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1.
Albo Carlos Cavalheiro 《Applications of Mathematics》2006,51(6):619-628
In the paper we study the equation L
u
= f, where L is a degenerate elliptic operator, with Neumann boundary condition in a bounded open set μ. We prove existence and uniqueness
of solutions in the space H(μ) for the Neumann problem. 相似文献
2.
de Toledo RA Santos MC Cavalheiro ET Mazo LH 《Analytical and bioanalytical chemistry》2005,381(6):1161-1166
This work describes an electroanalytical investigation of dopamine using cyclic voltammetry (CV) and the graphite–polyurethane composite electrode (GPU). In CV studies, well-defined redox peaks characterize the oxidation process at the GPU electrode, which is indicative of electrocatalytic effects associated with active sites on the GPU electrode surface. A new analytical methodology was developed using the GPU electrode and square wave voltammetry (SWV) in BR buffer solution (0.1 mol L–1; pH 7.4). Analytical curves were constructed under optimized conditions (f=60s–1, Ea=50 mV, EI=2 mV) and detection and quantification limits of 6.4×10–8 mol L–1 (12.1 g L–1) and 5.2×10–6 mol L–1 (0.9 mg L–1), respectively, were achieved. The precision of the method was checked by performing ten successive measurements for a 9.9×10–6 mol L–1 dopamine solution. For intra-assay and inter-assay precisions, the relative standard deviations were 1.9 and 2.3%, respectively. In order to evaluate the developed methodology, the determination of dopamine was performed with good sensitivity and selectivity, without the interference of ascorbic acid in synthetic cerebrospinal fluid, which indicates that the new methodology enables reliable analysis of dopamine. 相似文献
3.
Glutamic acid (H2glu) and its lithium, sodium
and ammonium monosalts were submitted to thermal analysis using thermogravimetry
(TG) and differential thermal analysis (DTA). The main goal of these studies
was to compare the relative thermal stability and to evaluate the effect of
the counter ion in the thermal decomposition pathways. Salts were obtained
by direct neutralization of the purified acid with LiOH, NaOH or NH4OH
and were characterized by elemental analysis (C, H and N) and IR spectroscopy.
Decomposition occurred after conversion to the pyroglutamic acid or the respective
pyroglutamates and ammonium salt loosing NH3 being
converted to H2glu before decomposition. 相似文献
4.
Simultaneous
thermogravimetry (TG) and differential thermal analysis (DTA) techniques were
used for the characterization the thermal degradation of loratadine, ethyl-4-(8-chloro-5,6-dihydro-11H-benzo[5,6]cyclohepta[1,2-b]pyridin-11-ylidine)-1-piperidinecarboxylate.
TG analysis revealed that the thermal decomposition occurs in one step in
the 200–400°C range in nitrogen atmosphere. DTA and DSC curves showed
that loratadine melts before the decomposition and the decomposition products
are volatile in nitrogen. In air the decomposition follows very similar profile
up to 300°C, but two exothermic events are observed in the 170–680°C
temperature range.
Flynn–Wall–Ozawa method was used
for the solid-state kinetic analysis of loratadine thermal decomposition.
The calculated activation energy (E
a)
was 91±1 kJ mol–1 for α between
0.02 and 0.2, where the mass loss is mainly due to the decomposition than
to the evaporation of the decomposition products. 相似文献
5.
Pinto B. V. Ferreira A. P. G. Cavalheiro E. T. G. 《Journal of Thermal Analysis and Calorimetry》2018,133(3):1509-1518
Journal of Thermal Analysis and Calorimetry - Citalopram, [(R,S)-1-[3-(dimethylamino)propyl]-1-(4-fluorophenyl)-1,3-dihydroisobenzofuran-5-carbonitrile] hydrobromide and its S-isomer, escitalopram... 相似文献
6.
Rita de Cássia da Silva Felipe Silva Semaan Csaba Novák Eder Tadeu Gomes Cavalheiro 《Journal of Thermal Analysis and Calorimetry》2013,111(3):1933-1937
Data from theoretical, thermal, and spectroscopic methods were compared in order to map a possible mechanism for the thermal decomposition of furosemide, a diuretic compound, in solid state. TG/DTG curves suggested a two-stage decomposition process. The first product of decomposition is water (m/z = 18), released due to a dimerization resulting in the formation of an amide. Then carbon dioxide (m/z = 44), nitroxide (m/z = 30), and 2-methyl-furanyl ion (m/z = 81) are released in the second stage. The chlorine substituted benzene ring, due to the double bond conjugated system, being the last fraction to decompose. Theoretical calculations presented are in agreement with experimental results. 相似文献
7.
