claudiu Sergentu Dr. David Teze Dr. Andréa Sabatié‐Gogova Dr. Cyrille Alliot Ning Guo Dr. Fadel Bassal Dr. Isidro Da Silva Prof. Dr. David Deniaud Dr. Rémi Maurice Dr. Julie Champion Dr. Nicolas Galland Dr. Gilles Montavon 《Chemistry (Weinheim an der Bergstrasse, Germany)》2016,22(9):2964-2971
It is generally assumed that astatide (At?) is the predominant astatine species in basic aqueous media. This assumption is questioned in non‐complexing and non‐reductive aqueous solutions by means of high‐pressure anion‐exchange chromatography. Contrary to what is usually believed, astatide is found to be a minor species at pH=11. A different species, which also bears a single negative charge, becomes predominant when the pH is increased beyond 7. Using competition experiments, an equilibrium constant value of 10?6.9 has been determined for the formation of this species from AtO(OH) with the exchange of one proton. The identification of this species, AtO(OH)2?, is achieved through relativistic quantum mechanical calculations, which rule out the significant formation of the AtO2? species, while leading to a hydrolysis constant of AtO(OH) in excellent agreement with experiment when the AtO(OH)2? species is considered. Beyond the completion of the Pourbaix diagram of astatine, this new information is of interest for the development of 211At radiolabeling protocols. 相似文献
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A NikitinL.R Brown L FéjardJ.P Champion Vl.G Tyuterev 《Journal of Molecular Spectroscopy》2002,216(2):225-251
As part of the simultaneous analysis of line positions and intensities of the first two polyads of monodeuterated methane, the results achieved for the region 3-5 μm are reported. It involves the three highest fundamentals, (ν1, ν2, ν4), overlapped by overtone (2ν3, 2ν5, 2ν6) and combination (ν3+ν6, ν3+ν5, ν5+ν6) bands. The theoretical model was based on the global tensorial model implemented in the MIRS package. Some 10 000 line positions and 2400 line intensities have been modeled to ±0.000 88 cm−1 and ±3.6% respectively, using measurements obtained at 0.0056 and 0.011 cm−1 resolution with the Fourier transform spectrometer at National Solar Observatory located at Kitt Peak. The strongest band in this polyad is ν4(E) at 3016.7 cm−1 with a strength of 6.3×10−18 cm−1/(molecule cm−2) at 296 K; the weakest band is 2ν3(E) at 2597.7 cm−1 with a strength of 1.9×10−20 cm−1/(molecule cm−2) at 296 K. The total calculated absorption arising from the CH3D nonad is 8.95×10−18 cm−1/(molecule cm−2) at 296 K. 相似文献
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