Franciani C. Sentanin Willian R. Caliman Rodrigo C. Sabadini Carla C. S. Cavalheiro Rui F. P. Pereira Maria M. Silva Agnieszka Pawlicka 《Molecules (Basel, Switzerland)》2021,26(8)
Nanocomposite polymer electrolytes (NPEs) were synthesized using sodium alginate (Alg) and either sodium (SCa-3-Na+)- or lithium (SCa-3-Li+)-modified montmorillonite clays. The samples were characterized by structural, optical, and electrical properties. SCa-3-Na+ and SCa-3-Li+ clays’ X-ray structural analyses revealed peaks at 2θ = 7.2° and 6.7° that corresponded to the interlamellar distances of 12.3 and 12.8 Å, respectively. Alg-based NPEs X-ray diffractograms showed exfoliated structures for samples with low clay percentages. The increase of clay content promoted the formation of intercalated structures. Electrochemical Impedance Spectroscopy revealed that Alg-based NPEs with 5 wt% of SCa-3-Na+ clay presented the highest conductivity of 1.96 × 10−2 S/cm2, and Alg with 10 wt% of SCa-3-Li+ showed conductivity of 1.30 × 10−2 S/cm2, both measured at 70 °C. From UV-Vis spectroscopy, it was possible to infer that increasing concentration of clay promoted a decrease of the samples’ transmittance and, consequently, an increase of their reflectance. 相似文献
8.
Deyber Arley Vargas Medina Ana Paula Garcia Ferreira Eder Tadeu Gomes Cavalheiro 《Journal of Thermal Analysis and Calorimetry》2014,117(1):361-367
The thermal behavior of sodium saccharin polymorphic forms was investigated using thermogravimetry and differential scanning calorimetry, while structural changes during the dehydration processes were monitored by X-ray powder diffraction. In solid state, sodium saccharine may exhibit three forms: anhydrate, 2/3 hydrate (triclinic), and 15/8 hydrate (monoclinic) ones. In this investigation, it was established that monoclinic and triclinic forms compose an entantiotropically related polymorphs system. At 82 °C, the 15/8 hydrated monoclinic form is converted to 2/3 hydrated triclinic form, which showed to be the more thermodynamically stable form at room temperature. Spontaneous solidification leads to the formation of triclinic cell setting, and additionally, spontaneous hydration of the anhydrous form leads to formation of 2/3 hydrated triclinic form. 相似文献
9.
1.IntrodnctionWegiveaproofofthestrongconvergenceinofthesolutionoftheparabolicapproximationtowardstheentropicsolutiontothescalarconservationlawwhereuo(RN),udenotessomeapproximationofuosuchthatandthefluxfsatisfiesTheconvergenceoftheapproximatesolutions... 相似文献
10.
Ronaldo S. Nunes Felipe S. Semaan Alan T. Riga Éder T. G. Cavalheiro 《Journal of Thermal Analysis and Calorimetry》2009,97(1):349-353
The thermal properties of verapamil hydrochloride (VRP) and its physical association as binary mixtures with some common excipients
were evaluated. Thermogravimetry (TG) was used to determine the thermal mass loss, as well as to study the kinetics of VRP
thermal decomposition, using the Flynn-Wall-Ozawa model. Based on their frequent use in pharmacy, five different excipients
(microcrystalline cellulose, magnesium stearate, hydroxypropyl methylcellulose, polyvinylpyrrolidone and talc) were blended
with VRP. Samples were prepared by mixing the analyte and excipients in a proportion of 1:1 (m/m). DSC curves for pure VRP
presented an endothermic event at 143 ± 2 °C (ΔHmelt = 132 ± 4 J g−1), which corresponds to the melting (literature Tm = 143.7 °C, ΔHmelt = 130.6 J g−1). Comparisons among the observed results for each compound and their binary physical mixtures presented no relevant changes.
This suggests no interaction between the drug and excipient. 相似文献